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Volume 24 Issue 9
Sep.  2017
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文章导航 >  矿物冶金与材料学报（英文）  > 2017  >  24(9): 1043-1051
J. Celina Selvakumari, M. Ahila, M. Malligavathy,  and D. Pathinettam Padiyan, Structural, morphological, and optical properties of tin(IV) oxide nanoparticles synthesized using Camellia sinensis extract:a green approach, Int. J. Miner. Metall. Mater., 24(2017), No. 9, pp. 1043-1051. https://doi.org/10.1007/s12613-017-1494-2
Cite this article as:
J. Celina Selvakumari, M. Ahila, M. Malligavathy,  and D. Pathinettam Padiyan, Structural, morphological, and optical properties of tin(IV) oxide nanoparticles synthesized using Camellia sinensis extract:a green approach, Int. J. Miner. Metall. Mater., 24(2017), No. 9, pp. 1043-1051. https://doi.org/10.1007/s12613-017-1494-2
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研究论文

Structural, morphological, and optical properties of tin(IV) oxide nanoparticles synthesized using Camellia sinensis extract:a green approach

  • Department of Physics, Manonmaniam Sundaranar University, Tirunelveli 627012, Tamil Nadu, India

  • 通讯作者:

    D. Pathinettam Padiyan    E-mail: dppadiyan@msuniv.ac.in

  • Tin oxide (SnO2) nanoparticles were cost-effectively synthesized using nontoxic chemicals and green tea (Camellia sinensis) extract via a green synthesis method. The structural properties of the obtained nanoparticles were studied using X-ray diffraction, which indicated that the crystallite size was less than 20 nm. The particle size and morphology of the nanoparticles were analyzed using scanning electron microscopy and transmission electron microscopy. The morphological analysis revealed agglomerated spherical nanoparticles with sizes varying from 5 to 30 nm. The optical properties of the nanoparticles' band gap were characterized using diffuse reflectance spectroscopy. The band gap was found to decrease with increasing annealing temperature. The O vacancy defects were analyzed using photoluminescence spectroscopy. The increase in the crystallite size, decreasing band gap, and the increasing intensities of the UV and visible emission peaks indicated that the green-synthesized SnO2 may play future important roles in catalysis and optoelectronic devices.
    • Research Article

    Structural, morphological, and optical properties of tin(IV) oxide nanoparticles synthesized using Camellia sinensis extract:a green approach

