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Volume 26 Issue 8
Aug.  2019
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Jian-guo Liu, Long-zhe Jin, Na Gao, Sheng-nan Ou, Shu Wang, and Wei-xiang Wang, A review on chemical oxygen supply technology within confined spaces: Challenges, strategies, and opportunities toward chemical oxygen generators (COGs), Int. J. Miner. Metall. Mater., 26(2019), No. 8, pp. 925-937. https://doi.org/10.1007/s12613-019-1809-6
Cite this article as:
Jian-guo Liu, Long-zhe Jin, Na Gao, Sheng-nan Ou, Shu Wang, and Wei-xiang Wang, A review on chemical oxygen supply technology within confined spaces: Challenges, strategies, and opportunities toward chemical oxygen generators (COGs), Int. J. Miner. Metall. Mater., 26(2019), No. 8, pp. 925-937. https://doi.org/10.1007/s12613-019-1809-6
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A review on chemical oxygen supply technology within confined spaces: Challenges, strategies, and opportunities toward chemical oxygen generators (COGs)

  • 通讯作者:

    Long-zhe Jin    E-mail: lzjin@ustb.edu.cn

  • Chemical oxygen generators (COGs) have been used worldwide in confined spaces as an emergency oxygen supply technology, mainly because they are independent and have a long shelf life. However, a number of challenges related to COGs remain unsolved, and a literature review of the current state of the technology is needed. First, the present article summarizes the basic information and applications of COGs, including their oxygen production mechanism, components, forming technology, and ignition system. Four current challenges encountered in applying COGs are discussed, along with the strategies adopted thus far to solve these problems, as found in the published literature. The literature survey reveals that, although much effort has been devoted to controlling the oxygen production rate and the heat output of COGs, the mechanism of producing toxic gases remains unclear and a reliable and safe ignition system has not been fully developed. Finally, future opportunities in the development of COGs are briefly listed.
  • Invited Review

    A review on chemical oxygen supply technology within confined spaces: Challenges, strategies, and opportunities toward chemical oxygen generators (COGs)

    + Author Affiliations
    • Chemical oxygen generators (COGs) have been used worldwide in confined spaces as an emergency oxygen supply technology, mainly because they are independent and have a long shelf life. However, a number of challenges related to COGs remain unsolved, and a literature review of the current state of the technology is needed. First, the present article summarizes the basic information and applications of COGs, including their oxygen production mechanism, components, forming technology, and ignition system. Four current challenges encountered in applying COGs are discussed, along with the strategies adopted thus far to solve these problems, as found in the published literature. The literature survey reveals that, although much effort has been devoted to controlling the oxygen production rate and the heat output of COGs, the mechanism of producing toxic gases remains unclear and a reliable and safe ignition system has not been fully developed. Finally, future opportunities in the development of COGs are briefly listed.
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    • [1]
      M.Y. Liu, Y. He, Z.G. Xu, and X.L. Bai, Key technologies of space station sun-tracking unit semi-physical test system. J. Astronaut., 40(2019), No. 5, p. 596.
      [2]
      K. Wang, H.Y. Huang, W.Z. Chen, and C.J. Zeng, Discussion on functional orientation and morphological evolution of urban underground stratification space. Chin. J. Underground Space Eng., 15(2019), No. 3, p. 652.
      [3]
      S. Wang, L.Z. Jin, Z.L. Han, Y.G. Li, S.N. Ou, N. Gao, and Z.L. Huang, Discharging performance of a forced-circulation ice thermal storage system for a permanent refuge chamber in an underground mine. Appl. Therm. Eng., 110(2017), p. 703.
      [4]
      Y. Du, W.M. Gai, and L.Z. Jin, A novel and green CO2 adsorbent developed with high adsorption properties in a coal mine refuge chamber, J. Cleaner Prod., 176(2018), p. 216.
      [5]
      Y. Du, W.M. Gai, L.Z. Jin, and S. Wang, Thermal comfort model analysis and optimization performance evaluation of a multifunctional ice storage air conditioning system in a confined mine refuge chamber, Energy, 141(2017), p. 964.
      [6]
      N. Gao, L.Z. Jin, L. Wang, and F. You, Research and application of oxygen supply system in Changcun Coal Mine refuge haven, J. China Coal Soc., 37(2012), No. 6, p. 1021.
      [7]
      N. Gao, J.G. Liu, L.Z. Jin, L. Lin, X. Huang, L. Zhou, and L.Y. Fan, Study and experiment of the system of oxygen supply and purification in the mine refuge space, J. China Coal Soc., 40(2015), No. 3, p. 616.
