Co2+取代钙钛矿结构B位对Bi0.5(Na0.68K0.22Li0.10)0.5TiO3陶瓷相形成、显微组织、电学和磁学性能的影响

Pamornnarumol Bhupaijit; Chonnarong Kaewsai; Tawat Suriwong; Supree Pinitsoontorn; Surirat Yotthuan; Naratip Vittayakorn; Theerachai Bongkarn

doi:10.1007/s12613-021-2345-8

Volume 29 Issue 9

Aug. 2022

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文章导航 > 矿物冶金与材料学报（英文版） > 2022 > 29(9) : 1798-1808. > DOI: 10.1007/s12613-021-2345-8

Cite this article as:

Pamornnarumol Bhupaijit, Chonnarong Kaewsai, Tawat Suriwong, Supree Pinitsoontorn, Surirat Yotthuan, Naratip Vittayakorn, and Theerachai Bongkarn, Effect of Co²⁺ substitution in B-sites of the perovskite system on the phase formation, microstructure, electrical and magnetic properties of Bi_0.5(Na_0.68K_0.22Li_0.10)_0.5TiO₃ ceramics, Int. J. Miner. Metall. Mater., 29(2022), No. 9, pp.1798-1808. https://dx.doi.org/10.1007/s12613-021-2345-8

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研究论文

Co²⁺取代钙钛矿结构B位对Bi_0.5(Na_0.68K_0.22Li_0.10)_0.5TiO₃陶瓷相形成、显微组织、电学和磁学性能的影响

1)
Department of Physics, Faculty of Science, Naresuan University, Phitsanulok 65000, Thailand
2)
School of Renewable Energy and Smart Grid Technology, Naresuan University, Phitsanulok 65000, Thailand
3)
Research Center for Academic Excellence in Applied Physics, Faculty of Science, Naresuan University, Phitsanulok 65000, Thailand
4)
Institute of Nanomaterials Research and Innovation for Energy (IN-RIE), Khon Kaen University, Khon Kaen 40002, Thailand
5)
Department of Chemistry, School of Science, King Mongkut's Institute of Technology Ladkrabang, Bangkok 10520, Thailand

通信作者:
Theerachai Bongkarn E-mail: researchcmu@yahoo.com

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中文摘要

通过固态燃烧技术制备Bi_0.5(Na_0.68K_0.22Li_0.10)_0.5Ti_1–xCo_xO₃ 无铅钙钛矿陶瓷（BNKLT–xCo, x = 0, 0.005, 0.010, 0.015, 0.020）。因少量Co²⁺离子置换到 Ti 位点而导致 BNKLT 陶瓷的相组成、微观结构、电学和磁学性能发生改变。使用 X 射线衍射 (XRD) 发现在所有样品中菱面体和四方相共存。 Rietveld 结果表明，当 x 从 0 增加到 0.020 时，菱面体相比例从 39% 增加到 88%。当 x 增加时，平均晶粒尺寸增加。随着 x 的增加，产生了更多的氧空位，导致双极应变（S–E）磁滞回线不对称。x = 0.010 时，介电常数 (ε_m) 达到5384，应变 (S_max)达到0.23%，归一化应变 (

$\left({d}_{33}^{*}\right)$ ) 为 460 pm·V^–1。 50 K温度下，BNKLT–0Co 陶瓷表现出抗磁行为，但所有 BNKLT–xCo 陶瓷表现出顺磁行。

关键词:

BNKLT–xCo ;
电介质 ;
铁电体 ;
应变 ;
磁性

Research Article

Effect of Co²⁺ substitution in B-sites of the perovskite system on the phase formation, microstructure, electrical and magnetic properties of Bi_0.5(Na_0.68K_0.22Li_0.10)_0.5TiO₃ ceramics

Author Affilications

1)
Department of Physics, Faculty of Science, Naresuan University, Phitsanulok 65000, Thailand
2)
School of Renewable Energy and Smart Grid Technology, Naresuan University, Phitsanulok 65000, Thailand
3)
Research Center for Academic Excellence in Applied Physics, Faculty of Science, Naresuan University, Phitsanulok 65000, Thailand
4)
Institute of Nanomaterials Research and Innovation for Energy (IN-RIE), Khon Kaen University, Khon Kaen 40002, Thailand
5)
Department of Chemistry, School of Science, King Mongkut's Institute of Technology Ladkrabang, Bangkok 10520, Thailand

Corresponding author:
Theerachai Bongkarn E-mail: researchcmu@yahoo.com

Received: 28 April 2021; Revised: 17 August 2021; Accepted: 23 August 2021; Available online: 25 August 2021

Abstract:

Bi_0.5(Na_0.68K_0.22Li_0.10)_0.5Ti_1–xCo_xO₃ lead-free perovskite ceramics (BNKLT–xCo, x = 0, 0.005, 0.010, 0.015 and 0.020) were fabricated via the solid-state combustion technique. A small-amount of Co²⁺ ion substitution into Ti-sites led to modification of the phase formation, microstructure, electrical and magnetic properties of BNKLT ceramics. Coexisting rhombohedral and tetragonal phases were observed in all samples using the X-ray diffraction (XRD) technique. The Rietveld refinement revealed that the rhombohedral phase increased from 39% to 88% when x increased from 0 to 0.020. The average grain size increased when x increased. With increasing x, more oxygen vacancies were generated, leading to asymmetry in the bipolar strain (S–E) hysteresis loops. For the composition of x = 0.010, a high dielectric constant (ε_m) of 5384 and a large strain (S_max) of 0.23% with the normalized strain

$\left({d}_{33}^{*}\right)$ of 460 pm·V^–1 were achieved. The BNKLT–0Co ceramic showed diamagnetic behavior but all of the BNKLT–xCo ceramics exhibited paramagnetic behavior, measured at 50 K.

Keywords:

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