GSM 模型和它的最新进展

周国治

doi:10.1007/s12613-022-2411-x

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文章导航 > 矿物冶金与材料学报（英文） > 2022 > 29(4): 577-585

Kuo-Chih Chou, General solution model and its new progress, Int. J. Miner. Metall. Mater., 29(2022), No. 4, pp. 577-585. https://doi.org/10.1007/s12613-022-2411-x

Cite this article as:

Kuo-Chih Chou, General solution model and its new progress, Int. J. Miner. Metall. Mater., 29(2022), No. 4, pp. 577-585. https://doi.org/10.1007/s12613-022-2411-x

Kuo-Chih Chou, General solution model and its new progress, Int. J. Miner. Metall. Mater., 29(2022), No. 4, pp. 577-585. https://doi.org/10.1007/s12613-022-2411-x

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Kuo-Chih Chou, General solution model and its new progress, Int. J. Miner. Metall. Mater., 29(2022), No. 4, pp. 577-585. https://doi.org/10.1007/s12613-022-2411-x

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研究论文

GSM 模型和它的最新进展

周国治

北京科技大学，北京 100083，中国

通讯作者:
周国治 E-mail: kcc126@126.com

文章亮点

(1) 提出了一种新的计算方式来获得关于浓度三角形中间区域的物理化学性数据。

(2) 从理论和实际应用两方面讨论了该模型的可行性。

(3) 总结分析了关于物理化学数据计算各类模型的发展情况和局限性。

中文摘要

多元体系的物理化学性质涉及到化学的各个领域，受到矿物、冶金、材料科学、环境、生物和农业等各个相关领域的关注。目前，相关数据主要可以通过两种计算方法获得，即第一原理法和经验法。虽然前者最近取得了很大的进展，但要提供实用数据还有很长的路要走；而后者在近半个世纪以来并没有取得任何进展。因此，需要一种理论上合理、实际应用中又准确的新方法来获得实际的、精确的三元和多元体系物理化学数据。本文在相应的二元模型基础上，提出了一种新的理论模型，即GSM模型。本文还从理论分析和实际应用两方面讨论了该理论模型的可行性。

关键词:

Research Article

General solution model and its new progress

Kuo-Chih Chou

+ Author Affiliations

Abstract

Abstract

The physicochemical properties of multicomponent systems are involved in all fields of chemistry and have received attention from various related areas such as minerals, metallurgy, material science, environment, biology, and agriculture. At present, the relevant data can be obtained by using two major calculation methods, namely, the first principle method and the empirical method. Though the former has achieved recent great progress, it is still a long way to offer practical data; while the latter has not received progress for almost half a century. Therefore, a new method that is theoretically reasonable and accurate in practical application is necessary to obtain practical and precise physicochemical data for ternary and multicomponent systems. In this paper, a new theoretical model is suggested based on its corresponding binary ones. The feasibility of this theoretical model is discussed in terms of both theoretical analysis and practical performance.
- multicomponent system;
- physicochemical properties;
- solution model;
- phenomenological theory

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