      [8]
      L.Z. Jin, S. Wang, S.C. Liu, and Z. Zhang, Development of a low oxygen generation rate chemical oxygen generator for emergency refuge spaces in underground mines, Combust. Sci. Technol., 187(2015), No. 8, p. 1229.
      [9]
      W.M. Gai, Y.F. Deng, and Y. Du, Adsorption properties of modified soda lime for carbon dioxide removal within the closed environment of a coal mine refuge chamber, Ind. Eng. Chem. Res., 55(2016), No. 40, p. 10794.
      [10]
      S. Wang, L.Z. Jin, S.C. Liu, and Z. Zhang, Research on application of chlorate oxygen candle to emergency refuge facility in non-coal mine, China Saf. Sci. J., 24(2014), No. 4, p. 166.
      [11]
      N. Gao, J. Li, L.Z. Jin, and Z. Zhang, Oxygen Supply System of Oxygen Candle in Emergency Rescue Space, Chinese Patent, Appl. 103362544A, 2013.
      [12]
      X.M. Zhou, X. Hu, S.H. Mao, Y. Zhang, and L. Mao, Test of oxygen candle as backup oxygen for manned space station, Space Med. Med. Eng., 26(2013), No. 5, p. 394.
      [13]
      X.M. Zhou, S.H. Mao, X. Hu, Y. Zhang, and L. Mao, Oxygen candle backup oxygen test for manned spacecraft, Manned Spaceflight, 19(2013), No. 3, p. 28.
      [14]
      V.N. Harwood, Chemical oxygen generators for business and utility aircraft, SAE Trans., 1971, p. 1494.
      [15]
      W. Ni, H. Yan, P.H. Wang, and Y.M. Yan, Oxygen supplying technologies in submarine cabin:A review, Ship Sci. Technol., 38(2016), No. 5, p. 138.
      [16]
      J.Y. Wang, C.G. Qi, and Z.Y. Wang, Study and application of sodium chlorate oxygen equipment on safety protection of pipeline construction in trench, Petrochem. Ind. Technol., 23(2016), No. 6, p. 47.
      [17]
      X. Han, On emergency oxygen-generation by using chlorate candle for passenger cars, J. Saf. Environ., 5(2005), No. 5, p.43.
      [18]
      W.M. Han, J.H. Yan, Q.P. Kong, B.Q. Xia, and X.F. Liu, Analysis on the effect of plateau oxygen supply of oxygen supply device of a certain type of oxygen candle, Occup. Health, 30(2014), No. 11, p. 1510.
      [19]
      M. Fan, J.J. Bu, and H.Y. Zheng, The research on actuality and development of oxygen candle, Ship Sci. Technol., 28(2006), No. 2, p. 16.
      [20]
      E. Shafirovich, A. Garcia, A.K.N. Swamy, D.J. Mast, and S.D. Hornung, On feasibility of decreasing metal fuel content in chemical oxygen generators, Combust. Flame, 159(2012), No. 1, p. 420.
      [21]
      Y. Zhang, T. Xv, M.L. Wang, X.M. Zhou, X. Hu, and H.Y. Wang, Study on reducing the quantity of heat production of chlorate solid chemical oxygen generator, Contemp. Chem. Ind., 46(2017), No. 8, p. 1534.
      [22]
      E. Shafirovich, A.S. Mukasyan, A. Varma, G. Kshirsagar, Y. Zhang, and J.C. Cannon, Mechanism of combustion in low-exothermic mixtures of sodium chlorate and metal fuel, Combust. Flame, 128(2002), No. 1-2, p. 133.
      [23]
      E. Shafirovich, C. Zhou, A.S. Mukasyan, A. Varma, G. Kshirsagar, Y. Zhang, and J.C. Cannon, Combustion fluctuations in low-exothermic condensed systems for emergency oxygen generation, Combust. Flame, 135(2003), No. 4, p. 557.
      [24]
      X. Hu, Z. Chang, Y. Zhang, L. Mao, J. Xiang, M.L. Wang, S.H. Mao, and X.M. Zhou, Safety and reliability study on improving oxygen candle starter of coal mine self-rescuer, Saf. Coal Mines, 46(2015), No. 7, p. 70.
      [25]
      Y.J. Wang, L.E. Ma, and J.F. Ning, Chlorine suppressants and chlorine gas filtering materials for the oxygen-generating candles, Chem. Def. Ships, 2010, No. 1, p. 21.
