留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 24 Issue 3
Mar.  2017
Turn off MathJax
目录
数据统计

分享

计量
  • 文章访问数:  551
  • HTML全文浏览量:  94
  • PDF下载量:  14
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2017  >  24(3): 316-323
Hong-pan Liu, Xiao-feng Huang, Li-ping Ma, Dan-li Chen, Zhi-biao Shang,  and Ming Jiang, Effect of Fe2O3 on the crystallization behavior of glass-ceramics produced from naturally cooled yellow phosphorus furnace slag, Int. J. Miner. Metall. Mater., 24(2017), No. 3, pp. 316-323. https://doi.org/10.1007/s12613-017-1410-9
Cite this article as:
Hong-pan Liu, Xiao-feng Huang, Li-ping Ma, Dan-li Chen, Zhi-biao Shang,  and Ming Jiang, Effect of Fe2O3 on the crystallization behavior of glass-ceramics produced from naturally cooled yellow phosphorus furnace slag, Int. J. Miner. Metall. Mater., 24(2017), No. 3, pp. 316-323. https://doi.org/10.1007/s12613-017-1410-9
shu
引用本文 PDF XML SpringerLink
研究论文

Effect of Fe2O3 on the crystallization behavior of glass-ceramics produced from naturally cooled yellow phosphorus furnace slag

  • Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650500, China

  • College of Resources and Environment, Yunnan Agricultural University, Kunming 650201, China

  • 通讯作者:

    Xiao-feng Huang    E-mail: hxfkmust@163.com

  • CaO-Al2O3-SiO2 (CAS) glass-ceramics were prepared via a melting method using naturally cooled yellow phosphorus furnace slag as the main raw material. The effects of the addition of Fe2O3 on the crystallization behavior and properties of the prepared glass-ceramics were studied by differential thermal analysis, X-ray diffraction, and scanning electron microscopy. The crystallization activation energy was calculated using the modified Johnson-Mehl-Avrami equation. The results show that the intrinsic nucleating agent in the yellow phosphorus furnace slag could effectively promote the crystallization of CAS. The crystallization activation energy first increased and then decreased with increasing amount of added Fe2O3. At 4wt% of added Fe2O3, the crystallization activation energy reached a maximum of 676.374 kJ·mol-1. The type of the main crystalline phase did not change with the amount of added Fe2O3. The primary and secondary crystalline phases were identified as wollastonite (CaSiO3) and hedenbergite (CaFe(Si2O6)), respectively.
    • Research Article

    Effect of Fe2O3 on the crystallization behavior of glass-ceramics produced from naturally cooled yellow phosphorus furnace slag

