Jishuo Han, Yong Li, Chenhong Ma, Qingyao Zheng, Xiuhua Zhang,  and Xiaofang Wu, Study on the oxidation mechanism of Al–SiC composite at elevated temperature, Int. J. Miner. Metall. Mater., 31(2024), No. 9, pp. 2077-2087. https://doi.org/10.1007/s12613-023-2778-3
Cite this article as:
Jishuo Han, Yong Li, Chenhong Ma, Qingyao Zheng, Xiuhua Zhang,  and Xiaofang Wu, Study on the oxidation mechanism of Al–SiC composite at elevated temperature, Int. J. Miner. Metall. Mater., 31(2024), No. 9, pp. 2077-2087. https://doi.org/10.1007/s12613-023-2778-3
Research Article

Study on the oxidation mechanism of Al–SiC composite at elevated temperature

+ Author Affiliations
  • Corresponding author:

    Yong Li    E-mail: lirefractory@vip.sina.com

  • Received: 22 August 2023Revised: 13 October 2023Accepted: 6 November 2023Available online: 10 November 2023
  • Resin-bonded Al–SiC composite was sintered at 1100, 1300, and 1500°C in the air, the oxidation mechanism was investigated. The reaction models were also established. The oxidation resistance of the Al–SiC composite was significantly enhanced with temperature increase. SiC in the exterior of the composite was partially oxidized slightly, while the transformation of metastable Al4C3 to stable Al4SiC4 existed in the interior. At 1100°C, Al in the interior reacted with residual C to form Al4C3. With increasing to 1300°C, high temperature and low oxygen partial pressure lead to active oxidation of SiC, and internal gas composition transforms to Al2O(g) + CO(g) + SiO(g) as the reaction proceeds. After Al4C3 is formed, CO(g) and SiO(g) are continuously deposited on its surface, transforming to Al4SiC4. At 1500°C, a dense layer consisting of SiC and Al4SiC4 whiskers is formed which cuts off the diffusion channel of oxygen. The active oxidation of SiC is accelerated, enabling more gas to participate in the synthesis of Al4SiC4, eventually forming hexagonal lamellar Al4SiC4 with mutual accumulation between SiC particles. Introducing Al enhances the oxidation resistance of SiC. In addition, the in situ generated non-oxide is uniformly dispersed on a micro-scale and bonds SiC stably.
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