      [26]
      Y.C. Zhang, M.J. Brumely, J.C. Cannon, J.E. Ellison, and G.S. Kshirsagar, Filter for Chemical Oxygen Generators, U.S. Patent, Appl. 6464757, 2002.
      [27]
      Y.C. Zhang, G. Kshirsagar, and J.C. Cannon, Functions of barium peroxide in sodium chlorate chemical oxygen generators, Ind. Eng. Chem. Res., 32(1993), No. 5, p. 966.
      [28]
      S.P. Schillaci, Chlorine Gas Filtering Material Suitable for Use in a Chemical Oxygen Generator, U.S. Patent, Appl. 4687640, 1987.
      [29]
      M.A. Machado, D.A. Rodriguez, Y. Aly, M. Schoenitz, E.L. Dreizin, and E. Shafirovich, Nanocomposite and mechanically alloyed reactive materials as energetic additives in chemical oxygen generators, Combust. Flame, 161(2014), No. 10, p. 2708.
      [30]
      V. Diakov, E. Shafirovich, and A. Varma, A numerical study of combustion stability in emergency oxygen generators, AIChE J., 52(2006), No. 4, p. 1495.
      [31]
      Y.W. Zhang, K. Yan, K.Z. Qiu, J.Z. Liu, Y. Wang, and J.H. Zhou, Catalyst for lithium perchlorate decomposition, J. Propul. Power, 38(2015), No. 6, p. 1.
      [32]
      E. Shafirovich, C.J. Zhou, S. Ekambaram, A. Varma, G. Kshirsagar, and J.E. Ellison, Catalytic effects of metals on thermal decomposition of sodium chlorate for emergency oxygen generators, Ind. Eng. Chem. Res., 46(2007), No. 10, p. 3073.
      [33]
      Y. Zhang, G. Kshirsagar, J.E. Ellison, and J.C. Cannon, Catalytic effects of non-oxide metal compounds on the thermal decomposition of sodium chlorate, Ind. Eng. Chem. Res., 32(1993), No. 11, p. 2863.
      [34]
      Y.C. Zhang, G. Kshirsagar, J.E. Ellison, and J.C. Cannon, Catalytic effects of metal oxides on the thermal decomposition of sodium chlorate, Thermochim. Acta, 228(1993), p. 147.
      [35]
      W.K. Rudloff and E.S. Freeman, Catalytic effect of metal oxides on thermal-decomposition reactions. I. The mechanism of the molten-phase thermal decomposition of potassium chlorate in mixtures with potassium chloride and potassium perchlorate, J. Phys. Chem., 73(1969), No. 5, p. 1209.
      [36]
      W.K. Rudloff and E.S. Freeman, Catalytic effect of metal oxides on thermal decomposition reactions. Ⅱ. Catalytic effect of metal oxides on the thermal decomposition of potassium chlorate and potassium perchlorate as detected by thermal analysis methods, J. Phys. Chem., 74(1970), No. 18, p. 3317.
      [37]
      W.K. Rudloff and E.S. Freeman, The catalytic effects of metal oxides on thermal decomposition reactions, Ⅲ:The influence of structural and electronic defects in iron oxides on their catalytic effectiveness with respect to the thermal decomposition of potassium chlorate, J. Therm. Anal. Calorim., 18(1980), No. 2, p. 359.
      [38]
      M.M. Markowitz, D.A. Boryta, and J.H. Stewart, The differential thermal analysis of perchlorates. VI. Transient perchlorate formation during the pyrolysis of the alkali metal chlorates, J. Phys. Chem., 68(1964), No. 8, p. 2282.
      [39]
      T. Wydeven, Catalytic decomposition of sodium chlorate, J. Catal., 19(1970), No. 2, p. 162.
      [40]
      J.G. Liu, L.Z. Jin, N. Gao, S. Wang, and H. Zhang, Catalytic effect of Mn particle size on thermal decomposition of sodium chlorate in oxygen generators, Chin. J. Eng., 39(2017), No. 8, p. 1159.
      [41]
      J.G. Liu, L.Z. Jin, N. Gao, J. Zhao, Z. Zhang, H. Zhang, and R.Y. Chen, Study on catalytic characteristics of Co2O3 for NaClO3 pyrolysis in oxygen candle, J. Saf. Sci. Technol., 13(2017), No. 8, p. 159.
