Recent advances and perspectives of zinc metal-free anodes for zinc ion batteries

Jiabing Miao; Yingxiao Du; Ruotong Li; Zekun Zhang; Ningning Zhao; Lei Dai; Ling Wang; Zhangxing He

doi:10.1007/s12613-023-2665-y

Volume 31 Issue 1

Jan. 2024

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2024 > 31(1): 33-47

Jiabing Miao, Yingxiao Du, Ruotong Li, Zekun Zhang, Ningning Zhao, Lei Dai, Ling Wang, and Zhangxing He, Recent advances and perspectives of zinc metal-free anodes for zinc ion batteries, Int. J. Miner. Metall. Mater., 31(2024), No. 1, pp. 33-47. https://doi.org/10.1007/s12613-023-2665-y

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Jiabing Miao, Yingxiao Du, Ruotong Li, Zekun Zhang, Ningning Zhao, Lei Dai, Ling Wang, and Zhangxing He, Recent advances and perspectives of zinc metal-free anodes for zinc ion batteries, Int. J. Miner. Metall. Mater., 31(2024), No. 1, pp. 33-47. https://doi.org/10.1007/s12613-023-2665-y

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Invited Review

Recent advances and perspectives of zinc metal-free anodes for zinc ion batteries

+ Author Affiliations

Corresponding authors:
Zekun Zhang    E-mail: zhangzekun1020@163.com

Lei Dai    E-mail: dailei_b@163.com

Zhangxing He    E-mail: zxhe@ncst.edu.cn
Received: 11 January 2023; Revised: 22 March 2023; Accepted: 25 April 2023; Available online: 26 April 2023

Abstract

Abstract

Zinc-ion batteries (ZIBs) are recognized as potential energy storage devices due to their advantages of low cost, high energy density, and environmental friendliness. However, zinc anodes are subject to unavoidable zinc dendrites, passivation, corrosion, and hydrogen evolution reactions during the charging and discharging of batteries, becoming obstacles to the practical application of ZIBs. Appropriate zinc metal-free anodes provide a higher working potential than metallic zinc anodes, effectively solving the problems of zinc dendrites, hydrogen evolution, and side reactions during the operation of metallic zinc anodes. The improvement in the safety and cycle life of batteries creates conditions for further commercialization of ZIBs. Therefore, this work systematically introduces the research progress of zinc metal-free anodes in “rocking chair” ZIBs. Zinc metal-free anodes are mainly discussed in four categories: transition metal oxides, transition metal sulfides, MXene (two dimensional transition metal carbide) composites, and organic compounds, with discussions on their properties and zinc storage mechanisms. Finally, the outlook for the development of zinc metal-free anodes is proposed. This paper is expected to provide a reference for the further promotion of commercial rechargeable ZIBs.
- zinc ion batteries;
- anode;
- zinc metal-free anode;
- recent advances;
- perspectives

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