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Volume 30 Issue 1
Jan.  2023
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文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(1): 54-62
Nuo Xu, Zirui Yuan, Zhihong Ma, Xinli Guo, Yunfeng Zhu, Yongjin Zou, and Yao Zhang, Effects of highly dispersed Ni nanoparticles on the hydrogen storage performance of MgH2, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 54-62. https://doi.org/10.1007/s12613-022-2510-8
Cite this article as:
Nuo Xu, Zirui Yuan, Zhihong Ma, Xinli Guo, Yunfeng Zhu, Yongjin Zou, and Yao Zhang, Effects of highly dispersed Ni nanoparticles on the hydrogen storage performance of MgH2, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 54-62. https://doi.org/10.1007/s12613-022-2510-8
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研究论文

高分散性Ni纳米颗粒催化MgH2储氢性能研究

  • 1)

    东南大学材料科学与工程学院，南京 211189，中国

  • 2)

    百色学院材料科学与工程学院，百色 533000，中国

  • 3)

    南京工业大学材料科学与工程学院，南京 211189，中国

  • 4)

    桂林电子科技大学广西信息材料重点实验室，桂林 541004，中国

    • * 共同第一作者
  • 通讯作者:

    张耀    E-mail: zhangyao@seu.edu.cn

文章亮点

  • (1) 成功合成平均粒径仅为2.14 nm的Ni颗粒。
  • (2) 10wt%的Ni纳米颗粒的加入即可有效降低MgH2的脱氢焓。
  • (3) 纳米镍成为参与脱氢反应–催化脱氢反应的双功能添加剂，显著改善了MgH2的热力学和动力学性能。
  • 氢能是一种清洁高效的二次能源，有希望从根本上解决人类面临的生态环境危机以及化石能源枯竭问题。在固态储氢材料中，MgH2因其重量轻、储量丰富、无毒、储氢容量大而备受关注，是一种很有前途的储氢材料。但是，它也存在着热稳定性高和动力学迟缓的问题。本文采用多元醇还原法制备了平均尺寸为2.14 nm的高度分散的Ni纳米颗粒，系统的研究了Ni纳米颗粒对MgH2体系的影响，以及Ni纳米颗粒对MgH2体系的催化机理。研究表明Ni纳米颗粒可以显著提高MgH2体系的储氢性能。样品MgH2–10wt% nano-Ni可以在温度达到497 K时开始释放H2，在温度为583 K时完全脱氢，脱氢量为6.2wt%；此外，该样品在温度为482 K，氢压3 MPa的条件下，1000 s内可逆吸附容量达到5.3wt%。通过室温至673 K的原位XRD测试发现脱氢反应中出现了Mg2Ni和Ni相；而在吸氢样品的透镜图中，发现了Mg2NiH4与Ni相。此外金属Ni纳米颗粒同时会作为催化剂诱导MgH2的分解与吸附。Ni纳米颗粒会导致MgH2体系的降稳，此现象可通过PCI曲线和范特霍夫方程式计算验证。本文这一发现表明Ni纳米颗粒作为一种双功能的添加剂能够显著改善MgH2体系的动力学和热力学性能。
    • Research Article

    Effects of highly dispersed Ni nanoparticles on the hydrogen storage performance of MgH2

    + Author Affiliations
      Abstract
    • MgH2 with a large hydrogen capacity is regarded as a promising hydrogen storage material. However, it still suffers from high thermal stability and sluggish kinetics. In this paper, highly dispersed nano-Ni has been successfully prepared by using the polyol reduction method with an average size of 2.14 nm, which significantly improves the de/rehydrogenation properties of MgH2. The MgH2–10wt% nano-Ni sample starts releasing H2 at 497 K, and roughly 6.2wt% H2 has been liberated at 583 K. The rehydrogenation kinetics of the sample are also greatly improved, and the adsorption capacity reaches 5.3wt% H2 in 1000 s at 482 K and under 3 MPa hydrogen pressure. Moreover, the activation energies of de/rehydrogenation of the MgH2–10wt% nano-Ni sample are reduced to (88 ± 2) and (87 ± 1) kJ·mol−1, respectively. In addition, the thermal stability of the MgH2–10wt% nano-Ni system is reduced by 5.5 kJ per mol H2 from that of pristine MgH2. This finding indicates that nano-Ni significantly improves both the thermodynamic and kinetic performances of the de/rehydrogenation of MgH2, serving as a bi-functional additive of both reagent and catalyst.
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