The Double Glow Plasma Surface Alloying Technique, the Xu-Tee Process, is a new method to produce high quality alloying layer on the surface of less expensive materials. By using thes technique, the surface alloying layer similar to superalloy Inconel 625 has been obtained on the surface of three kinds of melallic materials (low carbon steel, industrial pure iron, stainless steel Cr18Ni9). The results of the composition and microstructure analyzed by Scanning Electron Microscopy (SEM) and X-Ray Uffrachon (XRD) show that the alloying layer consistS of y matrix and several precipitates (Laves intermetallic phase and carbide etc.). The electrochemical corrosion results show that the surface alloying layer formed on the surface of stainless steel and industrial pure iron have better corrosion resistance than that of nickel base alloy inconel 625 and stainless steel Cr18Ni9 in 3.5%NaCl solution. The exper iments indicate that it is an effective way to obtain the gradient surface alloying layer on the surfaces of steels by using Double Glow Plasma Surface Alloying Technique.