留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
Volume 30 Issue 3
Mar.  2023
Turn off MathJax
目录

图(7)  / 表(1)

数据统计

分享

计量
  • 文章访问数:  734
  • HTML全文浏览量:  268
  • PDF下载量:  50
  • 被引次数: 0
文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(3): 515-524
Yuanyuan Zhou, Zhongyi Bai, Xiangyang Yang, Wei Liu, Bingbing Fan, Zhikai Yan, and Xiaoqin Guo, In-situ grown NiCo bimetal anchored on porous straw-derived biochar composites with boosted microwave absorption properties, Int. J. Miner. Metall. Mater., 30(2023), No. 3, pp. 515-524. https://doi.org/10.1007/s12613-022-2496-2
Cite this article as:
Yuanyuan Zhou, Zhongyi Bai, Xiangyang Yang, Wei Liu, Bingbing Fan, Zhikai Yan, and Xiaoqin Guo, In-situ grown NiCo bimetal anchored on porous straw-derived biochar composites with boosted microwave absorption properties, Int. J. Miner. Metall. Mater., 30(2023), No. 3, pp. 515-524. https://doi.org/10.1007/s12613-022-2496-2
shu
引用本文 PDF XML SpringerLink
研究论文

原位生长NiCo双金属增强多孔秸秆衍生生物碳复合材料的微波吸收性能

  • 1)

    郑州航空大学材料科学与工程学院河南省航空材料与应用技术重点实验室, 郑州 450046, 中国

  • 2)

    中国矿业大学 (北京)化学与环境工程学院,, 北京 100083, 中国

  • 3)

    郑州大学材料科学与工程学院, 郑州 450001, 中国

  • 通讯作者:

    范冰冰    E-mail: fanbingbing@zzu.edu.cn

    郭晓琴    E-mail: guoxq@zua.edu.cn

文章亮点

  • (1) 原位生长NiCo双金属增强多孔秸秆衍生生物碳复合材料可能成为有前途的微波吸收器。
  • (2) 通过水热法和退火工艺制备了具有出色的介电损耗和磁损耗的生物碳/镍钴复合材料。
  • (3) 生物碳/NiCo复合材料的最小反射损耗值在2.2 mm厚度下可达−27.0 dB，对应的吸收带宽(RL≤−10 dB)可达4.4 GHz (11.7~16.1 GHz)。
  • 目前，人们对电磁污染的保护意识逐渐增强，并且具有可再生性和环境友好性的吸收材料也引起人们的广泛关注。在这项工作中，通过高温碳化和水热反应的方法，我们成功制备了由秸秆衍生的生物碳与双金属NiCo组成的复合材料。通过改变镍钴合金的含量可以改变多孔生物碳/镍钴合金复合材料的电磁参数，改善其微波吸收性能。另外，其微波吸收性能的提高主要归功于电磁特性的协同效应，其中包括介电损耗（界面极化、偶极子极化）和磁损耗。值得注意的是，生物碳/NiCo复合材料的最小反射损耗值在2.2 mm厚度下可达−27.0 dB，对应的吸收带宽(RL≤−10 dB)可达4.4 GHz (11.7~16.1 GHz)。这些结果表明，多孔生物碳/镍钴复合材料具有密度低、重量轻、导电性好、吸收能力强、阻抗匹配良好等特点，因此，这种复合材料可以作为新一代的吸波材料。
    • Research Article

    In-situ grown NiCo bimetal anchored on porous straw-derived biochar composites with boosted microwave absorption properties

