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Volume 26 Issue 9
Sep.  2019
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文章导航 >  矿物冶金与材料学报（英文）  > 2019  >  26(9): 1113-1119
Qi-qiang Mou, Jian-li Li, Qiang Zeng,  and Hang-yu Zhu, Effect of Fe2O3 on the size and components of spinel crystals in the CaO-SiO2-MgO-Al2O3-Cr2O3 system, Int. J. Miner. Metall. Mater., 26(2019), No. 9, pp. 1113-1119. https://doi.org/10.1007/s12613-019-1822-9
Cite this article as:
Qi-qiang Mou, Jian-li Li, Qiang Zeng,  and Hang-yu Zhu, Effect of Fe2O3 on the size and components of spinel crystals in the CaO-SiO2-MgO-Al2O3-Cr2O3 system, Int. J. Miner. Metall. Mater., 26(2019), No. 9, pp. 1113-1119. https://doi.org/10.1007/s12613-019-1822-9
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研究论文

Effect of Fe2O3 on the size and components of spinel crystals in the CaO-SiO2-MgO-Al2O3-Cr2O3 system

  • The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China

  • Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology, Wuhan 430081, China

  • Hubei Provincial Key Laboratory for New Processes of Ironmaking and Steelmaking, Wuhan University of Science and Technology, Wuhan 430081, China

  • 通讯作者:

    Jian-li Li    E-mail: jli@wust.edu.cn

  • size of spinel crystals in the CaO-SiO2-MgO-Al2O3-Cr2O3 system was investigated using lab experiments carried out in a carbon tube furnace. Scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS) and X-ray diffraction (XRD) were used to analyze the microstructure, components, and the mineral phases of synthetic slags. FactSage 7.1 was used to calculate the crystallization process of the molten slag. The results showed that the addition of Fe2O3 promoted the precipitation of spinel crystals and inhibited the formation of dicalcium silicate. The size of spinel crystals increased from 2.74 to 8.10 μm and the contents of chromium and iron in the spinel varied as the Fe2O3 addition was increased from 0 to 20wt%. Fe2O3 thermodynamically provided the spinel-forming components to enhance the formation of FeCr2O4, MgFe2O4, and Fe3O4. The addition of Fe2O3 increased the fraction of liquid phase in a certain temperature range and promoted diffusion by decreasing the slag's viscosity. Therefore, Fe2O3 is beneficial to the growth of spinel crystals in stainless steel slag.
    • Research Article

    Effect of Fe2O3 on the size and components of spinel crystals in the CaO-SiO2-MgO-Al2O3-Cr2O3 system

    + Author Affiliations
      Abstract
    • size of spinel crystals in the CaO-SiO2-MgO-Al2O3-Cr2O3 system was investigated using lab experiments carried out in a carbon tube furnace. Scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS) and X-ray diffraction (XRD) were used to analyze the microstructure, components, and the mineral phases of synthetic slags. FactSage 7.1 was used to calculate the crystallization process of the molten slag. The results showed that the addition of Fe2O3 promoted the precipitation of spinel crystals and inhibited the formation of dicalcium silicate. The size of spinel crystals increased from 2.74 to 8.10 μm and the contents of chromium and iron in the spinel varied as the Fe2O3 addition was increased from 0 to 20wt%. Fe2O3 thermodynamically provided the spinel-forming components to enhance the formation of FeCr2O4, MgFe2O4, and Fe3O4. The addition of Fe2O3 increased the fraction of liquid phase in a certain temperature range and promoted diffusion by decreasing the slag's viscosity. Therefore, Fe2O3 is beneficial to the growth of spinel crystals in stainless steel slag.
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