      [42]
      Z. Zhang, L.Z. Jin, S.C. Liu, S. Wang, N. Gao, and J. Li, Study on optimization of oxygen candle formula for refuge chamber, China Saf. Sci. J., 23(2013), No. 9, p. 129.
      [43]
      A. Schwendiman, Toxicity and decomposition of sodium chlorate in soils, J. Am. Soc. Agron., 1941, p. 522.
      [44]
      P.F. Patrick and K.J. McCallum, Radiation decomposition of sodium chlorate, Nature, 194(1962), No. 4830, p. 766.
      [45]
      H.G. Heal, The decomposition of solid potassium chlorate by X Rays, Can. J. Chem., 37(1959), No. 5, p. 979.
      [46]
      R.A. Yetter, G.A. Risha, and S.F. Son, Metal particle combustion and nanotechnology, Proc. Combust. Inst., 32(2009), No. 2, p. 1819.
      [47]
      Submarine Air Regeneration and Analysis Writing Group, Submarine Air Regeneration and Analysis, National Defence Industry Press, Beijing, 1983, p. 103.
      [48]
      H.Y. Ding, Development of chlorate oxygen candle research to improve the air quality of submarine cabin, Chem. Def. Ships, 1991, No. 12, p. 2-3.
      [49]
      J.G. Liu, L.Z. Jin, N. Gao, W.X. Wang, and J. Shen, Effect of forming technology on oxygen supply performance of oxygen candles in refuge spaces,[in] 3rd International Symposium on Mine Safety Science and Engineering, Québec, 2016, p. 308.
      [50]
      Z. H. Zhang, Oxygen candle starting device of chemical oxygen self-rescuer, Saf. Coal Mines, 1995, No. 11, p. 29.
      [51]
      I. Vlad, Solid state oxygen development program, Saf. J., 32(2004), No. 1, p. 36.
      [52]
      R. Lester, Aircraft Passenger Oxygen, Survival and Escape Mask, U.S. Patent, Appl. 5709204, 1998.
      [53]
      E.J. Brennan, Emergency Oxygen System for Aircraft, U.S. Patent, Appl. 4609166, 1986.
      [54]
      R.F. Boehme and D.R. Zuck, Emergency Oxygen System for High Altitude Aircraft, U.S. Patent, Appl. 2934293, 1960.
      [55]
      W.S. McBride, Chemical Oxygen Generator, U.S. Patent, Appl. 4278637, 1981.
      [56]
      T.C. Blakeman, J.D. Rodriquez, T.J. Britton, J.A. Johannigman, M.C. Petro, and R.D. Branson, Evaluation of oxygen concentrators and chemical oxygen generators at altitude and temperature extremes, Mil. Med., 181(2016), No. S5, p. 160.
      [57]
      B.N. Arnold, Oxygen Candle Cover, UK Patent, Appl. 9703221, 1997.
      [58]
      H.C. Gao, W.X. Ma, Y. Zhang, and F.Y. Shi, Sodium Chlorate Oxygen Candle, Chinese Patent Appl. 1035248A, 1989.
      [59]
      Y.J. Wang, L.E. Ma, D.W. Guo, S.N. Jiang, and X.C. Wang, Choice of firefighting means when the oxygen generating candle catch fire in submarines, Ship Sci. Technol., 32(2010), No. 3, p. 94.
      [60]
      W.X. Wang, L.Z. Jin, N. Gao, L.Y. Fan, J. Shen, J.G. Liu, and Z. Zhang, Study on properties of double-layer structure oxygen candle for refuge space in mine, Coal Technol., 35(2016), No. 6, p. 201.
      [61]
      Z. Zhang, Research and Manufacture of an Oxygen Candle for Refuge Chamber [Dissertation], University of Science and Technology Beijing, Beijing, 2013, p. 56.
      [62]
      X. Han, A Method of Generating Oxygen by Using Microwave Heating Oxygen Candle and the Apparatus of Microwave, Chinese Patent, Appl. CN1962415, 2007.
      [63]
      X. Han, J.F. Mao, B.Y. Cheng, and D.Y. Jia, Theoretical study on oxygen generation using chlorate candle with microwave induction, China Saf. Sci. J., 16(2006), No. 4, p. 67.
      [64]
      M. Machado, D. Rodriguez, E. Shafirovich, and E. Dreizin, Selection of nanocomposite reactive materials for using in oxygen and hydrogen generators,[in] 51st AIAA Aerospace Sciences Meeting Including the New Horizons Forum and Aerospace Exposition, Grapevine, 2013, p. 822.

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