    + Author Affiliations
      Abstract
    • With the gradually increasing protection awareness about electromagnetic pollution, the demand for absorbing materials with renewability and environmental friendliness has attracted widespread attention. In this work, composites consisting of straw-derived biochar combined with NiCo alloy were successfully fabricated through high-temperature carbonization and subsequent hydrothermal reaction. The electromagnetic parameters of the porous biocarbon/NiCo composites can be effectively modified by altering their NiCo content, and their improved absorbing performance can be attributed to the synergy effect of magnetic–dielectric characteristics. An exceptional reflection loss of −27.0 dB at 2.2 mm thickness and an effective absorption bandwidth of 4.4 GHz (11.7–16.1 GHz) were achieved. These results revealed that the porous biocarbon/NiCo composites could be used as a new generation absorbing material because of their low density, light weight, excellent conductivity, and strong absorption.
      • FullText(HTML)
    • loading
      • Supplements(0)
      • References(57)
    • [1]
      P. Zhou, J.H. Chen, M. Liu, P. Jiang, B. Li, and X.M. Hou, Microwave absorption properties of SiC@SiO2@Fe3O4 hybrids in the 2–18 GHz range, Int. J. Miner. Metall. Mater., 24(2017), No. 7, p. 804. doi: 10.1007/s12613-017-1464-8
      [2]
      Y.F. Zhang, Z. Ji, K. Chen, C.C. Jia, S.W. Yang, and M.Y. Wang, Preparation and radar-absorbing properties of Al2O3/TiO2/Fe2O3/Yb2O3 composite powder, Int. J. Miner. Metall. Mater., 24(2017), No. 2, p. 216. doi: 10.1007/s12613-017-1398-1
      [3]
      H.L. Lv, Z.H. Yang, B. Liu, et al., A flexible electromagnetic wave-electricity harvester, Nat. Commun., 12(2021), No. 1, p. 1. doi: 10.1038/s41467-020-20314-w
      [4]
      Y. Li, Y.C. Qing, Y.F. Zhou, et al., Unique nanoporous structure derived from Co3O4–C and Co/CoO–C composites towards the ultra-strong electromagnetic absorption, Composites Part B, 213(2021), art. No. 108731. doi: 10.1016/j.compositesb.2021.108731
      [5]
      B. Zhao, X.Q. Guo, W.Y. Zhao, et al., Yolk–shell Ni@SnO2 composites with a designable interspace to improve the electromagnetic wave absorption properties, ACS Appl. Mater. Interfaces, 8(2016), No. 42, p. 28917. doi: 10.1021/acsami.6b10886
      [6]
      Q.H. Liu, Q. Cao, H. Bi, et al., CoNi@SiO2@TiO2 and CoNi@Air@TiO2 microspheres with strong wideband microwave absorption, Adv. Mater., 28(2016), No. 3, p. 486. doi: 10.1002/adma.201503149
      [7]
      J.W. Liu, R.C. Che, H.J. Chen, et al., Microwave absorption enhancement of multifunctional composite microspheres with spinel Fe3O4 cores and anatase TiO2 shells, Small, 8(2012), No. 8, p. 1214. doi: 10.1002/smll.201102245
      [8]
      B. Zhao, Y. Li, Q.W. Zeng, et al., Galvanic replacement reaction involving core-shell magnetic chains and orientation-tunable microwave absorption properties, Small, 16(2020), No. 40, art. No. 2003502. doi: 10.1002/smll.202003502
      [9]
      B. Zhao, X.Q. Guo, W.Y. Zhao, et al., Facile synthesis of yolk-shell Ni@void@SnO2(Ni3Sn2) ternary composites via galvanic replacement/Kirkendall effect and their enhanced microwave absorption properties, Nano Res., 10(2017), No. 1, p. 331. doi: 10.1007/s12274-016-1295-3
      [10]
      R.C. Che, L.M. Peng, X.F. Duan, Q. Chen, and X.L. Liang, Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes, Adv. Mater., 16(2004), No. 5, p. 401. doi: 10.1002/adma.200306460
      [11]
      B. Zhao, Y. Li, H.Y. Ji, et al., Lightweight graphene aerogels by decoration of 1D CoNi chains and CNTs to achieve ultra-wide microwave absorption, Carbon, 176(2021), p. 411. doi: 10.1016/j.carbon.2021.01.136
      [12]
      N. Zhang, Y. Huang, M.Y. Wang, X.D. Liu, and M. Zong, Design and microwave absorption properties of thistle-like CoNi enveloped in dielectric Ag decorated graphene composites, J. Colloid Interface Sci., 534(2019), p. 110. doi: 10.1016/j.jcis.2018.09.016
