木质素磺酸钙在磷灰石和白云石浮选体系中的作用机理

冯博; 张良柱; 张文谱; 汪惠惠; 高志勇

doi:10.1007/s12613-021-2313-3

Volume 29 Issue 9

Sep. 2022

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文章导航 > 矿物冶金与材料学报（英文） > 2022 > 29(9): 1697-1704

Bo Feng, Liangzhu Zhang, Wenpu Zhang, Huihui Wang, and Zhiyong Gao, Mechanism of calcium lignosulfonate in apatite and dolomite flotation system, Int. J. Miner. Metall. Mater., 29(2022), No. 9, pp. 1697-1704. https://doi.org/10.1007/s12613-021-2313-3

Cite this article as:

Bo Feng, Liangzhu Zhang, Wenpu Zhang, Huihui Wang, and Zhiyong Gao, Mechanism of calcium lignosulfonate in apatite and dolomite flotation system, Int. J. Miner. Metall. Mater., 29(2022), No. 9, pp. 1697-1704. https://doi.org/10.1007/s12613-021-2313-3

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研究论文

木质素磺酸钙在磷灰石和白云石浮选体系中的作用机理

1)
江西理工大学江西省矿业工程重点实验室, 赣州341000, 中国
2)
中南大学战略含钙矿物资源清洁高效利用湖南省重点实验室, 长沙410083, 中国
3)
稀有金属分离与综合利用国家重点实验室, 广州510600, 中国

通讯作者:
冯博 E-mail: fengbo319@163.com

文章亮点

(1) 研究了木质素磺酸钙对磷灰石和白云石浮选分离的影响。

(2) 白云石表面对木质素磺酸钙的吸附量大于磷灰石。

(3) 木质素磺酸钙能强烈地抑制白云石。

中文摘要

由于磷灰石和白云石的物理化学性质相似，这两种矿物的分离比较困难。因此，在使用浮选法进行这种分离时，有必要寻找选择性抑制剂。以木质素磺酸钙为抑制剂，对磷灰石和白云石的分离行为进行了试验研究，并对其分离机理进行了分析。结果表明，木质素磺酸钙对磷灰石和白云石均有抑制作用，但在相同用量下，对白云石的抑制作用更强。机理分析表明，木质素磺酸钙对白云石的吸附能力高于对磷灰石的吸附能力，这是由于木质素磺酸钙与白云石上的钙位点反应强烈所致。此外，木质素磺酸钙与白云石之间存在氢键，这进一步阻止了油酸钠对白云石的吸附，从而大大抑制了白云石的浮选。

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Research Article

Mechanism of calcium lignosulfonate in apatite and dolomite flotation system

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Abstract

Abstract

Since the physical and chemical properties of apatite and dolomite can be similar, the separation of these two minerals is difficult. Therefore, when performing this separation using the flotation method, it is necessary to search for selective depressants. An experimental research was performed on the separation behavior of apatite and dolomite using calcium lignosulfonate as a depressant, and the mechanism by which this occurs was analyzed. The results show that calcium lignosulfonate has a depressant effect on both apatite and dolomite, but the depressant effect on dolomite is stronger at the same dosage. Mechanism analysis shows that the adsorptive capacity of calcium lignosulfonate on dolomite is higher than that of apatite, which is due to the strong reaction between calcium lignosulfonate and the Ca sites on dolomite. In addition, there is a hydrogen bond between calcium lignosulfonate and dolomite, which further prevents the adsorption of sodium oleate to dolomite, thus greatly inhibiting the flotation of dolomite.
- apatite;
- dolomite;
- calcium lignosulfonate;
- depression mechanism

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