Recent advances and perspectives in MXene-based cathodes for aqueous zinc-ion batteries

Aiduo Wu; Tianhao Wang; Long Zhang; Chen Chen; Qiaomin Li; Xuanhui Qu; Yongchang Liu

doi:10.1007/s12613-024-2859-y

Volume 31 Issue 7

Jul. 2024

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Article Navigation > International Journal of Minerals, Metallurgy and Materials > 2024 > 31(7): 1752-1765

Aiduo Wu, Tianhao Wang, Long Zhang, Chen Chen, Qiaomin Li, Xuanhui Qu, and Yongchang Liu, Recent advances and perspectives in MXene-based cathodes for aqueous zinc-ion batteries, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1752-1765. https://doi.org/10.1007/s12613-024-2859-y

Cite this article as:

Aiduo Wu, Tianhao Wang, Long Zhang, Chen Chen, Qiaomin Li, Xuanhui Qu, and Yongchang Liu, Recent advances and perspectives in MXene-based cathodes for aqueous zinc-ion batteries, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1752-1765. https://doi.org/10.1007/s12613-024-2859-y

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Invited Review

Recent advances and perspectives in MXene-based cathodes for aqueous zinc-ion batteries

+ Author Affiliations

Corresponding authors:
Long Zhang    E-mail: zhanglong@ustb.edu.cn

Qiaomin Li    E-mail: qli091@ustb.edu.cn

Yongchang Liu    E-mail: liuyc@ustb.edu.cn
Received: 23 December 2023; Revised: 2 February 2024; Accepted: 22 February 2024; Available online: 23 February 2024

Abstract

Abstract

Aqueous zinc-ion batteries (AZIBs) show great potential for applications in grid-scale energy storage, given their intrinsic safety, cost effectiveness, environmental friendliness, and impressive electrochemical performance. However, strong electrostatic interactions exist between zinc ions and host materials, and they hinder the development of advanced cathode materials for efficient, rapid, and stable Zn-ion storage. MXenes and their derivatives possess a large interlayer spacing, excellent hydrophilicity, outstanding electronic conductivity, and high redox activity. These materials are considered “rising star” cathode candidates for AZIBs. This comprehensive review discusses recent advances in MXenes as AZIB cathodes from the perspectives of crystal structure, Zn-storage mechanism, surface modification, interlayer engineering, and conductive network design to elucidate the correlations among their composition, structure, and electrochemical performance. This work also outlines the remaining challenges faced by MXenes for aqueous Zn-ion storage, such as the urgent need for improved toxic preparation methods, exploration of potential novel MXene cathodes, and suppression of layered MXene restacking upon cycling, and introduces the prospects of MXene-based cathode materials for high-performance AZIBs.
- aqueous zinc-ion batteries;
- MXenes;
- terminal groups;
- interlayer engineering;
- conductive network design

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