摘要:
A high-energy-density Li-ion battery with excellent rate capability and long cycle life was fabricated with a Ni-rich layered LiNi
0.8Mn
0.1Co
0.1O
2 cathode and SiO-C composite anode. The LiNi
0.8Mn
0.1Co
0.1O
2 and SiO-C exhibited excellent electrochemical performance in both half and full cells. Specifically, when integrated into a full cell configuration, a high energy density (280 Wh·kg
-1) with excellent rate capability and long cycle life was attained. At 0.5C, the full cell retained 80% of its initial capacity after 200 charge/discharge cycles, and 60% after 600 cycles, indicating robust structural tolerance for the repeated insertion/extraction of Li
+ ions. The rate performance showed that, at high rate of 1C and 2C, 96.8% and 93% of the initial capacity were retained, respectively. The results demonstrate strong potential for the development of high energy density Li-ion batteries for practical applications.