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Volume 26 Issue 10
Oct.  2019
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Ying-zhong Ma, Chang-lin Yang, Yun-jin Liu, Fu-song Yuan, Shan-shan Liang, Hong-xiang Li, and Ji-shan Zhang, Microstructure, mechanical, and corrosion properties of extruded low-alloyed Mg–xZn–0.2Ca alloys, Int. J. Miner. Metall. Mater., 26(2019), No. 10, pp. 1274-1284. https://doi.org/10.1007/s12613-019-1860-3
Cite this article as:
Ying-zhong Ma, Chang-lin Yang, Yun-jin Liu, Fu-song Yuan, Shan-shan Liang, Hong-xiang Li, and Ji-shan Zhang, Microstructure, mechanical, and corrosion properties of extruded low-alloyed Mg–xZn–0.2Ca alloys, Int. J. Miner. Metall. Mater., 26(2019), No. 10, pp. 1274-1284. https://doi.org/10.1007/s12613-019-1860-3
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研究论文

Microstructure, mechanical, and corrosion properties of extruded low-alloyed Mg–xZn–0.2Ca alloys

  • 通讯作者:

    Hong-xiang Li    E-mail: hxli@skl.ustb.edu.cn

    Ji-shan Zhang    E-mail: zhangjs@skl.ustb.edu.cn

  • The microstructure, mechanical, and corrosion properties of extruded low-alloyed Mg-xZn-0.2Ca (x=0, 1.0, 2.0, 3.0) alloys were investigated in this study. Findings from scanning electron microscope, X-ray diffraction and transmission electron microscopy results indicate that the amount of ternary Ca2Mg6Zn3 phase, as the only secondary phase in 1.0Zn, 2.0Zn, and 3.0Zn alloys, gradually increases with the addition of Zn, while the Mg2Ca phase was observed in the Mg-0.2Ca alloy only. Zn has a strong effect on the orientation and intensity of textures, which also influence mechanical behaviors, as revealed by electron back-scatter diffraction. Among all the alloys, the Mg-2.0Zn-0.2Ca alloy obtains the maximum tensile strength (278 MPa) and yield strength (230 MPa). Moreover, Zn addition has an evident influence on the corrosion properties of Mg-xZn-0.2Ca alloy, and Mg-1.0Zn-0.2Ca alloy exhibits the minimum corrosion rate. This paper provides a novel low-alloyed magnesium alloy as a potential biodegradable material.
  • Research Article

    Microstructure, mechanical, and corrosion properties of extruded low-alloyed Mg–xZn–0.2Ca alloys

