南海环境下含Nb和Sb耐候钢的大气腐蚀行为研究

吴伟; 朱莉莉; 柴佩林; 刘霓昀; 宋龙飞; 刘智勇; 李晓刚

doi:10.1007/s12613-021-2383-2

Volume 29 Issue 11

Nov. 2022

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文章导航 > 矿物冶金与材料学报（英文） > 2022 > 29(11): 2041-2052

Wei Wu, Lili Zhu, Peilin Chai, Niyun Liu, Longfei Song, Zhiyong Liu, and Xiaogang Li, Atmospheric corrosion behavior of Nb- and Sb-added weathering steels exposed to the South China Sea, Int. J. Miner. Metall. Mater., 29(2022), No. 11, pp. 2041-2052. https://doi.org/10.1007/s12613-021-2383-2

Cite this article as:

Wei Wu, Lili Zhu, Peilin Chai, Niyun Liu, Longfei Song, Zhiyong Liu, and Xiaogang Li, Atmospheric corrosion behavior of Nb- and Sb-added weathering steels exposed to the South China Sea, Int. J. Miner. Metall. Mater., 29(2022), No. 11, pp. 2041-2052. https://doi.org/10.1007/s12613-021-2383-2

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研究论文

南海环境下含Nb和Sb耐候钢的大气腐蚀行为研究

1)
北京科技大学新材料技术研究院，北京 100083，中国
2)
北京科技大学冶金与材料史研究所，北京 100083，中国
3)
广州大学化学与化工学院，广州 510006，中国

通讯作者:
宋龙飞 E-mail: songlongfei@gzhu.edu.cn

刘智勇 E-mail: liuzhiyong7804@126.com

文章亮点

(1) 首次研究了南海真实环境下含Nb和Sb耐候钢的大气腐蚀行为。

(2) Nb和Sb复合添加能够更好地优化锈蚀结构，促进致密保护α-FeOOH的形成。

(3) Nb和Sb抑制了耐候钢锈层底部坑底的局部酸化，减缓了局部腐蚀。

中文摘要

随着我国海洋战略的不断推进，越来越多的耐候钢应用于海洋工程。然而，传统的耐候钢品种在热带海洋环境中面临着极大的腐蚀问题，通过微合金化提升耐候钢的耐蚀性能已经成为近年来的研究热点。本文旨在研究Nb和Sb微量元素添加对耐候钢在热带海洋环境中腐蚀行为的影响。本文制备了一系列含Nb和Sb的新型耐候钢，并结合现场暴露试验和腐蚀表征测试，详细阐明了这些新型耐候钢在南海真实环境中的大气腐蚀行为规律。研究结果表明，在钢中添加0.06wt% Nb和0.05wt% Sb能够一定程度上提升材料的耐蚀性，但Nb和Sb微量元素之间仍存在明显的差异。Nb元素的加入对常规耐候钢的表面锈层性质有一定的改善，但不能有效地抑制其电化学过程；而Sb元素的加入则能够同时从电化学性能和锈层性质两个方面提升材料耐蚀性。与仅仅添加0.06wt% Nb相比，0.05wt% Sb和0.06wt% Nb的复合添加能更好地优化锈层结构，促进更多的保护性α-FeOOH产物的形成，抵挡Cl^-的扩散，减轻锈层下蚀坑底部的局部酸化现象。

关键词:

Research Article

Atmospheric corrosion behavior of Nb- and Sb-added weathering steels exposed to the South China Sea

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Abstract

Abstract

The atmospheric corrosion behavior of new-type weathering steels (WSs) was comparatively studied, and the effects of Nb and Sb during corrosion were clarified in detail through field exposure and characterization. The results showed that the addition of Nb and Sb played positive roles in corrosion resistance, but there was a clear difference between these two elements. Nb addition slightly improved the rust property of conventional WS but could not inhibit the electrochemical process. In contrast, Sb addition significantly improved the corrosion resistance from the aspects of electrochemistry and rust layer. Compared with only 0.06wt% Nb, the combination of 0.05wt% Sb and 0.06wt% Nb could better optimize the rust structure, accelerate the formation of a high proportion of dense and protective α-FeOOH, repel the invasion of Cl⁻, and retard the localized acidification at the bottom of the pit.
- low alloy steel;
- Sb addition;
- atmospheric corrosion;
- corrosion products;
- marine;
- local acidification

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