    + Author Affiliations
      Abstract
    • CaO-Al2O3-SiO2 (CAS) glass-ceramics were prepared via a melting method using naturally cooled yellow phosphorus furnace slag as the main raw material. The effects of the addition of Fe2O3 on the crystallization behavior and properties of the prepared glass-ceramics were studied by differential thermal analysis, X-ray diffraction, and scanning electron microscopy. The crystallization activation energy was calculated using the modified Johnson-Mehl-Avrami equation. The results show that the intrinsic nucleating agent in the yellow phosphorus furnace slag could effectively promote the crystallization of CAS. The crystallization activation energy first increased and then decreased with increasing amount of added Fe2O3. At 4wt% of added Fe2O3, the crystallization activation energy reached a maximum of 676.374 kJ·mol-1. The type of the main crystalline phase did not change with the amount of added Fe2O3. The primary and secondary crystalline phases were identified as wollastonite (CaSiO3) and hedenbergite (CaFe(Si2O6)), respectively.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(31)
    • [1]
      Z.S. Abisheva, E.G. Bochevskaya, A.N. Zagorodnyaya, T.A. Shabanova, and Z.B. Karshigina, Technology of phosphorus slag processing for preparation of precipitated silica, Theor. Found. Chem. Eng., 47(2013), No. 4, p. 428.
      [2]
      J. Zhou, Z. Shu, X.H. Hu, and Y.X. Wang, Direct utilization of liquid slag from phosphorus-smelting furnace to prepare cast stone as decorative building material, Constr. Build. Mater., 24(2010), No. 5, p. 811.
      [3]
      J.A. Bhat, M.C. Kundu, G.C. Hazra, G.H. Santra, and B. Mandal, Rehabilitating acid soils for increasing crop productivity through low-cost liming material, Sci. Total Environ., 408(2010), No. 20, p. 4346.
      [4]
      Z. Shu, J. Zhou, Y.X. Wang, and X.S. Lu, On-site preparation of opaque glass using liquid phosphorus slag, Earth Sci. J. China Univ. Geosci., 34(2009), No. 6, p. 1019.
      [5]
      X.H. Niu, Y.C. Wang, Y.H. Jiao, B.C. Li, and G.P. Luo, Thermodynamic analysis on crystallization of glass-ceramics prepared from blast furnace slag, Trans. Mater. Heat Treat., 36(2015), No. 1, p. 6.
      [6]
      Z.H. Yang, Q. Lin, S.C. Lu, Y. He, G.D. Liao, and Y. Ke, Effect of CaO/SiO2 ratio on the preparation and crystallization of glass-ceramics from copper slag, Ceram. Int., 40(2014), No. 5, p. 7297.
      [7]
      J.W. Cao and Z. Wang, Effect of Na2O and heat-treatment on crystallization of glass-ceramics from phosphorus slag, J. Alloys Compd., 557(2013), No. 25, p. 190.
      [8]
      Y. Zhao, D.F. Chen, Y.Y. Bi, and M.J. Long, Preparation of low cost glass-ceramics from molten blast furnace slag, Ceram. Int., 38(2012), No. 3, p. 2495.
      [9]
      L. Gan, C.X. Zhang, J.C. Zhou, and F.Q. Shangguan, Continuous cooling crystallization kinetics of a molten blast furnace slag, J. Non Cryst. Solids, 358(2012), No. 1, p. 20.
      [10]
      H.Y. Liu, H.X. Lu, D.L. Chen, H.L. Wang, H.L. Xu, and R. Zhang, Preparation and properties of glass-ceramics derived from blast-furnace slag by a ceramic-sintering process, Ceram. Int., 35(2009), No. 8, p. 3181.
      [11]
      Z.H. Yang, Q. Lin, J.X. Xia, Y. He, G.D. Liao, Y. Ke, Preparation and crystallization of glass-ceramics derived from iron-rich copper slag, J. Alloys Compd., 574(2013), p. 354.
      [12]
      C.J. Liu, P.Y. Shi, D.Y. Zhang, and M.F. Jiang, Development of glass ceramics made from ferrous tailings and slag in China, J. Iron Steel Res. Int., 14(2007), No. 2, p. 73.
      [13]
      T. Toya, A. Nakamura, Y. Kameshima, A. Nakajima, and K. Okada, Glass-ceramics prepared from sludge generated by a water purification plant, Ceram. Int., 33(2007), No. 4, p. 573.
      [14]
      M. Rezvani, B. Eftekhari-Yekta, M. Solati-Hashjin, and V.K. Marghussian, Effect of Cr2O3, Fe2O3 and TiO2 nucleants on the crystallization behaviour of SiO2-Al2O3-CaO-MgO(R2O) glass-ceramics, Ceram. Int., 31(2005), No. 1, p. 75.
      [15]
      A.A. Omar, A.W.A. El-Shennawi, and G.A. Khater, The role of Cr2O3, LiF and their mixtures on crystalline phase formation and microstructure in Ba, Ca, Mg aluminosilicate glass, Br. Ceram. Trans. J., 90(1991), No. 6, p. 179.
      [16]
      G.A. Khater and E.M.A. Hamzawy, Effect of different nucleation catalysts on the crystallization behaviour, within the CaO-MgO-Al2O3-SiO2 system, Silic. Indus., 73(2008), No. 7-8, p. 103.
      [17]
      P. Alizadeh, B.E. Yekta, and A. Gervei, Effect of Fe2O3 addition on the sinterability and machinability of glass-ceramics in the system MgO-CaO-SiO2-P2O5, J. Eur. Ceram. Soc., 24(2004), No. 13, p. 3529.
      [18]
      S.M. Wang, Effects of Fe on crystallization and properties of a new high infrared radiance glass-ceramics, Environ. Sci. Technol., 44(2010), No. 12, p. 4816.
      [19]
      Z.J. Wang, W. Ni, K.Q. Li, X.Y. Huang, and L.P. Zhu, Crystallization characteristics of iron-rich glass ceramics prepared from nickel slag and blast furnace slag, Int. J. Miner. Metall. Mater., 18(2011), No. 4, p. 455.
      [20]
      Z.J. Yang, Y. Li, D.Q. Cang, M.L. Diao, and W.B. Guo, The influence of Fe2+ and Fe3+ on crystallization of CaO-Al2O3-SiO2-MgO system glass-ceramics, Mater. Sci. Technol., 20(2012), No. 2, p. 45.
      [21]
      M. Avrami, Kinetics of phase change:I. General theory, J. Chem. Phys., 7(1939), No. 12, p. 1103.
      [22]
      W.A. Johnson and R.F. Mehl, Reaction kinetics in processes of nucleation and growth, Trans. AIME., 135(1939), p. 369.
      [23]
      H.E. Kissinger, Variation of peak temperature with heating rate in differential thermal analysis, J. Res. Nat. Bur. Stand., 57(1956), No. 4, p. 2172.
      [24]
      H.E. Kissinger, Reaction kinetics in differential thermal analysis, Anal. Chem., 29(1957), No. 11, p. 1702.
      [25]
      X. Z. Ren, W. Zhang, Y. Zhang, P.X. Zhang, and J.H. Liu, Effects of Fe2O3 content on microstructure and mechanical properties of CaO-Al2O3-SiO2 system, Trans. Nonferrous Met. Soc. China, 25(2015), No. 1, p. 137.
      [26]
      H.X. Li, B.W. Li, X.F. Zhang, X.L. Jia, M. Zhao, and Z.W. Zhang, Influence of Fe2O3 on the microstructure and properties of the nanocrystalline tailing-based glass-ceramics, J. Synth. Cryst., 45(2016), No. 1, p. 176.
      [27]
      B. Xu, J.W. Cao, and K.M. Liang, Influence of Fe2O3 on the crystallization and foaming of CaO-Al2O3-SiO2 glass-ceramics, Rare Met. Mater. Eng., 40(2011), Suppl. 1, p. 15.
      [28]
      Z.J. Wang, W. Ni, Y. Jia, L.P. Zhu, and X.Y. Huang, Crystallization behavior of glass ceramics prepared from the mixture of nickel slag, blast furnace slag and quartz sand, J. Non Cryst. Solids, 356(2011), No. 31-32, p. 1554.
      [29]
      K. Singh and D. Bahadur, Characterization of SiO2-Na2O-Fe2O3-CaO-P2O5-B2O3 glass ceramics, J. Mater. Sci. Mater. Med., 10(1999), No. 8, p. 481.
      [30]
      Y.L. Tian, New Glass Technology, China Light Industry Press, Beijing, 2013, p. 86.
      [31]
      B. Li, L.H. Wen, and C. Ma, Effect of Fe2O3 on properties of CaO-SiO2 glasses and glass-ceramics, J. Ceram., 28(2007), No. 2, p. 99.
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计