      [13]
      H. Wang, Y.Y. Dai, W.J. Gong, et al., Broadband microwave absorption of CoNi@C nanocapsules enhanced by dual dielectric relaxation and multiple magnetic resonances, Appl. Phys. Lett., 102(2013), No. 22, art. No. 223113. doi: 10.1063/1.4809675
      [14]
      Z.C. Lou, Q.Y. Wang, U.I. Kara, et al., Biomass-derived carbon heterostructures enable environmentally adaptive wideband electromagnetic wave absorbers, Nano Micro Lett., 14(2021), No. 1, p. 1.
      [15]
      Y. Liu, Z.R. Jia, Q.Q. Zhan, Y.H. Dong, Q.M. Xu, and G.L. Wu, Magnetic manganese-based composites with multiple loss mechanisms towards broadband absorption, Nano Res., 15(2022), No. 6, p. 5590. doi: 10.1007/s12274-022-4287-5
      [16]
      Y. Wu, R.W. Shu, Z.Y. Li, et al., Design and electromagnetic wave absorption properties of reduced graphene oxide/multi-walled carbon nanotubes/nickel ferrite ternary nanocomposites, J. Alloys Compd., 784(2019), p. 887. doi: 10.1016/j.jallcom.2019.01.139
      [17]
      H. Sun, R.C. Che, X. You, et al., Cross-stacking aligned carbon-nanotube films to tune microwave absorption frequencies and increase absorption intensities, Adv. Mater., 26(2014), No. 48, p. 8120. doi: 10.1002/adma.201403735
      [18]
      B. Zhao, J.S. Deng, C.X. Zhao, et al., Achieving wideband microwave absorption properties in PVDF nanocomposite foams with an ultra-low MWCNT content by introducing a microcellular structure, J. Mater. Chem. C, 8(2020), No. 1, p. 58. doi: 10.1039/C9TC04575A
      [19]
      T.S. Liu, N. Liu, S.R. Zhai, et al., Tailor-made core/shell/shell-like Fe3O4@SiO2@PPy composites with prominent microwave absorption performance, J. Alloys Compd., 779(2019), p. 831. doi: 10.1016/j.jallcom.2018.11.167
      [20]
      X.Y. Wu, B.Y. Han, H.B. Zhang, et al., Compressible, durable and conductive polydimethylsiloxane-coated MXene foams for high-performance electromagnetic interference shielding, Chem. Eng. J., 381(2020), art. No. 122622. doi: 10.1016/j.cej.2019.122622
      [21]
      X.L. Cao, Z.R. Jia, D.Q. Hu, and G.L. Wu, Synergistic construction of three-dimensional conductive network and double heterointerface polarization via magnetic FeNi for broadband microwave absorption, Adv. Compos. Hybrid Mater., 5(2022), No. 2, p. 1030. doi: 10.1007/s42114-021-00415-w
      [22]
      M.A. Aslam, W. Ding, S. ur Rehman, et al., Low cost 3D bio-carbon foams obtained from wheat straw with broadened bandwidth electromagnetic wave absorption performance, Appl. Surf. Sci., 543(2021), art. No. 148785. doi: 10.1016/j.apsusc.2020.148785
      [23]
      Y.Y. Wang, Z.H. Zhou, J.L. Zhu, et al., Low-temperature carbonized carbon nanotube/cellulose aerogel for efficient microwave absorption, Composites Part B, 220(2021), art. No. 108985. doi: 10.1016/j.compositesb.2021.108985
      [24]
      H.Q. Zhao, Y. Cheng, H.L. Lv, B.S. Zhang, G. Ji, and Y.W. Du, Achieving sustainable ultralight electromagnetic absorber from flour by turning surface morphology of nanoporous carbon, ACS Sustain. Chem. Eng., 6(2018), No. 11, p. 15850. doi: 10.1021/acssuschemeng.8b04461
      [25]
      X.X. Sun, M.L. Yang, S. Yang, et al., Ultrabroad band microwave absorption of carbonized waxberry with hierarchical structure, Small, 15(2019), No. 43, art. No. 1902974. doi: 10.1002/smll.201902974
      [26]
      G.J. Gou, F.B. Meng, H.G. Wang, M. Jiang, W. Wei, and Z.W. Zhou, Wheat straw-derived magnetic carbon foams: In-situ preparation and tunable high-performance microwave absorption, Nano Res., 12(2019), No. 6, p. 1423. doi: 10.1007/s12274-019-2376-x
      [27]
      H.Q. Zhao, Y. Cheng, J.N. Ma, Y.N. Zhang, G.B. Ji, and Y.W. Du, A sustainable route from biomass cotton to construct lightweight and high-performance microwave absorber, Chem. Eng. J., 339(2018), p. 432. doi: 10.1016/j.cej.2018.01.151
      [28]
