Solid FeS lubricant:a possible alternative to MoS2 for Cu-Fe-based friction materials

Tao Peng, Qing-zhi Yan, Xiao-lu Zhang, Xiao-jiao Shi

分享

计量
  • 文章访问数:  578
  • HTML全文浏览量:  141
  • PDF下载量:  25
  • 被引次数: 0

目录

HTML全文

  • 参考文献(24)

资源附件(0)
参考文献(24)
相关文章
施引文献

Cite this article as:

Tao Peng, Qing-zhi Yan, Xiao-lu Zhang, and Xiao-jiao Shi, Solid FeS lubricant:a possible alternative to MoS2 for Cu-Fe-based friction materials, Int. J. Miner. Metall. Mater., 24(2017), No. 11, pp.1278-1283. https://dx.doi.org/10.1007/s12613-017-1520-4
Tao Peng, Qing-zhi Yan, Xiao-lu Zhang, and Xiao-jiao Shi, Solid FeS lubricant:a possible alternative to MoS2 for Cu-Fe-based friction materials, Int. J. Miner. Metall. Mater., 24(2017), No. 11, pp.1278-1283. https://dx.doi.org/10.1007/s12613-017-1520-4
shu
引用本文 PDF XML SpringerLink
研究论文 Open Access

Solid FeS lubricant:a possible alternative to MoS2 for Cu-Fe-based friction materials

  • Laboratory of Special Ceramics and Powder Metallurgy, University of Science and Technology Beijing, Beijing 100083, China

基金项目: 

This work was financially supported by the National Natural Science Foundation of China (No. 51572026).

    通信作者:

    Qing-zhi Yan E-mail: qzyan@ustb.edu.cn

中文摘要

Molybdenum disulfide (MoS2) is one of the most commonly used solid lubricants for Cu-Fe-based friction materials. Nevertheless, MoS2 reacts with metal matrices to produce metal sulfides (e.g., FeS) and Mo during sintering, and the lubricity of the composite may be related to the generation of FeS. Herein, the use of FeS as an alternative to MoS2 for producing Cu-Fe-based friction materials was investigated. According to the reaction principle of thermodynamics, two composites-one with MoS2 (Fe-Cu-MoS2 sample) and the other with FeS (FeS-Cu2S-Cu-Fe-Mo sample), were prepared and their friction behaviors and mechanical properties were compared. The results showed that MoS2 reacted with the Cu-Fe matrix to produce FeS, metallic ternary sulfides, and Mo when sintered at 1050℃. The MoS2-Cu-Fe and FeS-Cu2S-Cu-Fe-Mo samples thereby exhibited similar characteristics with respect to phase composition, density, hardness, and tribological behaviors. Micrographs of the worn surfaces revealed that the stable friction regime for both composites stemmed from the iron sulfides friction layers rather than from the molybdenum sulfides layers.

 

Research Article Open Access

Solid FeS lubricant:a possible alternative to MoS2 for Cu-Fe-based friction materials

Author Affilications

    • Laboratory of Special Ceramics and Powder Metallurgy, University of Science and Technology Beijing, Beijing 100083, China

  • Funds: 

    This work was financially supported by the National Natural Science Foundation of China (No. 51572026).

  • Received: 12 March 2017; Revised: 22 June 2017; Accepted: 24 June 2017;
Molybdenum disulfide (MoS2) is one of the most commonly used solid lubricants for Cu-Fe-based friction materials. Nevertheless, MoS2 reacts with metal matrices to produce metal sulfides (e.g., FeS) and Mo during sintering, and the lubricity of the composite may be related to the generation of FeS. Herein, the use of FeS as an alternative to MoS2 for producing Cu-Fe-based friction materials was investigated. According to the reaction principle of thermodynamics, two composites-one with MoS2 (Fe-Cu-MoS2 sample) and the other with FeS (FeS-Cu2S-Cu-Fe-Mo sample), were prepared and their friction behaviors and mechanical properties were compared. The results showed that MoS2 reacted with the Cu-Fe matrix to produce FeS, metallic ternary sulfides, and Mo when sintered at 1050℃. The MoS2-Cu-Fe and FeS-Cu2S-Cu-Fe-Mo samples thereby exhibited similar characteristics with respect to phase composition, density, hardness, and tribological behaviors. Micrographs of the worn surfaces revealed that the stable friction regime for both composites stemmed from the iron sulfides friction layers rather than from the molybdenum sulfides layers.

 

    HTML全文
    • 资源附件(0)

    • 参考文献(24)

    参考文献(24)

  • R.M. German, Powder Metallurgy and Particulate Materials Processing:The Processes, Materials, Products, Properties, and Applications, Metal Powder Industries Federation, Princeton, 2005.

