Effects and mechanisms of fluorite on the co-reduction of blast furnace dust and seaside titanomagnetite

Tian-yang Hu; Ti-chang Sun; Jue Kou; Chao Geng; Yong-qiang Zhao

doi:10.1007/s12613-017-1512-4

Volume 24 Issue 11

Nov. 2017

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文章导航 > 矿物冶金与材料学报（英文） > 2017 > 24(11): 1201-1210

Tian-yang Hu, Ti-chang Sun, Jue Kou, Chao Geng, and Yong-qiang Zhao, Effects and mechanisms of fluorite on the co-reduction of blast furnace dust and seaside titanomagnetite, Int. J. Miner. Metall. Mater., 24(2017), No. 11, pp. 1201-1210. https://doi.org/10.1007/s12613-017-1512-4

Cite this article as:

Tian-yang Hu, Ti-chang Sun, Jue Kou, Chao Geng, and Yong-qiang Zhao, Effects and mechanisms of fluorite on the co-reduction of blast furnace dust and seaside titanomagnetite, Int. J. Miner. Metall. Mater., 24(2017), No. 11, pp. 1201-1210. https://doi.org/10.1007/s12613-017-1512-4

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研究论文

Effects and mechanisms of fluorite on the co-reduction of blast furnace dust and seaside titanomagnetite

School of Civil and Resources Engineering, University of Science and Technology Beijing, Beijing 100083, China
Key Laboratory of Ministry of Education of China for Efficient Mining and Safety of Metal Mines, Beijing 100083, China

通讯作者:
Ti-chang Sun E-mail: suntc@ces.ustb.edu.cn

中文摘要

The co-reduction roasting and grinding magne -tic separation of seaside titanomagnetite and blast furnace dust was investigated with and without fluorite addition at a reduction roasting temperature of 1250℃ for 60 min, a grinding fineness of -43 μm accounting for 69.02wt% of the total, and a low-intensity magnetic field strength of 151 kA/m. The mineral composition, microstructure, and state of the roasted products were analyzed, and the concentrations of CO and CO₂ were analyzed in the co-reduction roasting. Better results were achieved with a small fluorite dosage (≤ 4wt%) in the process of co-reduction. In addition, F^- was found to reduce the melting point and viscosity of the slag phase because of the high content of aluminate and silicate minerals in the blast furnace dust. The low moisture content of the blast furnace dust and calcic minerals inhibited the hydrolysis of CaF₂ and the loss of F^-. Compared with the blast furnace dust from Chengdeng, the blast furnace dusts from Jiugang and Jinxin inhibited the diffusion of F^- when used as reducing agents, leading to weaker effects of fluorite.

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Research Article

Effects and mechanisms of fluorite on the co-reduction of blast furnace dust and seaside titanomagnetite

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Abstract

Abstract

The co-reduction roasting and grinding magne -tic separation of seaside titanomagnetite and blast furnace dust was investigated with and without fluorite addition at a reduction roasting temperature of 1250℃ for 60 min, a grinding fineness of -43 μm accounting for 69.02wt% of the total, and a low-intensity magnetic field strength of 151 kA/m. The mineral composition, microstructure, and state of the roasted products were analyzed, and the concentrations of CO and CO₂ were analyzed in the co-reduction roasting. Better results were achieved with a small fluorite dosage (≤ 4wt%) in the process of co-reduction. In addition, F^- was found to reduce the melting point and viscosity of the slag phase because of the high content of aluminate and silicate minerals in the blast furnace dust. The low moisture content of the blast furnace dust and calcic minerals inhibited the hydrolysis of CaF₂ and the loss of F^-. Compared with the blast furnace dust from Chengdeng, the blast furnace dusts from Jiugang and Jinxin inhibited the diffusion of F^- when used as reducing agents, leading to weaker effects of fluorite.
- seaside titanomagnetite;
- blast furnace dust;
- co-reduction roasting;
- fluorite;
- mechanisms

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Effects and mechanisms of fluorite on the co-reduction of blast furnace dust and seaside titanomagnetite

中文摘要

Effects and mechanisms of fluorite on the co-reduction of blast furnace dust and seaside titanomagnetite

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