Special Issue on High-Temperature Molten Salt Chemistry and Technology
Guest editors
Prof. Dr. Shu-qiang Jiao E-mail
State Key Laboratory of Advanced Metallurgy
University of Science and Technology Beijing, Beijing 100083, China
Prof. Dr. Ming-yong Wang E-mail
State Key Laboratory of Advanced Metallurgy
University of Science and Technology Beijing, Beijing 100083, China
Prof. Dr. Wei-li Song E-mail
Institute of Advanced Structure Technology
Beijing Institute of Technology, Beijing 100081, China
Scope
High-temperature molten salt usually consists of metal cations and non-metal anions. Recently, molten oxides are also considered as a kind of molten salt. Generally, molten salts possess various attractive physical-chemical properties (such as high conductivity, broad electrochemical window, rapid mass transfer, high solubility to reactants, and low vapor pressure) and are considered as a favorable medium to break the limits of aqueous solutions. In the past, high-temperature molten salt electrolysis has been widely applied as an indispensable metallurgy method to produce Al, rare earth, alkali/alkaline-earth metals and refractory metals. Besides, application and investigation of molten salts can be also extended to material synthesis, energy storage, gas capture, and nuclear energy, with expectation to advance the interdisciplinary development of metallurgy, materials, energy, chemical engineering, environment, and so on.
This Special Issue emphasizes, but is not limited to the following:
(1) Structure and properties of high-temperature molten salts, including theory, modeling, simulation and in-situ characterization methods;
(2) Novel electrochemical and chemical metallurgy processes in the high-temperature molten salts;
(3) Structural and functional materials synthetized in the high-temperature molten salts;
(4) Capture and utilization of CO2 and SOx;
(5) Heat storage for solar and nuclear energy;
(6) Treatment and recovery of nuclear wastes;
(7) Novel batteries based on high-temperature molten salt electrolytes.
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Editorial for special issue on high-temperature molten salt chemistry and technology
2020, vol. 27, no. 12, pp. 1569-1571. doi: 10.1007/s12613-020-2225-7
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Interactions of molten salts with cathode products in the FFC Cambridge Process
2020, vol. 27, no. 12, pp. 1572-1587. doi: 10.1007/s12613-020-2202-1
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A review on liquid metals as cathodes for molten salt/oxide electrolysis
2020, vol. 27, no. 12, pp. 1588-1598. doi: 10.1007/s12613-020-1971-x
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Applications of molten salt and progress of molten salt electrolysis in secondary metal resource recovery
2020, vol. 27, no. 12, pp. 1599-1617. doi: 10.1007/s12613-020-2175-0
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Improve titanate reduction by electro-deoxidation of Ca3Ti2O7 precursor in molten CaCl2
2020, vol. 27, no. 12, pp. 1618-1625. doi: 10.1007/s12613-020-2165-2
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Solid oxide membrane-assisted electrolytic reduction of Cr2O3 in molten CaCl2
2020, vol. 27, no. 12, pp. 1626-1634. doi: 10.1007/s12613-020-2141-x
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Towards a sustainable technology for production of extra-pure Ti metal: Electrolysis of sulfurized Ti(C,N) in molten CaCl2
2020, vol. 27, no. 12, pp. 1635-1643. doi: 10.1007/s12613-020-2162-5
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Electrochemistry of Hf(IV) in NaCl–KCl–NaF–K2HfF6 molten salts
2020, vol. 27, no. 12, pp. 1644-1649. doi: 10.1007/s12613-020-2083-3
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Electrochemical deposition of Nd and Nd–Fe alloy from Cu6Nd alloy in a NaCl–KCl–NdCl3 melt
2020, vol. 27, no. 12, pp. 1650-1656. doi: 10.1007/s12613-020-2130-0
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Electrochemical behavior and underpotential deposition of Sm on reactive electrodes (Al, Ni, Cu and Zn) in a LiCl–KCl melt
2020, vol. 27, no. 12, pp. 1657-1665. doi: 10.1007/s12613-020-2112-2
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High-value utilization of CO2 to synthesize sulfur-doped carbon nanofibers with excellent capacitive performance
2020, vol. 27, no. 12, pp. 1666-1677. doi: 10.1007/s12613-020-2120-2
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Recovery and separation of Fe and Mn from simulated chlorinated vanadium slag by molten salt electrolysis
2020, vol. 27, no. 12, pp. 1678-1686. doi: 10.1007/s12613-020-2140-y
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Direct electrochemical N-doping to carbon paper in molten LiCl‒KCl‒Li3N
2020, vol. 27, no. 12, pp. 1687-1694. doi: 10.1007/s12613-020-2026-z
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Electrochemical preparation of the Fe–Ni36 Invar alloy from a mixed oxides precursor in molten carbonates
2020, vol. 27, no. 12, pp. 1695-1702. doi: 10.1007/s12613-020-2169-y
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Controllable nitridation of Ta2O5 in molten salts for enhanced photocatalysis
2020, vol. 27, no. 12, pp. 1703-1710. doi: 10.1007/s12613-020-2050-z
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Nanosheet-stacked flake graphite for high-performance Al storage in inorganic molten AlCl3−NaCl salt
2020, vol. 27, no. 12, pp. 1711-1722. doi: 10.1007/s12613-020-2080-6
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Electrochemical properties of Ca–Pb electrode for calcium-based liquid metal batteries
2020, vol. 27, no. 12, pp. 1723-1729. doi: 10.1007/s12613-020-2150-9