    G.M. Zhang, K.Q. Feng, Y. Li, and H.F. Yue, Effects of sintering process on preparing iron-based friction material directly from vanadium-bearing titanomagnetite concentrates, Mater. Des., 86(2015), p. 616.

    T. Ram Prabhu, V.K. Varma, and S. Vedantam, Effect of reinforcement type, size, and volume fraction on the tribological behavior of Fe matrix composites at high sliding speed conditions, Wear, 309(2014), No. 1-2, p. 247.

    W. Österle, C. Prietzel, H. Kloß, and A.I. Dmitriev, On the role of copper in brake friction materials, Tribol. Int., 43(2010), No. 12, p. 2317.

    X. Zhao, L.C. Guo, L. Zhang, T.T. Jia, C.G. Chen, J.J. Hao, H.P. Shao, Z.M. Guo, J. Luo, and J.B. Sun, Influence of nano-Al2O3-reinforced oxide-dispersion-strengthened Cu on the mechanical and tribological properties of Cu-based composites, Int. J. Miner. Metall. Mater., 23(2016), No. 12, p. 1444.

    A. Savan, E. Pflüger, P. Voumard, A. Schröer, and M. Simmonds, Modern solid lubrication:Recent developments and applications of MoS2, Lubr. Sci., 12(2000), No. 2, p. 185.

    A. Erdemir, Review of engineered tribological interfaces for improved boundary lubrication, Tribol. Int., 38(2005), No. 3, p. 249.

    F.J. Clauss, Solid Lubricants and Self-Lubricating Solids, Elsevier, Amsterdam, 2012, p. 78.

    M.H. Cho, J. Ju, S.J. Kim, and H. Jang, Tribological properties of solid lubricants (graphite, Sb2S3, MoS2) for automotive brake friction materials, Wear, 260(2006), No. 7-8, p. 855.

    S. Li, Y. Feng, S. Ling, X.B. Zhang, and J. Wang, Effect of sintering temperature on properties of Cu-MoS2 composite materials, Met. Funct. Mater., 15(2008), No. 1, p. 24.

    D. Uzunsoy, E. Kelesoglu, and Y. Erarslan, Contribution of MoS2 additives to the microstructure and properties of PM copper based brake material, Mater. Test., 51(2009), No. 5, p. 318.

    S. Dhanasekaran and R. Gnanamoorthy, Dry sliding friction and wear characteristics of Fe-C-Cu alloy containing molybdenum di sulphide, Mater. Des., 28(2007), No. 4, p. 1135.

    S. Dhanasekaran and R. Gnanamoorthy, Heat generation in Fe-C-Cu-MoS2-sintered spur gears under unlubricated conditions, Proc. Inst. Mech. Eng. Part J J. Eng. Tribol., 221(2007), No. 6, p. 645.

    S. Dhanasekaran and R. Gnanamoorthy, Microstructure, strength and tribological behavior of Fe-C-Cu-Ni sintered steels prepared with MoS2 addition, J. Mater. Sci., 42(2007), No. 12, p. 4659.

    H. Kato, M. Takama, Y. Iwai, K. Washida, and Y. Sasaki, Wear and mechanical properties of sintered copper-tin composites containing graphite or molybdenum disulfide, Wear, 255(2003), No. 1-6, p. 573.

    K.P. Senthil, K. Manisekar, E. Subramanian, and R. Narayanasamy, Dry sliding friction and wear characteristics of Cu-Sn alloy containing molybdenum disulfide, Tribol. Trans., 56(2013), No. 5, p. 857.

    K.P. Furlan, C. Binder, A.N. Klein, and J.D.B. de Mello, Thermal stability of the MoS2 phase in injection moulded 17-4 PH stainless steel, J. Mater. Res. Technol., 1(2012), No. 3, p. 134.

    K.P. Furlan, J.Z. de Assunção, G. Paz, C. Binder, and A.N. Klein, Sintering studies and microstructural evolution of Fe-MoS2 mixtures, Mater. Sci. Forum, 802(2014), p. 415.

    K.P. Furlan, P.B. Prates, T. Andrea dos Santos, M.V. Gouvêa Dias, H.T. Ferreira, J.B. Rodrigues Neto, and A.N. Klein, Influence of alloying elements on the sintering thermodynamics, microstructure and properties of Fe-MoS2 composites, J. Alloys Compd., 652(2015), p. 450.

    J.S. Han, J.H. Jia, J.J. Lu, and J.B. Wang, High temperature tribological characteristics of Fe-Mo-based self-lubricating composites, Tribol. Lett., 34(2009), No. 3, p. 193.

