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Volume 25 Issue 9
Sep.  2018
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Song Chen, Zhen Sun,  and De-gui Zhu, Mineral-phase evolution and sintering behavior of MO-SiO2-Al2O3-B2O3 (M=Ca, Ba) glass-ceramics by low-temperature liquid-phase sintering, Int. J. Miner. Metall. Mater., 25(2018), No. 9, pp. 1042-1054. https://doi.org/10.1007/s12613-018-1655-y
Cite this article as:
Song Chen, Zhen Sun,  and De-gui Zhu, Mineral-phase evolution and sintering behavior of MO-SiO2-Al2O3-B2O3 (M=Ca, Ba) glass-ceramics by low-temperature liquid-phase sintering, Int. J. Miner. Metall. Mater., 25(2018), No. 9, pp. 1042-1054. https://doi.org/10.1007/s12613-018-1655-y
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研究论文

Mineral-phase evolution and sintering behavior of MO-SiO2-Al2O3-B2O3 (M=Ca, Ba) glass-ceramics by low-temperature liquid-phase sintering

  • 通讯作者:

    Song Chen    E-mail: schen2012@swjtu.edu.cn

  • In this work, network former SiO2 and network intermediate Al2O3 were introduced into typical low-melting binary compositions CaO·B2O3, CaO·2B2O3, and BaO·B2O3 via an aqueous solid-state suspension milling route. Accordingly, multiple-phase aluminosilicate glass-ceramics were directly obtained via liquid-phase sintering at temperatures below 950℃. On the basis of liquid-phase sintering theory, mineral-phase evolutions and glass-phase formations were systematically investigated in a wide MO-SiO2-Al2O3-B2O3 (M=Ca, Ba) composition range. The results indicate that major mineral phases of the aluminosilicate glass-ceramics are Al20B4O36, CaAl2Si2O8, and BaAl2Si2O8 and that the glass-ceramic materials are characterized by dense microstructures and excellent dielectric properties.
  • Research Article

    Mineral-phase evolution and sintering behavior of MO-SiO2-Al2O3-B2O3 (M=Ca, Ba) glass-ceramics by low-temperature liquid-phase sintering

    + Author Affiliations
    • In this work, network former SiO2 and network intermediate Al2O3 were introduced into typical low-melting binary compositions CaO·B2O3, CaO·2B2O3, and BaO·B2O3 via an aqueous solid-state suspension milling route. Accordingly, multiple-phase aluminosilicate glass-ceramics were directly obtained via liquid-phase sintering at temperatures below 950℃. On the basis of liquid-phase sintering theory, mineral-phase evolutions and glass-phase formations were systematically investigated in a wide MO-SiO2-Al2O3-B2O3 (M=Ca, Ba) composition range. The results indicate that major mineral phases of the aluminosilicate glass-ceramics are Al20B4O36, CaAl2Si2O8, and BaAl2Si2O8 and that the glass-ceramic materials are characterized by dense microstructures and excellent dielectric properties.
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