锂–硫电池硫正极的金属磷化物和硫化物催化载体

高睿; 王振宇; 刘胜; 邵光杰; 高学平

doi:10.1007/s12613-022-2451-2

Volume 29 Issue 5

Apr. 2022

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文章导航 > 矿物冶金与材料学报（英文） > 2022 > 29(5): 990-1002

Rui Gao, Zhenyu Wang, Sheng Liu, Guangjie Shao, and Xueping Gao, Metal phosphides and borides as the catalytic host of sulfur cathode for lithium–sulfur batteries, Int. J. Miner. Metall. Mater., 29(2022), No. 5, pp. 990-1002. https://doi.org/10.1007/s12613-022-2451-2

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Rui Gao, Zhenyu Wang, Sheng Liu, Guangjie Shao, and Xueping Gao, Metal phosphides and borides as the catalytic host of sulfur cathode for lithium–sulfur batteries, Int. J. Miner. Metall. Mater., 29(2022), No. 5, pp. 990-1002. https://doi.org/10.1007/s12613-022-2451-2

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锂–硫电池硫正极的金属磷化物和硫化物催化载体

1)
燕山大学环境与化学工程学院，秦皇岛 066004
2)
南开大学材料与科学工程学院，天津 300350

通讯作者:
邵光杰 E-mail: shaogj@ysu.edu.cn

高学平 E-mail: xpgao@nankai.edu.cn

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Invited Review

Metal phosphides and borides as the catalytic host of sulfur cathode for lithium–sulfur batteries

+ Author Affiliations

Abstract

Abstract

Lithium−sulfur batteries are one of the most competitive high-energy batteries due to their high theoretical energy density of 2600 W·h·kg⁻¹. However, their commercialization is limited by poor cycle stability mainly due to the low intrinsic electrical conductivity of sulfur and its discharged products (Li₂S₂/Li₂S), the sluggish reaction kinetics of sulfur cathode, and the “shuttle effect” of soluble intermediate lithium polysulfides in ether-based electrolyte. To address these challenges, catalytic hosts have recently been introduced in sulfur cathodes to enhance the conversion of soluble polysulfides to the final solid products and thus prevent the dissolution and loss of active-sulfur material. In this review, we summarize the recent progress on the use of metal phosphides and borides of different dimensions as the catalytic host of sulfur cathodes and demonstrate the catalytic conversion mechanism of sulfur cathodes with the help of metal phosphides and borides for high-energy and long-life lithium–sulfur batteries. Finally, future outlooks are proposed on developing advanced catalytic host materials to improve battery performance.
- lithium–sulfur batteries;
- sulfur cathode;
- catalytic host;
- metal phosphides;
- metal borides

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锂–硫电池硫正极的金属磷化物和硫化物催化载体

Metal phosphides and borides as the catalytic host of sulfur cathode for lithium–sulfur batteries

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