    + Author Affiliations
    • The microstructure, mechanical, and corrosion properties of extruded low-alloyed Mg-xZn-0.2Ca (x=0, 1.0, 2.0, 3.0) alloys were investigated in this study. Findings from scanning electron microscope, X-ray diffraction and transmission electron microscopy results indicate that the amount of ternary Ca2Mg6Zn3 phase, as the only secondary phase in 1.0Zn, 2.0Zn, and 3.0Zn alloys, gradually increases with the addition of Zn, while the Mg2Ca phase was observed in the Mg-0.2Ca alloy only. Zn has a strong effect on the orientation and intensity of textures, which also influence mechanical behaviors, as revealed by electron back-scatter diffraction. Among all the alloys, the Mg-2.0Zn-0.2Ca alloy obtains the maximum tensile strength (278 MPa) and yield strength (230 MPa). Moreover, Zn addition has an evident influence on the corrosion properties of Mg-xZn-0.2Ca alloy, and Mg-1.0Zn-0.2Ca alloy exhibits the minimum corrosion rate. This paper provides a novel low-alloyed magnesium alloy as a potential biodegradable material.
    • loading
    • [1]
      H.R. Baksheesh-Rad, E. Hamzah, A. Fereidouni-Lotfabadi, M. Daroonparvar, M.A.M. Yajid, M. Mezbahul-Islam, M. Kasiri-Asgarani, and M. Medraj, Microstructure and bio-corrosion behavior of Mg–Zn and Mg–Zn–Ca alloys for biomedical applications, Mater. Corros., 65(2014), No. 12, p. 1178.
      [2]
      H.S. Brar, J.P. Ball, I.S. Berglund, J.B. Allen, and M.V. Manuel, A study of a biodegradable Mg–3Sc–3Y alloy and the effect of self-passivation on the in vitro degradation, Acta Biomater., 9(2013), p. 5331.
      [3]
      L.B. Tong, M.Y. Zheng, L.R. Cheng, S. Kamado, and H.J. Zhang, Effect of extruded ratio on microstructure, texture and mechanical properties of indirectly extruded Mg–Zn–Ca alloy, Mater. Sci. Eng. A, 569(2013), p. 48.
      [4]
      Y.Z. Du, M.Y. Zheng, C. Xu, X.G. Qiao, K. Wu, X.D. Liu, G.J. Wang, and X.Y. Lv, Microstructures and mechanical properties of as-cast and as-extruded Mg–4.50Zn–1.13Ca (wt%) alloys, Mater. Sci. Eng. A, 576(2013), p. 6.
      [5]
      M. Hradilová, D. Vojtěch, J. Kubásek, J. Čapek, and M. Vlach, Structural and mechanical characteristics of Mg–4Zn and Mg–4Zn–0.4Ca alloys after different thermal and mechanical processing routes, Mater. Sci. Eng. A, 586(2013), p. 284.
      [6]
      H.R. Bakhsheshi-Rad, M.H. Idris, M.R. Abdul-Kadir, A. Ourdjini, M. Medraj, M. Daroonparvar, and E. Hamzah, Mechanical and bio-corrosion properties of quaternary Mg–Ca–Mn–Zn alloys compared with binary Mg–Ca alloys, Mater. Des., 53(2014), p. 283.
      [7]
      J. Yang, J. Peng, M. Li, E.A. Nyberg, and F.S. Pan, Effects of Ca addition on the mechanical properties and corrosion behavior of ZM21 wrought alloys, Acta Metall. Sin. (Engl. Lett.), 30(2017), No. 1, p. 53.
      [8]
      P. Yin, N.F. Li, T. Lei, L. Liu, and C. Ouyang, Effects of Ca on microstructure, mechanical and corrosion properties and biocompatibility of Mg–Zn–Ca alloys, J. Mater. Sci. - Mater. Med., 24(2013), No. 6, p. 1365.
      [9]
      B.P. Zhang, L. Geng, L.J. Huang, X.X. Zhang, and C.C. Dong, Enhanced mechanical properties in fine-grained Mg–1.0Zn–0.5Ca alloys prepared by extruded atdifferent temperatures, Scr. Mater., 63(2010), No. 10, p. 1024.
      [10]
      J. Hofstetter, S. Rüedi, I. Baumgartner, H. Kilian, B. Mingler, E. Povoden-Karadeniz, S. Pogatscher, P.J. Uggowitzer, and J.F. Löffler, Processing and microstructure–property relations of high-strength low-alloy (HSLA) Mg–Zn–Ca alloys, Acta Mater., 98(2015), p. 423.
      [11]
      L.B. Tong, M.Y. Zheng, X.S. Hu, K. Wu, S.W. Xu, S. Kamado, and Y. Kojima, Influence of ECAP routes on microstructure and mechanical properties of Mg–Zn–Ca alloy, Mater. Sci. Eng. A, 527(2010), No. 16-17, p. 4250.
      [12]
      T. Kokubo and H. Takadama, How useful is SBF in predicting in vivo bone bioactivity, Biomaterials, 27(2006), No. 15, p. 2907.
      [13]
      D. Zander and N.A. Zumdick, Influence of Ca and Zn on the microstructure and corrosion of biodegradable Mg–Ca–Zn alloys, Corros. Sci., 93(2015), p. 222.
      [14]
      E. Zhang and L. Yang, Microstructure, mechanical properties and bio-corrosion properties of Mg–Zn–Mn–Ca alloy for biomedical application, Mater. Sci. Eng. A, 497(2008), No. 1-2, p. 111.
      [15]
      A. Takeuchi and A. Inoue, Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element, Mater. Trans., 46(2005), No. 12, p. 2817.
      [16]
      K. Kubok, L. Litynska-Dobrzynska, J. Wojewoda-Budka, A. Góral, and A. Debski, Investigation of structures in as-cast alloys from the Mg–Zn–Ca system, Arch. Metall. Mater., 58(2013), No. 2, p. 399.
      [17]
      G. Levi, S. Avraham, A. Ziberov, and M. Bamberger, Solidification, solution treatment and age hardening of a Mg–1.6wt% Ca–3.2wt% Zn alloy, Acta Mater. 54(2006), No. 2, p. 523.
      [18]
      Y. Lu, A.R. Bradshaw, Y. L. Chiu, and I.P. Jones, Effects of secondary phase and grain size on the corrosion of biodegradable Mg–Zn–Ca alloys, Mater. Sci. Eng. C, 48(2015), p. 480.
      [19]
      L. Geng, B.P. Zhang, A.B. Li, and C.C. Dong, Microstructure and mechanical properties of Mg–4.0Zn–0.5Ca alloy, Mater. Lett., 63(2009), No. 5, p. 557.

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