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Volume 26 Issue 3
Mar.  2019
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文章导航 >  矿物冶金与材料学报（英文）  > 2019  >  26(3): 350-359
Zhi-yuan Chen, Li-jun Wang, Xiao-jia Du, Zai-hong Sun, Fu-shen Li,  and Kuo-Chih Chou, Carbon deposition in porous nickel/yttria-stabilized zirconia anode under methane atmosphere, Int. J. Miner. Metall. Mater., 26(2019), No. 3, pp. 350-359. https://doi.org/10.1007/s12613-019-1744-6
Cite this article as:
Zhi-yuan Chen, Li-jun Wang, Xiao-jia Du, Zai-hong Sun, Fu-shen Li,  and Kuo-Chih Chou, Carbon deposition in porous nickel/yttria-stabilized zirconia anode under methane atmosphere, Int. J. Miner. Metall. Mater., 26(2019), No. 3, pp. 350-359. https://doi.org/10.1007/s12613-019-1744-6
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研究论文

Carbon deposition in porous nickel/yttria-stabilized zirconia anode under methane atmosphere

  • State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083, China

  • Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft, The Netherland

  • Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing 100083, China

  • Suzhou Huatsing Jingkun New Energy Technology Co., Ltd., Suzhou 215314, China

  • School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

  • 通讯作者:

    Li-jun Wang    E-mail: lijunwang@ustb.edu.cn

  • A commercial solid oxide fuel cell with a Ni/YSZ anode was characterized under a pure methane atmosphere. The amount of deposited carbon increased with an increase in temperature but decreased when the temperature exceeded 700℃. The reactivity of carbon decreased with increasing deposition temperature. Filamentous carbon was deposited from 400 to 600℃, whereas flake carbon was deposited at 700 and 800℃. With increasing temperature, the intensity ratio of the D band over the sum of the G and D bands was constant at the beginning and then decreased with the transformation of the carbon morphology. The crystallite size increased from 2.9 to 13 nm with increasing temperature. The results also indicated that the structure of the deposited carbon was better ordered with increasing deposition temperature. In comparison with pure Ni powders, the interaction between the YSZ substrate and Ni particles could not only modify the carbon deposition kinetics but also reduce the temperature effect on the structure and reactivity variation of carbon.
    • Research Article

    Carbon deposition in porous nickel/yttria-stabilized zirconia anode under methane atmosphere

    + Author Affiliations
      Abstract
    • A commercial solid oxide fuel cell with a Ni/YSZ anode was characterized under a pure methane atmosphere. The amount of deposited carbon increased with an increase in temperature but decreased when the temperature exceeded 700℃. The reactivity of carbon decreased with increasing deposition temperature. Filamentous carbon was deposited from 400 to 600℃, whereas flake carbon was deposited at 700 and 800℃. With increasing temperature, the intensity ratio of the D band over the sum of the G and D bands was constant at the beginning and then decreased with the transformation of the carbon morphology. The crystallite size increased from 2.9 to 13 nm with increasing temperature. The results also indicated that the structure of the deposited carbon was better ordered with increasing deposition temperature. In comparison with pure Ni powders, the interaction between the YSZ substrate and Ni particles could not only modify the carbon deposition kinetics but also reduce the temperature effect on the structure and reactivity variation of carbon.
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