A gel polymer electrolyte with IL@UiO-66-NH<sub>2</sub> as fillers for high-performance all-solid-state lithium metal batteries

Tao Wei; Qi Zhang; Sijia Wang; Mengting Wang; Ye Liu; Cheng Sun; Yanyan Zhou; Qing Huang; Xiangyun Qiu; Fang Tian

doi:10.1007/s12613-023-2639-0

Volume 30 Issue 10

Oct. 2023

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2023 > 30(10): 1897-1905

Tao Wei, Qi Zhang, Sijia Wang, Mengting Wang, Ye Liu, Cheng Sun, Yanyan Zhou, Qing Huang, Xiangyun Qiu, and Fang Tian, A gel polymer electrolyte with IL@UiO-66-NH₂ as fillers for high-performance all-solid-state lithium metal batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1897-1905. https://doi.org/10.1007/s12613-023-2639-0

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Tao Wei, Qi Zhang, Sijia Wang, Mengting Wang, Ye Liu, Cheng Sun, Yanyan Zhou, Qing Huang, Xiangyun Qiu, and Fang Tian, A gel polymer electrolyte with IL@UiO-66-NH2 as fillers for high-performance all-solid-state lithium metal batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1897-1905. https://doi.org/10.1007/s12613-023-2639-0

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Research Article

A gel polymer electrolyte with IL@UiO-66-NH₂ as fillers for high-performance all-solid-state lithium metal batteries

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Corresponding author:
Tao Wei E-mail: wt863@just.edu.cn
Received: 7 February 2023; Revised: 28 March 2023; Accepted: 29 March 2023; Available online: 30 March 2023

Abstract

Abstract

All solid-state electrolytes have the advantages of good mechanical and thermal properties for safer energy storage, but their energy density has been limited by low ionic conductivity and large interfacial resistance caused by the poor Li⁺ transport kinetics due to the solid–solid contacts between the electrodes and the solid-state electrolytes. Herein, a novel gel polymer electrolyte (UPP-5) composed of ionic liquid incorporated metal-organic frameworks nanoparticles (IL@MOFs) is designed, it exhibits satisfying electrochemical performances, consisting of an excellent electrochemical stability window (5.5 V) and an improved Li⁺ transference number of 0.52. Moreover, the Li/UPP-5/LiFePO₄ full cells present an ultra-stable cycling performance at 0.2C for over 100 cycles almost without any decay in capacities. This study might provide new insight to create an effective Li⁺ conductive network for the development of all-solid-state lithium-ion batteries.
- all solid-state lithium-ion batteries;
- metal-organic frameworks;
- gel polymer electrolytes;
- ionic liquid;
- solid electrolyte interphase

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References

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