      H.Q. Zhao, Y. Cheng, H.L. Lv, G.B. Ji, and Y.W. Du, A novel hierarchically porous magnetic carbon derived from biomass for strong lightweight microwave absorption, Carbon, 142(2019), p. 245. doi: 10.1016/j.carbon.2018.10.027
      [29]
      P.F. Yin, L.M. Zhang, Y.Y. Jiang, et al., Recycling of waste straw in sorghum for preparation of biochar/(Fe,Ni) hybrid aimed at significant electromagnetic absorbing of low-frequency band, J. Mater. Res. Technol., 9(2020), No. 6, p. 14212. doi: 10.1016/j.jmrt.2020.10.034
      [30]
      J. Cui, X.H. Wang, L. Huang, C.W. Zhang, Y. Yuan, and Y.B. Li, Environmentally friendly bark-derived Co-Doped porous carbon composites for microwave absorption, Carbon, 187(2022), p. 115. doi: 10.1016/j.carbon.2021.10.077
      [31]
      B. Zhao, G. Shao, B.B. Fan, W.Y. Zhao, Y.J. Xie, and R. Zhang, Synthesis of flower-like CuS hollow microspheres based on nanoflakes self-assembly and their microwave absorption properties, J. Mater. Chem. A, 3(2015), No. 19, p. 10345. doi: 10.1039/C5TA00086F
      [32]
      J. Feng, F.Z. Pu, Z.X. Li, X.H. Li, X.Y. Hu, and J.T. Bai, Interfacial interactions and synergistic effect of CoNi nanocrystals and nitrogen-doped graphene in a composite microwave absorber, Carbon, 104(2016), p. 214. doi: 10.1016/j.carbon.2016.04.006
      [33]
      L.L. Liang, Z.Q. Zhang, F. Song, et al., Ultralight, flexible carbon hybrid aerogels from bacterial cellulose for strong microwave absorption, Carbon, 162(2020), p. 283. doi: 10.1016/j.carbon.2020.02.045
      [34]
      H.L. Lv, Z.H. Yang, H.B. Xu, L.Y. Wang, and R.B. Wu, An electrical switch-driven flexible electromagnetic absorber, Adv. Funct. Mater., 30(2020), No. 4, art. No. 1907251. doi: 10.1002/adfm.201907251
      [35]
      Y.C. Qing, Y. Li, W. Li, and H.Y. Yao, Ti3+ self-doped dark TiO2 nanoparticles with tunable and unique dielectric properties for electromagnetic applications, J. Mater. Chem. C, 9(2021), No. 4, p. 1205. doi: 10.1039/D0TC05112H
      [36]
      X.F. Zhang, P.F. Guan, and X.L. Dong, Transform between the permeability and permittivity in the close-packed Ni nanoparticles, Appl. Phys. Lett., 97(2010), No. 3, art. No. 033107. doi: 10.1063/1.3464975
      [37]
      Z.X. Yu, N. Zhang, Z.P. Yao, X.J. Han, and Z.H. Jiang, Synthesis of hierarchical dendritic micro-nano structure CoxFe1−x alloy with tunable electromagnetic absorption performance, J. Mater. Chem. A, 1(2013), No. 40, p. 12462. doi: 10.1039/c3ta12840g
      [38]
      Z.C. Wu, K. Pei, L.S. Xing, X.F. Yu, W.B. You, and R.C. Che, Enhanced microwave absorption performance from magnetic coupling of magnetic nanoparticles suspended within hierarchically tubular composite, Adv. Funct. Mater., 29(2019), No. 28, art. No. 1901448. doi: 10.1002/adfm.201901448
      [39]
      R. Qiang, Y.C. Du, H.T. Zhao, et al., Metal organic framework-derived Fe/C nanocubes toward efficient microwave absorption, J. Mater. Chem. A, 3(2015), No. 25, p. 13426. doi: 10.1039/C5TA01457C
      [40]
      X. Wen, L.Z. Hou, L.W. Deng, D.T. Kuang, H. Luo, and S.L. Wang, Facile fabrication of extremely small CoNi/C core/shell nanoparticles for efficient microwave absorber, Nano, 14(2019), No. 7, art. No. 1950090. doi: 10.1142/S1793292019500905
      [41]
      H.L. Lv, Z.H. Yang, S.J.H. Ong, et al., A flexible microwave shield with tunable frequency-transmission and electromagnetic compatibility, Adv. Funct. Mater., 29(2019), No. 14, art. No. 1900163. doi: 10.1002/adfm.201900163
      [42]
      C. Zhang, C. Long, S. Yin, et al., Graphene-based anisotropic polarization meta-filter, Mater. Des., 206(2021), art. No. 109768. doi: 10.1016/j.matdes.2021.109768
      [43]
      Z.C. Lou, Q.Y. Wang, Y. Zhang, et al., In-situ formation of low-dimensional, magnetic core–shell nanocrystal for electromagnetic dissipation, Composites Part B, 214(2021), art. No. 108744. doi: 10.1016/j.compositesb.2021.108744
      [44]
