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Volume 17 Issue 3
Jun.  2010
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Hai-tao Li, Bo-ping Zhang, Qian Zhang, Peng-peng Shang,  and Gao-lei Zhao, Microstructure, crystalline phase and electrical properties of Li0.06(Na0.5K0.5)0.94Nb(1-2x/5)MgxO3 lead-free piezoelectric ceramics, Int. J. Miner. Metall. Mater., 17(2010), No. 3, pp. 340-346. https://doi.org/10.1007/s12613-010-0316-6
Cite this article as:
Hai-tao Li, Bo-ping Zhang, Qian Zhang, Peng-peng Shang,  and Gao-lei Zhao, Microstructure, crystalline phase and electrical properties of Li0.06(Na0.5K0.5)0.94Nb(1-2x/5)MgxO3 lead-free piezoelectric ceramics, Int. J. Miner. Metall. Mater., 17(2010), No. 3, pp. 340-346. https://doi.org/10.1007/s12613-010-0316-6
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Microstructure, crystalline phase and electrical properties of Li0.06(Na0.5K0.5)0.94Nb(1-2x/5)MgxO3 lead-free piezoelectric ceramics

  • 通讯作者:

    Bo-ping Zhang    E-mail: bpzhang@.ustb.edu.cn

  • MgO-modified Li0.06(Na0.5K0.5)0.94NbO3 (L6NKN) lead-free piezoelectric ceramics were synthesized by normal sintering at a relatively low temperature of 1000℃. The crystalline phase, microstructure, and electrical properties of the ceramics were investigated with a special emphasis on the influence of MgO content. The addition of MgO effectively improves the sinterability of the L6NKN ceramics. X-ray diffraction analysis indicates that the morphotropic phase boundary (MPB) separating orthorhombic and tetragonal phases for the ceramics lies in the range of Mg doping content (x) from 0.3at% to 0.7at%. High electrical properties of the piezoelectric constant (d33=238 pC/N), planar electromechanical coupling coefficient (kp=41.5%), relative dielectric constant (εr=905), and remanent polarization (Pr=38.3 μC/cm2) are obtained from the specimen with x=0.5at%, which suggests that the Li0.06(Na0.5K0.5)0.94Nb(1-2x/5)MgxO3 (x=0.5at%) ceramic is a promising lead-free piezoelectric material.
  • Microstructure, crystalline phase and electrical properties of Li0.06(Na0.5K0.5)0.94Nb(1-2x/5)MgxO3 lead-free piezoelectric ceramics

    + Author Affiliations
    • MgO-modified Li0.06(Na0.5K0.5)0.94NbO3 (L6NKN) lead-free piezoelectric ceramics were synthesized by normal sintering at a relatively low temperature of 1000℃. The crystalline phase, microstructure, and electrical properties of the ceramics were investigated with a special emphasis on the influence of MgO content. The addition of MgO effectively improves the sinterability of the L6NKN ceramics. X-ray diffraction analysis indicates that the morphotropic phase boundary (MPB) separating orthorhombic and tetragonal phases for the ceramics lies in the range of Mg doping content (x) from 0.3at% to 0.7at%. High electrical properties of the piezoelectric constant (d33=238 pC/N), planar electromechanical coupling coefficient (kp=41.5%), relative dielectric constant (εr=905), and remanent polarization (Pr=38.3 μC/cm2) are obtained from the specimen with x=0.5at%, which suggests that the Li0.06(Na0.5K0.5)0.94Nb(1-2x/5)MgxO3 (x=0.5at%) ceramic is a promising lead-free piezoelectric material.
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