Competitive oxidation behavior of Ni-based superalloy GH4738 at extreme temperature

Hui Xu; Shufeng Yang; Enhui Wang; Yunsong Liu; Chunyu Guo; Xinmei Hou; Yanling Zhang

doi:10.1007/s12613-023-2687-5

Volume 31 Issue 1

Jan. 2024

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2024 > 31(1): 138-145

Hui Xu, Shufeng Yang, Enhui Wang, Yunsong Liu, Chunyu Guo, Xinmei Hou, and Yanling Zhang, Competitive oxidation behavior of Ni-based superalloy GH4738 at extreme temperature, Int. J. Miner. Metall. Mater., 31(2024), No. 1, pp. 138-145. https://doi.org/10.1007/s12613-023-2687-5

Cite this article as:

Hui Xu, Shufeng Yang, Enhui Wang, Yunsong Liu, Chunyu Guo, Xinmei Hou, and Yanling Zhang, Competitive oxidation behavior of Ni-based superalloy GH4738 at extreme temperature, Int. J. Miner. Metall. Mater., 31(2024), No. 1, pp. 138-145. https://doi.org/10.1007/s12613-023-2687-5

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Research Article

Competitive oxidation behavior of Ni-based superalloy GH4738 at extreme temperature

+ Author Affiliations

Corresponding authors:
Shufeng Yang E-mail: yangshufeng@ustb.edu.cn

Enhui Wang E-mail: wangenhui@ustb.edu.cn
Received: 27 January 2023; Revised: 3 May 2023; Accepted: 1 June 2023; Available online: 6 June 2023

Abstract

Abstract

A high thrust-to-weight ratio poses challenges to the high-temperature performance of Ni-based superalloys. The oxidation behavior of GH4738 at extreme temperatures has been investigated by isothermal and non-isothermal experiments. As a result of the competitive diffusion of alloying elements, the oxide scale included an outermost porous oxide layer (OOL), an inner relatively dense oxide layer (IOL), and an internal oxide zone (IOZ), depending on the temperature and time. A high temperature led to the formation of large voids at the IOL/IOZ interface. At 1200°C, the continuity of the Cr-rich oxide layer in the IOL was destroyed, and thus, spallation occurred. Extension of oxidation time contributed to the size of Al-rich oxide particles with the increase in the IOZ. Based on this finding, the oxidation kinetics of GH4738 was discussed, and the corresponding oxidation behavior at 900–1100°C was predicted.
- Ni-based superalloy GH4738;
- extreme temperature;
- competitive oxidation;
- oxidation mechanism;
- oxidation kinetics

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