Hui Wang, Shang-gang Xiao, and Tao Zhang, Fabrication of nanoporous silver by de-alloying Cu-Zr-Ag amorphous alloys, Int. J. Miner. Metall. Mater., 23(2016), No. 7, pp. 835-843. https://doi.org/10.1007/s12613-016-1298-9
Cite this article as:
Hui Wang, Shang-gang Xiao, and Tao Zhang, Fabrication of nanoporous silver by de-alloying Cu-Zr-Ag amorphous alloys, Int. J. Miner. Metall. Mater., 23(2016), No. 7, pp. 835-843. https://doi.org/10.1007/s12613-016-1298-9
Hui Wang, Shang-gang Xiao, and Tao Zhang, Fabrication of nanoporous silver by de-alloying Cu-Zr-Ag amorphous alloys, Int. J. Miner. Metall. Mater., 23(2016), No. 7, pp. 835-843. https://doi.org/10.1007/s12613-016-1298-9
Citation:
Hui Wang, Shang-gang Xiao, and Tao Zhang, Fabrication of nanoporous silver by de-alloying Cu-Zr-Ag amorphous alloys, Int. J. Miner. Metall. Mater., 23(2016), No. 7, pp. 835-843. https://doi.org/10.1007/s12613-016-1298-9
Nanoporous silver (NPS) with a ligament size ranging from 15 to 40 nm was fabricated by de-alloying (Cu50Zr50)100-xAgx (x = 10at%, 20at%, 30at%, and 40at%) amorphous ribbons in a mixed aqueous solution of hydrofluoric (HF) acid and nitric acid under free corrosion conditions. Nanoporous silver ligaments and pore sizes were able to be fine-tuned through tailoring the chemical composition, corrosion conditions, and de-alloying time. The ligament size increases with an increase in Ag content and de-alloying time, but decreases with an increase in HF concentration. This phenomenon may be attributed to the dissolution of Zr/Cu and the diffusion, aggregation, nucleation, and recrystallization of Ag, leading to an oriented attachment of adjacent nanocrystals as revealed by TEM analysis.
Nanoporous silver (NPS) with a ligament size ranging from 15 to 40 nm was fabricated by de-alloying (Cu50Zr50)100-xAgx (x = 10at%, 20at%, 30at%, and 40at%) amorphous ribbons in a mixed aqueous solution of hydrofluoric (HF) acid and nitric acid under free corrosion conditions. Nanoporous silver ligaments and pore sizes were able to be fine-tuned through tailoring the chemical composition, corrosion conditions, and de-alloying time. The ligament size increases with an increase in Ag content and de-alloying time, but decreases with an increase in HF concentration. This phenomenon may be attributed to the dissolution of Zr/Cu and the diffusion, aggregation, nucleation, and recrystallization of Ag, leading to an oriented attachment of adjacent nanocrystals as revealed by TEM analysis.
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