Effects of Na<sub>2</sub>SO<sub>4</sub> on iron and nickel reduction in a high-iron and low-nickel laterite ore

Xiao-ping Wang; Ti-chang Sun; Chao Chen; Jue Kou

doi:10.1007/s12613-018-1582-y

Volume 25 Issue 4

Apr. 2018

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文章导航 > 矿物冶金与材料学报（英文） > 2018 > 25(4): 383-390

Xiao-ping Wang, Ti-chang Sun, Chao Chen, and Jue Kou, Effects of Na₂SO₄ on iron and nickel reduction in a high-iron and low-nickel laterite ore, Int. J. Miner. Metall. Mater., 25(2018), No. 4, pp. 383-390. https://doi.org/10.1007/s12613-018-1582-y

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Xiao-ping Wang, Ti-chang Sun, Chao Chen, and Jue Kou, Effects of Na2SO4 on iron and nickel reduction in a high-iron and low-nickel laterite ore, Int. J. Miner. Metall. Mater., 25(2018), No. 4, pp. 383-390. https://doi.org/10.1007/s12613-018-1582-y

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研究论文

Effects of Na₂SO₄ on iron and nickel reduction in a high-iron and low-nickel laterite ore

Key Laboratory of Ministry of Education of China for Efficient Mining and Safety of Metal Mines, University of Science and Technology Beijing, Beijing 100083, China

通讯作者:
Ti-chang Sun E-mail: suntc@ces.ustb.edu.cn

中文摘要

This study investigates the reactions of Na₂SO₄ and its effects on iron and nickel reduction in the roasting of a high-iron and low-nickel laterite ore through gas composition, X-ray diffraction, and scanning electron microscope analyses. Results showed that a reduction reaction of Na₂SO₄ to SO₂ was performed with roasting up to 600℃. However, no clear influence on iron and nickel reductions appeared, because only a small amount of Na₂SO₄ reacted to produce SO₂. Na₂SO₄ reacted completely at 1000℃, mainly producing troilite and nepheline, which remarkably improves selective reduction of nickel. Furthermore, the production of low-melting-point minerals, including troilite and nepheline, accelerated nickel reduction and delayed iron reduction, which is attributed to the concurrent production of magnesium magnetite, whose structure is more stable than the structure of magnetite. Reduction reactions of Na₂SO₄ resulted in weakening of the reduction atmosphere, and the main product of Na₂SO₄ changed and delayed the reduction of iron. Eventually, iron metallization was effectively controlled during laterite ore reduction roasting, leading to iron mainly being found in wustite and high iron-containing olivine.

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Research Article

Effects of Na₂SO₄ on iron and nickel reduction in a high-iron and low-nickel laterite ore

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Abstract

Abstract

This study investigates the reactions of Na₂SO₄ and its effects on iron and nickel reduction in the roasting of a high-iron and low-nickel laterite ore through gas composition, X-ray diffraction, and scanning electron microscope analyses. Results showed that a reduction reaction of Na₂SO₄ to SO₂ was performed with roasting up to 600℃. However, no clear influence on iron and nickel reductions appeared, because only a small amount of Na₂SO₄ reacted to produce SO₂. Na₂SO₄ reacted completely at 1000℃, mainly producing troilite and nepheline, which remarkably improves selective reduction of nickel. Furthermore, the production of low-melting-point minerals, including troilite and nepheline, accelerated nickel reduction and delayed iron reduction, which is attributed to the concurrent production of magnesium magnetite, whose structure is more stable than the structure of magnetite. Reduction reactions of Na₂SO₄ resulted in weakening of the reduction atmosphere, and the main product of Na₂SO₄ changed and delayed the reduction of iron. Eventually, iron metallization was effectively controlled during laterite ore reduction roasting, leading to iron mainly being found in wustite and high iron-containing olivine.
- laterite ore;
- ferronickel;
- reduction;
- magnetic separation

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References

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Effects of Na₂SO₄ on iron and nickel reduction in a high-iron and low-nickel laterite ore

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Effects of Na₂SO₄ on iron and nickel reduction in a high-iron and low-nickel laterite ore

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