    + Author Affiliations
      Abstract
    • Tin oxide (SnO2) nanoparticles were cost-effectively synthesized using nontoxic chemicals and green tea (Camellia sinensis) extract via a green synthesis method. The structural properties of the obtained nanoparticles were studied using X-ray diffraction, which indicated that the crystallite size was less than 20 nm. The particle size and morphology of the nanoparticles were analyzed using scanning electron microscopy and transmission electron microscopy. The morphological analysis revealed agglomerated spherical nanoparticles with sizes varying from 5 to 30 nm. The optical properties of the nanoparticles' band gap were characterized using diffuse reflectance spectroscopy. The band gap was found to decrease with increasing annealing temperature. The O vacancy defects were analyzed using photoluminescence spectroscopy. The increase in the crystallite size, decreasing band gap, and the increasing intensities of the UV and visible emission peaks indicated that the green-synthesized SnO2 may play future important roles in catalysis and optoelectronic devices.
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    • [1]
      H. Sharghi, S. Ebrahimpourmoghaddam, R. Memarzadeh, and S. Javadpour, Tin oxide nanoparticles (NP-SnO2):preparation, characterization and their catalytic application in the Knoevenagel condensation, J. Iran. Chem. Soc., 10(2013), No. 1, p. 141.
      [2]
      R.S. Kalubarme, J.Y. Lee, and C.J. Park, Carbon encapsulated tin oxide nanocomposites:An efficient anode for high performance sodium-ion batteries, ACS Appl. Mater. Interfaces, 7(2015), No. 31, p. 17226.
      [3]
      M. D'Arienzo, D. Cristofori, R. Scotti, and F. Morazzoni, New insights in the SnO2 sensing mechanism based on the properties of shape controlled tin oxide nanoparticles, Chem. Mater., 25(2013), No. 18, p. 3675.
      [4]
      H. Chae, D. Song, Y.G. Lee, T. Son, W. Cho, Y.B. Pyun, T.Y. Kim, J.H. Lee, F.F. Santiago, J. Bisquert, and Y.S. Kang, Chemical effects of tin oxide nanoparticles in polymer electrolytes-based dye-sensitized solar cells, J. Phys. Chem. C, 118(2014), No. 30, p. 16510.
      [5]
      S. Sudhaparimala, A. Gnanamani, and A.B. Mandal, Green synthesis of tin based nanomedicine:Assessment of microstructure and surface property, Am. J. Nanosci. Nanotechnol., 2(2014), No. 4, p. 75.
      [6]
      H.S. Desarkar, P. Kumbhakar, and A.K. Mitra, Optical properties of tin oxide nanoparticles prepared by laser ablation in water:Influence of laser ablation time duration and laser fluence, Mater. Charact., 73(2012), p. 158.
      [7]
      Q.Q. Zhao, L.S. Ma, Q. Zhang, C.G. Wang, and X.J. Xu, SnO2-based nanomaterials:Synthesis and application in lithium-ion batteries and supercapacitors, J. Nanomater., 2015(2015), art. No. 850147.
      [8]
      S. Sagadevan, Preparation, structural and electrical properties of tin oxide nanoparticles, J. Nanomater. Mol. Nanotechnol., 4(2015), No. 1, p. 889.
      [9]
      S. Nilavazhagani, S. Muthukumaran, and M. Ashokkumar, Microstructural and band gap exploration on Ni-doped SnO2 nanoparticles co-doped with Cu, J. Mater. Sci. Mater. Electron., 26(2015), No. 6, p. 3989.
      [10]
      V. Juttukonda, R.L. Paddock, J.E. Raymond, D. Denomme, A.E. Richardson, L.E. Slusher, and B.D. Fahlman, Facile synthesis of tin oxide nanoparticles stabilized by dendritic polymers, J. Am. Chem. Soc., 128(2006), No. 2, p. 420.
      [11]
      S.C. Wang and M.O. Shaikh, A room temperature H2 sensor fabricated using high performance Pt-loaded SnO2 nanoparticles, Sensors, 15(2015), No. 6, p. 14286.
      [12]
      A. Bhattacharjee and Md. Ahmaruzzaman, Photocatalytic-degradation and reduction of organic compounds using SnO2 quantum dots (via a green route) under direct sunlight, RSC Adv., 5(2015), No. 81, p. 66122.
      [13]
      A.R. Kamali and D.J. Fray, Tin-based materials as advanced anode materials for lithium ion batteries:A review, Rev. Adv. Mater. Sci., 27(2011), No. 1, p. 14.
      [14]
      Y.H. Zhou, J.W. Shim, C. Fuentes-Hernandez, A. Sharma, K.A. Knauer, A.J. Giordano, S.R. Marder, and B. Kippelen, Direct correlation between work function of indium-tin-oxide electrodes and solar cell performance influenced by ultraviolet irradiation and air exposure, Phys. Chem. Chem. Phys., 14(2012), No. 34, p. 12014.
      [15]
      S. Gnanam and V. Rajendran, Synthesis of tin oxide nanoparticles by sol-gel process:effect of solvents on the optical properties, J. Sol-Gel Sci. Technol., 53(2010), No. 3, p. 555.
      [16]
      K.C. Song and Y. Kang, Preparation of high surface area tin oxide powders by a homogeneous precipitation method, Mater. Lett., 42(2000), No. 5, p. 283.
      [17]
      G.E. Patil, D.D. Kajale, V.B. Gaikwad, and G.H. Jain, Preparation and characterization of SnO2 nanoparticles by hydrothermal route, Int. Nano Lett., 2(2012), p. 17.
      [18]
      Z.L. He and J.Q. Zhou, Synthesis, characterization and activity of tin oxide nanoparticles:Influence of solvothermal time on photocatalytic degradation of rhodamine B, Mod. Res. Catal., 2(2013), p. 13.
      [19]