      M.L. Yang, Y. Yuan, W.L. Yin, et al., Co/CoO@C nanocomposites with a hierarchical bowknot-like nanostructure for high performance broadband electromagnetic wave absorption, Appl. Surf. Sci., 469(2019), p. 607. doi: 10.1016/j.apsusc.2018.10.045
      [45]
      B.Y. Zhu, P. Miao, J. Kong, X.L. Zhang, G.Y. Wang, and K.J. Chen, Co/C composite derived from a newly constructed metal–organic framework for effective microwave absorption, Cryst. Growth Des., 19(2019), No. 3, p. 1518. doi: 10.1021/acs.cgd.9b00064
      [46]
      Z. Zheng, B. Xu, L. Huang, L. He, and X.M. Ni, Novel composite of Co/carbon nanotubes: Synthesis, magnetism and microwave absorption properties, Solid State Sci., 10(2008), No. 3, p. 316. doi: 10.1016/j.solidstatesciences.2007.09.016
      [47]
      F.S. Wen, F. Zhang, and Z.Y. Liu, Investigation on microwave absorption properties for multiwalled carbon nanotubes/Fe/Co/Ni nanopowders as lightweight absorbers, J. Phys. Chem. C, 115(2011), No. 29, p. 14025. doi: 10.1021/jp202078p
      [48]
      W. Liu, L. Liu, Z.H. Yang, J.J. Xu, Y.L. Hou, and G.B. Ji, A versatile route toward the electromagnetic functionalization of metal–organic framework-derived three-dimensional nanoporous carbon composites, ACS Appl. Mater. Interfaces, 10(2018), No. 10, p. 8965. doi: 10.1021/acsami.8b00320
      [49]
      X.M. Zhang, G.B. Ji, W. Liu, et al., Thermal conversion of an Fe3O4@metal–organic framework: A new method for an efficient Fe-Co/nanoporous carbon microwave absorbing material, Nanoscale, 7(2015), No. 30, p. 12932. doi: 10.1039/C5NR03176A
      [50]
      J. Lv, X.H. Liang, G.B. Ji, B. Quan, W. Liu, and Y.W. Du, Structural and carbonized design of 1D FeNi/C nanofibers with conductive network to optimize electromagnetic parameters and absorption abilities, ACS Sustainable Chem. Eng., 6(2018), No. 6, p. 7239. doi: 10.1021/acssuschemeng.7b03807
      [51]
      H.F. Qiu, X.Y. Zhu, P. Chen, J.L. Liu, and X.L. Zhu, Self-etching template method to synthesize hollow dodecahedral carbon capsules embedded with Ni–Co alloy for high-performance electromagnetic microwave absorption, Compos. Commun., 20(2020), art. No. 100354. doi: 10.1016/j.coco.2020.04.020
      [52]
      A. Das, P. Negi, S.K. Joshi, and A. Kumar, Enhanced microwave absorption properties of Co and Ni co-doped iron (II, III)/reduced graphene oxide composites at X-band frequency, J. Mater. Sci. Mater. Electron., 30(2019), No. 21, p. 19325. doi: 10.1007/s10854-019-02293-x
      [53]
      X.L. Wu, K. Liu, J.W. Ding, et al., Construction of Ni-based alloys decorated sucrose-derived carbon hybrid towards: Effective microwave absorption application, Adv. Compos. Hybrid Mater., 5(2022), 3, p. 2260. doi: 10.1007/s42114-021-00383-1
      [54]
      Z.B. Su, J. Tao, J.Y. Xiang, Y. Zhang, C. Su, and F.S. Wen, Structure evolution and microwave absorption properties of nickel nanoparticles incorporated carbon spheres, Mater. Res. Bull., 84(2016), p. 445. doi: 10.1016/j.materresbull.2016.08.036
      [55]
      H.L. Lv, Z.H. Yang, P.L. Wang, et al., A voltage-boosting strategy enabling a low-frequency, flexible electromagnetic wave absorption device, Adv. Mater., 30(2018), No. 15, art. No. 1706343. doi: 10.1002/adma.201706343
      [56]
      Y. Li, Y.C. Qing, B. Zhao, et al., Tunable magnetic coupling and dipole polarization of core-shell Magnéli Ti4O7 ceramic/magnetic metal possessing broadband microwave absorption properties, Ceram. Int., 47(2021), No. 23, p. 33373. doi: 10.1016/j.ceramint.2021.08.240
      [57]
      H. Du, Q.P. Zhang, B. Zhao, et al., Novel hierarchical structure of MoS2/TiO2/Ti3C2Tx composites for dramatically enhanced electromagnetic absorbing properties, J. Adv. Ceram., 10(2021), No. 5, p. 1042. doi: 10.1007/s40145-021-0487-9
      • Relative Articles
      Cited By

    Catalog


    • /

      返回文章
      返回

      版权所有 ©《矿物冶金与材料学报（英文）》编辑部

      地址：北京市海淀区学院路30号邮政编码：100083

      电子邮箱：journal@ustb.edu.cn电话：+86-10-62332875

      本系统由 北京仁和汇智信息技术有限公司 开发    百度统计