Hybrid CoMoO3/CoMoO4 Nanorods for Enhanced Lithium-Ion Battery Performance

Lijia Wan; Tingting Zhang; Ran Sun; Chunlai Huang; Ting Lu; Junping Hu; Likun Pan

doi:10.1007/s12613-024-3051-0

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International Journal of Minerals, Metallurgy and Materials > 2024 > Accepted Manuscript > DOI: 10.1007/s12613-024-3051-0

Lijia Wan, Tingting Zhang, Ran Sun, Chunlai Huang, Ting Lu, Junping Hu, and Likun Pan, Hybrid CoMoO3/CoMoO4 Nanorods for Enhanced Lithium-Ion Battery Performance, Int. J. Miner. Metall. Mater.,(2024). https://dx.doi.org/10.1007/s12613-024-3051-0

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Research Article

Hybrid CoMoO3/CoMoO4 Nanorods for Enhanced Lithium-Ion Battery Performance

Lijia Wan^1,2),
Tingting Zhang¹⁾,
Ran Sun¹⁾,
Chunlai Huang¹⁾,
Ting Lu²⁾,
Junping Hu¹⁾ and
Likun Pan^2),

Author Affilications

1)
Nanchang Key Laboratory of Photoelectric Conversion and Energy Storage Materials, Nanchang Institute of Technology, Nanchang 330099, China
2)
Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China

Received: 04 October 2024; Revised: 19 November 2024; Accepted: 20 November 2024; Available Online: 21 November 2024

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Abstract

Abstract

Electrode materials that rely on conversion reactions for lithium-ion batteries (LIBs) are known for their higher energy densities. However, a key issue in their design is to bolster their stability and to minimize the volume variations that occur during lithiation and delithiation. Herein, an effective strategy has been devised to fulfill the fully reversible conversion reaction for lithium storage in CoMoO4 by hybridizing CoMoO3. The CoMoO3/CoMoO4 with a nanorod structure was synthesized via one-step annealing treatment after a solvothermal process. In such a structure, CoMoO3/CoMoO4 nanorod can significantly boost their mechanical robustness and offer ample space to counteract volume fluctuations throughout successive cycles, owing to the cooperative interaction between CoMoO3 and CoMoO4. The CoMoO3/CoMoO4 exhibits a superior lithium-storage capacity (919.6 mAh/g at 0.1 A/g after cycling for 200) and cycling stability (683.4 mAh/g after at 1 A/g after cycling for 600). The CoMoO3/CoMoO4 show high potential as an anode material for LIBs.
- CoMoO3/CoMoO4,
- Nanorod structure,
- Hybrid material,
- Lithium-ion batteries

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