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Volume 30 Issue 6
Jun.  2023
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Article Navigation >  International Journal of Minerals, Metallurgy and Materials  > 2023  >  30(6): 1152-1161
Dan Zhang, Chunyan Zhang, Xuan Zheng, Yizhuo Zhao, Xinyu Shi, Baomin Luo, Yuzhu Li, Guangyin Liu, Xiaodi Liu, and Chuang Yu, Facile synthesis of the Mn3O4 polyhedron grown on N-doped honeycomb carbon as high-performance negative material for lithium-ion batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 6, pp. 1152-1161. https://doi.org/10.1007/s12613-022-2590-5
Cite this article as:
Dan Zhang, Chunyan Zhang, Xuan Zheng, Yizhuo Zhao, Xinyu Shi, Baomin Luo, Yuzhu Li, Guangyin Liu, Xiaodi Liu, and Chuang Yu, Facile synthesis of the Mn3O4 polyhedron grown on N-doped honeycomb carbon as high-performance negative material for lithium-ion batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 6, pp. 1152-1161. https://doi.org/10.1007/s12613-022-2590-5
shu
Research Article

Facile synthesis of the Mn3O4 polyhedron grown on N-doped honeycomb carbon as high-performance negative material for lithium-ion batteries

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  • Corresponding authors:

    Dan Zhang    E-mail: danzhangny@163.com

    Chuang Yu    E-mail: cyu2020@hust.edu.cn

  • Received: 26 October 2022; Revised: 7 December 2022; Accepted: 22 December 2022; Available online: 23 December 2022
    Abstract
  • Because of their large volume variation and inferior electrical conductivity, Mn3O4-based oxide anode materials have short cyclic lives and poor rate capability, which obstructs their development. In this study, we successfully prepared a Mn3O4/N-doped honeycomb carbon composite using a smart and facile synthetic method. The Mn3O4 nanopolyhedra are grown on N-doped honeycomb carbon, which evidently mitigates the volume change in the charging and discharging processes but also improves the electrochemical reaction kinetics. More importantly, the Mn–O–C bond in the Mn3O4/N-doped honeycomb carbon composite benefits electrochemical reversibility. These features of the Mn3O4/N-doped honeycomb carbon (NHC) composite are responsible for its superior electrochemical performance. When used for Li-ion batteries, the Mn3O4/N-doped honeycomb carbon anode exhibits a high reversible capacity of 598 mAh·g−1 after 350 cycles at 1 A·g−1. Even at 2 A·g−1, the Mn3O4/NHC anode still delivers a high capacity of 472 mAh·g−1. This work provides a new prospect for synthesizing and developing manganese-based oxide materials for energy storage.
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