新型Cr<sup>3+</sup>激活的远红光荧光粉

赵芳仪; 宋振; 刘泉林

doi:10.1007/s12613-021-2363-6

Volume 29 Issue 6

Jun. 2022

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文章导航 > 矿物冶金与材料学报（英文） > 2022 > 29(6): 1286-1294

Fangyi Zhao, Zhen Song, and Quanlin Liu, Novel Cr³⁺-activated far-red emitting phosphors with β-Ca₃(PO₄)₂-type structure for indoor plant cultivation, Int. J. Miner. Metall. Mater., 29(2022), No. 6, pp. 1286-1294. https://doi.org/10.1007/s12613-021-2363-6

Cite this article as:

Fangyi Zhao, Zhen Song, and Quanlin Liu, Novel Cr3+-activated far-red emitting phosphors with β-Ca3(PO4)2-type structure for indoor plant cultivation, Int. J. Miner. Metall. Mater., 29(2022), No. 6, pp. 1286-1294. https://doi.org/10.1007/s12613-021-2363-6

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研究论文

新型Cr³⁺激活的远红光荧光粉

北京科技大学材料科学与工程学院，北京 100083，中国

通讯作者:
宋振 E-mail: zsong@ustb.edu.cn

刘泉林 E-mail: qlliu@ustb.edu.cn

文章亮点

(1) 报道了一系列Cr³⁺激活的β-Ca₃(PO₄)_{2结构的远红光-近红外发光材料Ca_{9Ga(PO₄)₇:Cr³⁺ (M = Al, Ga, Sc, In, Lu, Y)。}}

(2)Ca_{9Ga(PO₄)₇:Cr³⁺远红光荧光粉具有高的内量子效率值以及优异的热稳定性。}

(3) Ca_{9Ga(PO₄)₇:Cr³⁺远红光荧光粉有望用于室内植物种植领域。}

中文摘要

远红光和近红外光谱在食品分析、植物生长、夜视、生物成像、安全监控、虹膜识别等领域具有广泛的应用价值，近年来对远红光和近红外荧光粉的研究获得了越来越多的关注。本文采用高温固相法合成了一系列Cr³⁺激活的β-Ca₃(PO₄)₂结构的远红光-近红外发光材料Ca₉M(PO₄)₇:Cr³⁺ (M = Al, Ga, Sc, In, Lu, Y)，并对这一系列样品进行了XRD、光谱、紫外漫反射及扫描电镜测试。随着M³⁺离子类型由半径较小的Al³⁺变为半径较大的Y³⁺，发射光谱由694 nm红移至795 nm；由于M³⁺离子半径的增加为Cr³⁺离子提供了更为宽松的八面体环境，晶体场强度降低，从而引起发射光谱的红移。其中，当M³⁺离子为Ga³⁺时发射光谱强度最大，在440 nm蓝光激发下，该荧光粉可呈现出峰位在735 nm的宽带远红光发射，发射范围从650 nm到850 nm，并在690 nm和698 nm处呈现出两个尖锐的R线发射。Ca₉Ga_0.97(PO₄)₇:0.03Cr³⁺荧光粉的内量子效率达到55.7%；且该样品具有优异的发光热稳定性能，在423 K时发射光谱的强度仍可保持室温的68.5%。由于Ca₉Ga(PO₄)₇:Cr³⁺荧光粉的发射光谱与植物远红光光敏色素PFR的吸收光谱存在很大的光谱重叠，通过搭配450 nm蓝光芯片进行封装所得到的LED器件有望用于室内植物种植领域，从而促进植物生长。

关键词:

Research Article

Novel Cr³⁺-activated far-red emitting phosphors with β-Ca₃(PO₄)₂-type structure for indoor plant cultivation

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Abstract

Abstract

Cr³⁺-activated far-red and near-infrared phosphors have drawn considerable attention owing to their adjustable emission wavelengths and wide applications. Herein, we reported a series of Cr³⁺-doped phosphors with β-Ca₃(PO₄)₂-type structure, of which Ca₉Ga(PO₄)₇:Cr³⁺ possessed the highest far-red emission intensity. At an excitation of 440 nm, the Ca₉Ga(PO₄)₇:Cr³⁺ phosphors exhibited a broad emission band ranging from 650 to 850 nm and peaking at 735 nm, and the broadband superimposed two sharp lines centering at 690 and 698 nm. The optimal sample Ca₉Ga_0.97(PO₄)₇:0.03Cr³⁺ had an internal quantum efficiency of 55.7%. The luminescence intensity of the Ca₉Ga_0.97(PO₄)₇:0.03Cr³⁺ phosphor obtained at 423 K could maintain 68.5% of that at room temperature, demonstrating its outstanding luminescence thermal stability. A phosphor-conversion light-emitting diode was fabricated, indicating that the Ca₉Ga(PO₄)₇:Cr³⁺ phosphor has potential applications in indoor plant cultivation.
- far-red;
- near-infrared;
- luminescence;
- trivalent chromium ion;
- plant cultivation

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Novel Cr³⁺-activated far-red emitting phosphors with β-Ca₃(PO₄)₂-type structure for indoor plant cultivation

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Novel Cr3+-activated far-red emitting phosphors with β-Ca3(PO4)2-type structure for indoor plant cultivation

Abstract

References

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新型Cr³⁺激活的远红光荧光粉

Novel Cr³⁺-activated far-red emitting phosphors with β-Ca₃(PO₄)₂-type structure for indoor plant cultivation