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Volume 30 Issue 3
Mar.  2023
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文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(3): 485-493
Rao Zhang, Congpu Mu, Bochong Wang, Jianyong Xiang, Kun Zhai, Tianyu Xue, and Fusheng Wen, Composites of In/C hexagonal nanorods and graphene nanosheets for high-performance electromagnetic wave absorption, Int. J. Miner. Metall. Mater., 30(2023), No. 3, pp. 485-493. https://doi.org/10.1007/s12613-022-2520-6
Cite this article as:
Rao Zhang, Congpu Mu, Bochong Wang, Jianyong Xiang, Kun Zhai, Tianyu Xue, and Fusheng Wen, Composites of In/C hexagonal nanorods and graphene nanosheets for high-performance electromagnetic wave absorption, Int. J. Miner. Metall. Mater., 30(2023), No. 3, pp. 485-493. https://doi.org/10.1007/s12613-022-2520-6
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研究论文

In/C六边形纳米棒和石墨烯纳米片复合物的电磁波吸收性能研究

  • 1)

    燕山大学亚稳材料料制备技术与科学国家重点实验室, 秦皇岛066004, 中国

  • 2)

    燕山大学理学院河北省微结构材料物理重点实验室, 秦皇岛066004, 中国

  • 通讯作者:

    牟从普    E-mail: congpumu@ysu.edu.cn

    温福昇    E-mail: wenfsh03@126.com

文章亮点

  • (1) 低温(450°C)热解金属有机骨架获得尺寸均匀地六边形纳米棒。
  • (2) 在1.14 mm厚度下，In/C-Gr复合材料的有效吸收带宽达到3.7 GHz。
  • (3) In/C-Gr复合材料对电磁波的最小反射损耗可以达到−43.7 dB。
  • 近年来，随着智能电子设备和高频无线通信技术的高速发展，电磁波辐射和污染问题受到越来越多的关注。如何消除电磁波辐射和污染已经成为当代研究的热点问题之一。电磁波吸收是解决电磁波辐射和污染的有效手段之一。金属有机骨架由于其密度低、机构新颖以及易制备等优点有利于电磁波吸收而被广泛地研究。在本文中，通过低温(450°C)热解金属铟有机骨架获得金属铟纳米颗粒/多孔碳(In/C)六边形纳米棒复合物。由于低的热解温度，使得In/C纳米棒电导率较低，从而导致对电磁波的介电损耗低。因此，为了提高In/C纳米棒的电导率，通过引入高电导率的石墨烯(graphene, Gr)纳米片来调节In/C纳米棒的电磁波吸收性能。研究结果表明，Gr纳米片的引入可以有效地改善In/C纳米棒的电磁参数，从而实现对电磁波的高效吸收。在1.30 mm厚度下，In/C-Gr-4复合材料对电磁波的最小反射损耗可以达到-43.7 dB。当厚度减小到1.14 mm时，In/C-Gr-4复合材料的最小反射损耗仍高达-39.3 dB，并且有效吸收带宽为3.7 GHz (从14.3到18.0 GHz)。因此，本工作表明In/C-Gr-4复合材料具有优异的电磁波吸收性能(即薄厚度下高的反射损耗和宽的有效吸收带宽)。
    • Research Article

    Composites of In/C hexagonal nanorods and graphene nanosheets for high-performance electromagnetic wave absorption

    + Author Affiliations
      Abstract
    • In recent years, electromagnetic wave (EMW) absorption has been extensively investigated for solving EMW radiation and pollution. The metal–organic frameworks (MOFs) have attracted attention due to their low density and unique structure, which can meet the requirements of strong reflection loss (RL) and wide absorption bandwidth of EMW absorption materials. In this manuscript, indium nanoparticles/porous carbon (In/C) nanorods composites were prepared via the pyrolysis of nanorods-like In-MOFs at a low temperature of 450°C. Indium nanoparticles are evenly attached and embedded on porous carbon. Low electrical conductivity of In/C nanorods is unfavorable to EMW absorption performance, which is due to the low temperature carbonization. Thus, graphene (Gr) nanosheets with high electrical conductivity are introduced to adjust electromagnetic parameters of In/C nanorods for enhancing EMW absorption. The minimum RL of the In/C-Gr-4 composite is up to −43.7 dB with a thin thickness of 1.30 mm. In addition, when the thickness is further reduced to 1.14 mm, the minimum RL of −39.3 dB at 16.1 GHz and effective absorption bandwidth of 3.7 GHz (from 14.3 to 18.0 GHz) can be achieved. This work indicates that In/C-Gr composites show excellent EMW absorption performance.
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