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Volume 29 Issue 9
Sep.  2022
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文章导航 >  矿物冶金与材料学报（英文）  > 2022  >  29(9): 1798-1808
Pamornnarumol Bhupaijit, Chonnarong Kaewsai, Tawat Suriwong, Supree Pinitsoontorn, Surirat Yotthuan, Naratip Vittayakorn, and Theerachai Bongkarn, Effect of Co2+ substitution in B-sites of the perovskite system on the phase formation, microstructure, electrical and magnetic properties of Bi0.5(Na0.68K0.22Li0.10)0.5TiO3 ceramics, Int. J. Miner. Metall. Mater., 29(2022), No. 9, pp. 1798-1808. https://doi.org/10.1007/s12613-021-2345-8
Cite this article as:
Pamornnarumol Bhupaijit, Chonnarong Kaewsai, Tawat Suriwong, Supree Pinitsoontorn, Surirat Yotthuan, Naratip Vittayakorn, and Theerachai Bongkarn, Effect of Co2+ substitution in B-sites of the perovskite system on the phase formation, microstructure, electrical and magnetic properties of Bi0.5(Na0.68K0.22Li0.10)0.5TiO3 ceramics, Int. J. Miner. Metall. Mater., 29(2022), No. 9, pp. 1798-1808. https://doi.org/10.1007/s12613-021-2345-8
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研究论文

Co2+取代钙钛矿结构B位对Bi0.5(Na0.68K0.22Li0.10)0.5TiO3陶瓷相形成、显微组织、电学和磁学性能的影响

  • 1)

    Department of Physics, Faculty of Science, Naresuan University, Phitsanulok 65000, Thailand

  • 2)

    School of Renewable Energy and Smart Grid Technology, Naresuan University, Phitsanulok 65000, Thailand

  • 3)

    Research Center for Academic Excellence in Applied Physics, Faculty of Science, Naresuan University, Phitsanulok 65000, Thailand

  • 4)

    Institute of Nanomaterials Research and Innovation for Energy (IN-RIE), Khon Kaen University, Khon Kaen 40002, Thailand

  • 5)

    Department of Chemistry, School of Science, King Mongkut's Institute of Technology Ladkrabang, Bangkok 10520, Thailand

  • 通讯作者:

    Theerachai Bongkarn    E-mail: researchcmu@yahoo.com

  • 通过固态燃烧技术制备Bi0.5(Na0.68K0.22Li0.10)0.5Ti1–xCoxO3 无铅钙钛矿陶瓷（BNKLT–xCo, x = 0, 0.005, 0.010, 0.015, 0.020）。因少量Co2+离子置换到 Ti 位点而导致 BNKLT 陶瓷的相组成、微观结构、电学和磁学性能发生改变。使用 X 射线衍射 (XRD) 发现在所有样品中菱面体和四方相共存。 Rietveld 结果表明，当 x 从 0 增加到 0.020 时，菱面体相比例从 39% 增加到 88%。当 x 增加时，平均晶粒尺寸增加。随着 x 的增加，产生了更多的氧空位，导致双极应变（S–E）磁滞回线不对称。x = 0.010 时，介电常数 (εm) 达到5384，应变 (Smax)达到0.23%，归一化应变 ($\left({d}_{33}^{*}\right) $) 为 460 pm·V–1。 50 K温度下，BNKLT–0Co 陶瓷表现出抗磁行为，但所有 BNKLT–xCo 陶瓷表现出顺磁行。
    • Research Article

    Effect of Co2+ substitution in B-sites of the perovskite system on the phase formation, microstructure, electrical and magnetic properties of Bi0.5(Na0.68K0.22Li0.10)0.5TiO3 ceramics

    + Author Affiliations
      Abstract
    • Bi0.5(Na0.68K0.22Li0.10)0.5Ti1–xCoxO3 lead-free perovskite ceramics (BNKLT–xCo, x = 0, 0.005, 0.010, 0.015 and 0.020) were fabricated via the solid-state combustion technique. A small-amount of Co2+ ion substitution into Ti-sites led to modification of the phase formation, microstructure, electrical and magnetic properties of BNKLT ceramics. Coexisting rhombohedral and tetragonal phases were observed in all samples using the X-ray diffraction (XRD) technique. The Rietveld refinement revealed that the rhombohedral phase increased from 39% to 88% when x increased from 0 to 0.020. The average grain size increased when x increased. With increasing x, more oxygen vacancies were generated, leading to asymmetry in the bipolar strain (S–E) hysteresis loops. For the composition of x = 0.010, a high dielectric constant (εm) of 5384 and a large strain (Smax) of 0.23% with the normalized strain $ \left({d}_{33}^{*}\right) $ of 460 pm·V–1 were achieved. The BNKLT–0Co ceramic showed diamagnetic behavior but all of the BNKLT–xCo ceramics exhibited paramagnetic behavior, measured at 50 K.
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