Temperature-sensing array using the metal-to-insulator transition of NdxSm1−xNiO3

Fengbo Yan; Ziang Li; Hao Zhang; Yuchen Cui; Kaiqi Nie; Nuofu Chen; Jikun Chen

doi:10.1007/s12613-023-2816-1

Volume 31 Issue 7

Jul. 2024

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2024 > 31(7): 1694-1700

Fengbo Yan, Ziang Li, Hao Zhang, Yuchen Cui, Kaiqi Nie, Nuofu Chen, and Jikun Chen, Temperature-sensing array using the metal-to-insulator transition of Nd_xSm_1−xNiO₃, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1694-1700. https://doi.org/10.1007/s12613-023-2816-1

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Fengbo Yan, Ziang Li, Hao Zhang, Yuchen Cui, Kaiqi Nie, Nuofu Chen, and Jikun Chen, Temperature-sensing array using the metal-to-insulator transition of NdxSm1−xNiO3, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1694-1700. https://doi.org/10.1007/s12613-023-2816-1

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Research Article

Temperature-sensing array using the metal-to-insulator transition of Nd_xSm_1−xNiO₃

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Corresponding author:
Jikun Chen E-mail: jikunchen@ustb.edu.cn
Received: 18 August 2023; Revised: 21 December 2023; Accepted: 22 December 2023; Available online: 27 December 2023

Abstract

Abstract

Rare-earth nickelates (RENiO₃) show widely tunable metal-to-insulator transition (MIT) properties with ignorable variations in lattice constants and small latent heat across the critical temperature (T_MIT). Particularly, it is worth noting that compared with the more commonly investigated vanadium oxides, the MIT of RENiO₃ is less abrupt but usually across a wider range of temperatures. This sheds light on their alternative applications as negative temperature coefficient resistance (NTCR) thermistors with high sensitivity compared with the current NTCR thermistors, other than their expected use as critical temperature resistance thermistors. In this work, we demonstrate the NTCR thermistor functionality for using the adjustable MIT of Nd_xSm_1−xNiO₃ within 200–400 K, which displays larger magnitudes of NTCR (e.g., more than 7%/K) that is unattainable in traditional NTCR thermistor materials. The temperature dependence of resistance (R–T) shows sharp variation during the MIT of Nd_xSm_1−xNiO₃ with no hysteresis via decreasing the Nd content (e.g., x ≤ 0.8), and such a R–T tendency can be linearized by introducing an optimum parallel resistor. The sensitive range of temperature can be further extended to 210–360 K by combining a series of Nd_xSm_1−xNiO₃ with eight rare-earth co-occupation ratios as an array, with a high magnitude of NTCR (e.g., 7%–14%/K) covering the entire range of temperatures.
- rare-earth nickelates;
- metal-to-insulator transition;
- correlated oxides;
- perovskites

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References(24)

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