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Wei Zhang, Xiaoming Liu, and Zengqi Zhang, Mechanical, expansion and rheological properties of circulating fluidized bed fly ash based ecological cement: A critical review, Int. J. Miner. Metall. Mater., 29(2022), No. 9, pp.1670-1682. https://dx.doi.org/10.1007/s12613-021-2403-2
Wei Zhang, Xiaoming Liu, and Zengqi Zhang, Mechanical, expansion and rheological properties of circulating fluidized bed fly ash based ecological cement: A critical review, Int. J. Miner. Metall. Mater., 29(2022), No. 9, pp.1670-1682. https://dx.doi.org/10.1007/s12613-021-2403-2
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循环流化床粉煤灰基生态水泥的力学性能、膨胀性和流变性研究进展

摘要: 循环流化床粉煤灰是电厂循环流化床锅炉在燃煤发电过程中排放的副产物,其长期堆存不仅占用土地空间,还存在污染环境的隐患。循环流化床粉煤灰应用于建筑材料具备降本增效和低碳环保的特点,近年来,利用循环流化床粉煤灰制备水泥是当前研究的热点。本文介绍了循环流化床粉煤灰的理化特性,分类总结了掺入循环流化床粉煤灰对水泥力学性能、膨胀性和流变性影响的研究进展,重点论述了循环流化床粉煤灰对生态水泥抗压强度、体积膨胀和流变特性的影响机理,系统地探讨了现有循环流化床粉煤灰在水泥中应用的优缺点,并对其今后的利用途径和方法进行了展望,提出了利用循环流化床粉煤灰中f-CaO补偿水泥硬化体体积收缩的新途径,介绍了循环流化床粉煤灰制备低成本、高耐久、高环保水泥的新技术。

 

Mechanical, expansion and rheological properties of circulating fluidized bed fly ash based ecological cement: A critical review

Abstract: Circulating fluidized bed fly ash (CFBFA) is a solid waste product from circulating fluidized bed (CFB) boilers in power plants, and the storage of CFBFA is increasingly become an environmental problem. Previous scholars have made contributions to improve the resource utilization of CFBFA. Especially, ecological cement is prepared by CFBFA, which is more conducive to its large-scale utilization. In recent years, a lot of effort has been paid to improve the properties of ecological cement containing CFBFA. In this work, the physicochemical properties of CFBFA are introduced, and recent research progress on the mechanical, expansion, and rheological properties of CFBFA based ecological cement (CEC) is extensively reviewed. The problem of over- expansion of f-CaO is summarized, which limits the scale application of CFBFA in ecological cement. Hence, the challenge for f-CaO in CFBFA to compensate for cement volume shrinkage is proposed, which is beneficial to the utilization of CFBFA in ecological cement, and the reduction of CO2 emissions from the cement industry. In addition, the environmental performance, durability, and economy of CEC should be valued in future research, especially the environmental performance, because the CFBFA contains heavy metals, such as Cr, As, which may pollute groundwater.

 

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