A functionalized activated carbon adsorbent prepared from waste amidoxime resin by modifying with H3PO4 and ZnCl2 and its excellent Cr(VI) adsorption

Chunlin He; Yun Liu; Mingwei Qi; Zunzhang Liu; Yuezhou Wei; Toyohisa Fujita; Guifang Wang; Shaojian Ma; Wenchao Yang

doi:10.1007/s12613-023-2737-z

Volume 31 Issue 3

Mar. 2024

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2024 > 31(3): 585-598

Chunlin He, Yun Liu, Mingwei Qi, Zunzhang Liu, Yuezhou Wei, Toyohisa Fujita, Guifang Wang, Shaojian Ma, and Wenchao Yang, A functionalized activated carbon adsorbent prepared from waste amidoxime resin by modifying with H₃PO₄ and ZnCl₂ and its excellent Cr(VI) adsorption, Int. J. Miner. Metall. Mater., 31(2024), No. 3, pp. 585-598. https://doi.org/10.1007/s12613-023-2737-z

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Chunlin He, Yun Liu, Mingwei Qi, Zunzhang Liu, Yuezhou Wei, Toyohisa Fujita, Guifang Wang, Shaojian Ma, and Wenchao Yang, A functionalized activated carbon adsorbent prepared from waste amidoxime resin by modifying with H3PO4 and ZnCl2 and its excellent Cr(VI) adsorption, Int. J. Miner. Metall. Mater., 31(2024), No. 3, pp. 585-598. https://doi.org/10.1007/s12613-023-2737-z

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Research Article

A functionalized activated carbon adsorbent prepared from waste amidoxime resin by modifying with H₃PO₄ and ZnCl₂ and its excellent Cr(VI) adsorption

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Corresponding author:
Chunlin He E-mail: helink1900@126.com
Received: 10 April 2023; Revised: 30 June 2023; Accepted: 8 September 2023; Available online: 9 September 2023

Abstract

Abstract

With the application of resins in various fields, numerous waste resins that are difficult to treat have been produced. The industrial wastewater containing Cr(VI) has severely polluted soil and groundwater environments, thereby endangering human health. Therefore, in this paper, a novel functionalized mesoporous adsorbent PPR-Z was synthesized from waste amidoxime resin for adsorbing Cr(VI). The waste amidoxime resin was first modified with H₃PO₄ and ZnCl₂, and subsequently, it was carbonized through slow thermal decomposition. The static adsorption of PPR-Z conforms to the pseudo-second-order kinetic model and Langmuir isotherm, indicating that the Cr(VI) adsorption by PPR-Z is mostly chemical adsorption and exhibits single-layer adsorption. The saturated adsorption capacity of the adsorbent for Cr(VI) could reach 255.86 mg/g. The adsorbent could effectively reduce Cr(VI) to Cr(III) and decrease the toxicity of Cr(VI) during adsorption. PPR-Z exhibited Cr(VI) selectivity in electroplating wastewater. The main mechanisms involved in the Cr(VI) adsorption are the chemical reduction of Cr(VI) into Cr(III) and electrostatic and coordination interactions. Preparation of PPR-Z not only solves the problem of waste resin treatment but also effectively controls Cr(VI) pollution and realizes the concept of “treating waste with waste”.
- waste amidoxime resin;
- mesoporous adsorbent;
- H₃PO₄ and ZnCl₂ processing;
- Cr(VI) adsorption;
- electroplating wastewater

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