    T. Peng, Q.Z. Yan, Y. Zhang, X.J. Shi, and M.Y. Ba, Low-cost solid FeS lubricant as a possible alternative to MoS2 for producing Fe-based friction materials, Int. J. Miner. Metall. Mater., 24(2017), No. 1, p. 115.

    Y. Wang, Q.Z. Yan, F.F. Zhang, C.C. Ge, X.L. Zhang, and H.Q. Zhao, Sintering behavior of Cr in different atmospheres and its effect on the microstructure and properties of copper-based composite materials, Int. J. Miner. Metall. Mater., 20(2013), No. 12, p. 1208.

    P.R. Subramanlan, L. Kacprza, and W.W. Scott, Binary Alloy Phase Diagrams, American Society for Metals, Metals Park, OH, 1986.

    J. Chen, P. Yao, and X. Xiong, The behaviors of MoS2 in the sintering process of Fe-based friction materials, Non Met. Mines, 26(2003), No. 4, p. 50.
    • 相关文章
    施引文献

Relative Articles

Int. J. Miner. Metall. Mater., 2013, 20(6): 541-548.

PDF View details

Le-yu Zhou, Lei Wu, Ya-zheng Liu, Xiao-jie Cheng, Jin-hong Sun. Microstructure and texture evolution of cold-rolled deep-drawing steel sheet during annealing [J]. 矿物冶金与材料学报（英文版）. DOI: 10.1007/s12613-013-0763-y

View details

Int. J. Miner. Metall. Mater., 2011, 18(1): 24-34.

PDF View details

A. Ramírez-López, G. Soto-Cortés, J. González-Trejo, D. Muñoz-Negrón. Computational algorithms for simulating the grain structure formed on steel billets using cellular automaton and chaos theories [J]. 矿物冶金与材料学报（英文版）. DOI: 10.1007/s12613-011-0395-z

View details

Int. J. Miner. Metall. Mater., 2010, 17(5): 596-607.

PDF View details

A. Ramírez-López, G. Soto-Cortés, M. Palomar-Pardavé, M. A. Romero-Romo, R. Aguilar-López. Computational algorithms to simulate the steel continuous casting [J]. 矿物冶金与材料学报（英文版）. DOI: 10.1007/s12613-010-0362-0

View details

Int. J. Miner. Metall. Mater., 2008, 15(3): 330-334.

PDF View details

Jinqiao Xu, Yazheng Liu, Shumei Zhou. Computer simulation on the controlled cooling of 82B high-speed rod [J]. 矿物冶金与材料学报（英文版）. DOI: 10.1016/S1005-8850(08)60062-6

View details

Int. J. Miner. Metall. Mater., 2005, 12(6): 512-516.

PDF View details

Jinghong Sun, Yazheng Liu, Leyu Zhou. Simulation of annealing process effect on texture evolution of deep-drawing sheet Stl5 [J]. 矿物冶金与材料学报（英文版）.

View details

Int. J. Miner. Metall. Mater., 2003, 10(4): 55-60.

PDF View details

Yuhong Zhao, Zheng Chen, Xiaoling Li. Computer simulation of strain-induced morphological transformation of coherent precipitates [J]. 矿物冶金与材料学报（英文版）.

View details

Int. J. Miner. Metall. Mater., 2002, 9(5): 360-362.

PDF View details

Junxiang Lei, Yonglin Kang, Fangqin Qu. Prediction and determination of both friction coefficient and forming force on sheet metal deep-drawing [J]. 矿物冶金与材料学报（英文版）.

View details

Int. J. Miner. Metall. Mater., 1999, 6(3): 201-204.

PDF View details

Junxiang Lei, Yonglin Kang. Prediction and Control of both Wrinkle Limit and Fracture Limit on Cylindrical Cup Deep-drawing (Ⅱ) [J]. 矿物冶金与材料学报（英文版）.

View details

Int. J. Miner. Metall. Mater., 1998, 5(4): 237-240,250.

PDF View details

Junxiang Lei. Prediction and Control of Both Wrinkle Limit and Fracture Limit on Cylindrical Cup Deep-Drawing [J]. 矿物冶金与材料学报（英文版）.

View details

Int. J. Miner. Metall. Mater., 1995, 2(2): 84-91,108.

PDF View details

陈国良, 葛红林. Mg在Ni基高温合金中的晶界偏析行为和强化机制的计算机模拟 [J]. 矿物冶金与材料学报（英文版）.

View details

/

返回文章
返回

版权所有 © 《矿物冶金与材料学报（英文）》编辑部

地址: 北京市海淀区学院路30号邮政编码: 100083

电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

本系统由北京仁和汇智信息技术有限公司开发      百度统计