Abstract: Gangue existing states largely affect the high-temperature characteristics of iron ores. Using a micro-sintering method and scanning electron microscopy, the effects of gangue content, gangue type, and gangue size on the assimilation characteristics and fluidity of liquid phase of five different iron ores were analyzed in this study. Next, the mechanism based on the reaction between gangues and sintering materials was unraveled. The results show that, as the SiO₂ levels increase in the iron ores, the lowest assimilation temperature (LAT) decreases, whereas the index of fluidity of liquid phase (IFL) increases. Below 1.5wt%, Al₂O₃ benefits the assimilation reaction, but higher concentrations proved detrimental. Larger quartz particles increase the SiO₂ levels at the local reaction interface between the iron ore and CaO, thereby reducing the LAT. Quartz-gibbsite is more conductive to assimilation than kaolin. Quartz-gibbsite and kaolin gangues encourage the formation of liquid-phase low-Al₂O₃-SFCA with high IFL and high-Al₂O₃-SFCA with low IFL, respectively.