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Volume 30 Issue 3
Mar.  2023
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文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(3): 559-569
Xing Feng, Pengfei Yin, Limin Zhang, Xiyuan Sun, Jian Wang, Liang Zhao, Changfang Lu, Zhihua Gao, and Yongxin Zhan, Innovative preparation of Co@CuFe2O4 composite via ball-milling assisted chemical precipitation and annealing for glorious electromagnetic wave absorption, Int. J. Miner. Metall. Mater., 30(2023), No. 3, pp. 559-569. https://doi.org/10.1007/s12613-022-2488-2
Cite this article as:
Xing Feng, Pengfei Yin, Limin Zhang, Xiyuan Sun, Jian Wang, Liang Zhao, Changfang Lu, Zhihua Gao, and Yongxin Zhan, Innovative preparation of Co@CuFe2O4 composite via ball-milling assisted chemical precipitation and annealing for glorious electromagnetic wave absorption, Int. J. Miner. Metall. Mater., 30(2023), No. 3, pp. 559-569. https://doi.org/10.1007/s12613-022-2488-2
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研究论文

新型球磨辅助化学沉淀–煅烧法制备电磁吸波性能优异的Co@CuFe2O4复合材料

  • 1)

    四川农业大学理学院, 雅安 625014, 中国

  • 2)

    西北工业大学物理科学与技术学院, 西安 710129, 中国

    • * 共同第一作者
  • 通讯作者:

    殷鹏飞    E-mail: yinpengfei@sicau.edu.cn

文章亮点

  • (1) 创新性地利用球磨方式辅助化学沉淀法合成Co@CuFe2O4前驱体。
  • (2) 通过后续的退火煅烧过程构建了Co@CuFe2O4吸波复合材料。
  • (3) 所制备Co@CuFe2O4吸波材料在1.72 mm厚度下具有6.74 GHz的有效吸波带宽。
  • 为解决日益增长的电磁辐射危害，利用球磨辅助化学沉淀-煅烧法制备了较低材料厚度下具有优异阻抗匹配性质的Co@CuFe2O4吸波剂。由于扁平状Co片与大量CuFe2O4粒子充分接触，所制备复合材料具有很好的界面极化能力。除了片状Co能提供优异的涡流损耗以外，偶极极化、电荷跃迁与传导、结构散射等同样有助于复合材料宽频吸波的实现。材料厚度仅为1.8 mm时，最大微波吸收损耗在频率为12.93 GHz处可达到−35.56 dB，且最宽的有效吸波带宽可在材料厚度为1.72 mm时达到6.74 GHz。文中所报道的制备方法可作为性能优异的电磁吸波剂的研制提供一种新型途径。
    • Research Article

    Innovative preparation of Co@CuFe2O4 composite via ball-milling assisted chemical precipitation and annealing for glorious electromagnetic wave absorption

    + Author Affiliations
      Abstract
    • To deal with the growing electromagnetic hazards, herein a Co@CuFe2O4 absorbing agent with excellent impedance matching at thin thickness was obtained via an innovative route of ball-milling assisted chemical precipitation and annealing. The as-prepared composite possesses excellent interface polarization ability due to sufficient contact between CuFe2O4 NPs and flat Co, and this compressed Co lamella can also provide sufficient eddy current loss. Moreover, the dipole polarization, electron hopping/conduction, and structural scattering also contribute to the broadband microwave absorption of the composite. Thus, the minimum microwave reflection loss achieves −35.56 dB at 12.93 GHz for 1.8 mm thickness, and the broadest efficient absorption bandwidth can reach 6.74 GHz for a thinner thickness of 1.72 mm. The preparation method reported here can be referenced as a new-type route to manufacture electromagnetic absorbers with outstanding performance.
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