Mechanically mixing copper and silver into self-supporting electrocatalyst for hydrogen evolution

Xinzhuo Hu; Zhe Liu; Yi Feng; Yongfeng Zhang; Zhe Li; Zhennan Chen; Jing Mao; Jing Yang; Hui Liu; Pengfei Yin; Lei Cui; Xiwen Du

doi:10.1007/s12613-023-2695-5

Volume 30 Issue 10

Oct. 2023

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2023 > 30(10): 1906-1913

Xinzhuo Hu, Zhe Liu, Yi Feng, Yongfeng Zhang, Zhe Li, Zhennan Chen, Jing Mao, Jing Yang, Hui Liu, Pengfei Yin, Lei Cui, and Xiwen Du, Mechanically mixing copper and silver into self-supporting electrocatalyst for hydrogen evolution, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1906-1913. https://doi.org/10.1007/s12613-023-2695-5

Cite this article as:

Xinzhuo Hu, Zhe Liu, Yi Feng, Yongfeng Zhang, Zhe Li, Zhennan Chen, Jing Mao, Jing Yang, Hui Liu, Pengfei Yin, Lei Cui, and Xiwen Du, Mechanically mixing copper and silver into self-supporting electrocatalyst for hydrogen evolution, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1906-1913. https://doi.org/10.1007/s12613-023-2695-5

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Research Article

Mechanically mixing copper and silver into self-supporting electrocatalyst for hydrogen evolution

+ Author Affiliations

Corresponding authors:
Pengfei Yin    E-mail: pengfeiyin@tju.edu.cn

Lei Cui    E-mail: leicui@tju.edu.cn

Xiwen Du    E-mail: xwdu@tju.edu.cn
Received: 26 March 2023; Revised: 18 June 2023; Accepted: 21 June 2023; Available online: 29 June 2023

Abstract

Abstract

Commercial hydrogen production involves the development of efficient hydrogen evolution reaction catalysts. Herein, we adopted a friction stir processing (FSP) technique to mix immiscible metals homogenously and obtain a self-supporting copper–silver (CuAg) catalyst. The gust of Ag atoms with larger atomic sizes caused a tensile strain in the Cu matrix. Meanwhile, the chemical-potential difference induced electron transfer from Cu to Ag, and the two factors jointly led to the upshift of Cu d-band and improved the catalytic activity. Consequently, the CuAg electrode exhibited a high turnover frequency (12 times that of pure Cu), a low overpotential at high current density (superior to platinum foil), and high durability (1.57% decay over 180 h). Our work demonstrates that FSP is a powerful method for preparing self-supporting catalysts of immiscible alloys with high catalytic performance.
- hydrogen evolution reaction;
- catalyst;
- friction stir processing;
- strain;
- electron transfer

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