      A. Diallo, E. Manikandan, V. Rajendran, and M. Maaza, Physical and enhanced photocatalytic properties of green synthesized SnO2 nanoparticles via Aspalathus linearis, J. Alloys Compd., 681(2016), p. 561.
      [20]
      E. Haritha, S.M. Roopan, G. Madhavi, G. Elango, N.A. Al-Dhabi, and M.V. Arasu, Green chemical approach towards the synthesis of SnO2 NPs in argument with photocatalytic degradation of diazo dye and its kinetic studies, J. Photochem. Photobiol. B, 162(2016), p. 441.
      [21]
      L. Fu, Y. Zheng, Q. Ren, A. Wang, and B. Deng, Green biosynthesis of SnO2 nanoparticles by plectranthus amboinicus leaf extract their photocatalytic activity toward rhodamine B degradation, J. Ovonic Res., 11(2015), No. 1, p. 21.
      [22]
      A. Bhattacharjee and M. Ahmaruzzaman, Facile synthesis of SnO2 quantum dots and its photocatalytic activity in the degradation of eosin Y dye:A green approach, Mater. Lett., 139(2015), p. 418.
      [23]
      Y.H. Zheng, L. Fu, F.G. Han, A.W. Wang, W. Cai, J.P. Yu, J. Yang, and F. Peng, Green biosynthesis and characterization of zinc oxide nanoparticles using Corymbia citriodora leaf extract and their photocatalytic activity, Green Chem. Lett. Rev., 8(2015), No. 2, p. 56.
      [24]
      N. Srivastava and M. Mukhopadhyay, Biosynthesis of SnO2 nanoparticles using bacterium Erwinia herbicola and their photocatalytic activity for degradation of dyes, Ind. Eng. Chem. Res., 53(2014), No. 36, p. 13971.
      [25]
      Y.H. Zheng, A.W. Wang, W. Cai, Z. Wan, F. Peng, Z. Liu, and L. Fu, Hydrothermal preparation of reduced graphene oxide-silver nanocomposite using Plectranthus amboinicus leaf extract and its electrochemical performance, Enzyme Microb. Technol., 95(2016), p. 112.
      [26]
      S. Begum, Th.B. Devi, and M. Ahmaruzzaman, L-lysine monohydrate mediated facile and environment friendly synthesis of SnO2 nanoparticles and their prospective applications as a catalyst for the reduction and photodegradation of aromatic compounds, J. Environ. Chem. Eng., 4(2016), No. 3, p. 2976.
      [27]
      G. Elango and S.M. Roopan, Efficacy of SnO2 nanoparticles toward photocatalytic degradation of methylene blue dye, J. Photochem. Photobiol. B, 155(2016), p. 34.
      [28]
      L. Fu and Z.X. Fu, Plectranthus amboinicus leaf extract-assisted biosynthesis of ZnO nanoparticles and their photocatalytic activity, Ceram. Int., 41(2015), No. 2, p. 2492.
      [29]
      A. Dasgupta and K. Klein, Antioxidants in Food, Vitamins and Supplements:Prevention and Treatment of Disease, Elsevier, p. 239.
      [30]
      H. Nagabhushana, R.B. Basavaraj, B.D. Prasad, S.C. Sharma, H.B. Premkumar, Udayabhanu, and G.R. Vijayakumar, Facile EGCG assisted green synthesis of raspberry shaped CdO nanoparticles, J. Alloys Compd., 669(2016), p. 232.
      [31]
      P. Sutradhar and M. Saha, Synthesis of zinc oxide nanoparticles using tea leaf extract and its application for solar cell, Bull. Mater. Sci., 38(2015), No. 3, p. 653.
      [32]
      P. Sutradhar, M. Saha, and D. Maiti, Microwave synthesis of copper oxide nanoparticles using tea leaf and coffee powder extracts and its antibacterial activity, J. Nanostruct. Chem., 4(2014), p. 86.
      [33]
      J. Wang, H.Q. Fan, H.W. Yu, and X. Wang, Synthesis and optical properties of SnO2 structures with different morphologies via hydrothermal method, J. Mater. Eng. Perform., 24(2015), No. 9, p. 3426.
      [34]
      J. Nemeth, I. Dekany, K. Suvegh, T. Marek, Z. Klencsar, A. Vertes, and J.H. Fendler, Preparation and structural properties of tin oxide-montmorillonite nanocomposites, Langmuir, 19(2003), No. 9, p. 3762.
      [35]
      M.J. Han, K. Jiang, J.Z. Zhang, W.L. Yu, Y.W. Li, Z.G. Hu, and J.H. Chu, Structural, electronic band transition and optoelectronic properties of delafossite CuGa1-xCrxO2(0 ≤ x ≤ 1) solid solution films grown by sol-gel method, J. Mater. Chem., 22(2012), No. 35, p. 18463.
      [36]
      Ayeshamariam, S. Ramalingam, M. Bououdina, and M. Jayachandran, Preparation and characterizations of SnO2 nanopowder and spectroscopic (FT-IR, FT-Raman, UV-Visible and NMR) analysis using HF and DFT calculations, Spectrochim. Acta Part A, 118(2014), p. 1135.
      [37]
      S.A. Ansari and M.H. Cho, Highly visible light responsive, narrow band gap TiO2 nanoparticles modified by elemental red phosphorus for photocatalysis and photoelectrochemical applications, Sci. Rep., 6(2016), art. No. 25405.
      [38]
      A. Kar, S. Kundu, and A. Patra, Surface defect-related luminescence properties of SnO2 nanorods and nanoparticles, J. Phys. Chem. C, 115(2011), No. 1, p. 118.
      [39]
      B. Liu, C.W. Cheng, R. Chen, Z.X. Shen, H.J. Fan, and H.D. Sun, Fine structure of ultraviolet photoluminescence of tin oxide nanowires, J. Phys. Chem. C, 114(2010), No. 8, p. 3407.
      [40]
      W. Chen, D. Ghosh, and S.W. Chen, Large-scale electrochemical synthesis of SnO2 nanoparticles, J. Mater. Sci., 43(2008), No. 15, p. 5291.
      [41]
      E.R. Viana, J.C. González, G.M. Ribeiro, and A.G. de Oliveira, Photoluminescence and high-temperature persistent photoconductivity experiments in SnO2 nanobelts, J. Phys. Chem. C, 117(2013), No. 15, p. 7844.
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