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Volume 30 Issue 3
Mar.  2023
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文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(3): 494-503
Shipeng Wang, Ziyan Liu, Qiangchun Liu, Baojun Wang, Wei Wei, Hao Wu, Zijie Xu, Shikuo Li, Fangzhi Huang, and Hui Zhang, Promoting the microwave absorption performance of hierarchical CF@NiO/Ni composites via phase and morphology evolution, Int. J. Miner. Metall. Mater., 30(2023), No. 3, pp. 494-503. https://doi.org/10.1007/s12613-022-2524-2
Cite this article as:
Shipeng Wang, Ziyan Liu, Qiangchun Liu, Baojun Wang, Wei Wei, Hao Wu, Zijie Xu, Shikuo Li, Fangzhi Huang, and Hui Zhang, Promoting the microwave absorption performance of hierarchical CF@NiO/Ni composites via phase and morphology evolution, Int. J. Miner. Metall. Mater., 30(2023), No. 3, pp. 494-503. https://doi.org/10.1007/s12613-022-2524-2
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研究论文

通过物相和形貌演变提升多级结构CF@NiO/Ni复合材料的吸波性能

  • 1)

    安徽大学材料科学与工程学院, 合肥 230601, 中国

  • 2)

    杂化材料结构与功能调控教育部重点实验室, 安徽大学, 合肥 230601, 中国

  • 3)

    安徽大学化学与化工学院, 合肥 230601, 中国

  • 4)

    淮北师范大学物理与电子信息学院, 淮北235000, 中国

  • 通讯作者:

    李士阔    E-mail: lishikuo@ahu.edu.cn

    黄方志    E-mail: huangfangzhi@163.com

    张惠    E-mail: zhhui@ahu.edu.cn

文章亮点

  • (1) 采用简单的退火工艺成功实现了NiO/Ni体系的物相结构和形貌调控。 (2) 系统研究了CF@NiO/Ni复合材料物相结构和形貌演变对吸波性能的影响。 (3) 当填充量为3wt%时，CF@NiO/Ni-500 复合材料获得了最小反射损耗−43.9 dB，有效吸收带宽为5.64 GHz。
  • 轻质和高效的碳基微波吸收剂在解决日益严重的电磁污染方面具有重要意义。为了解决单一碳纤维材料阻抗匹配差和损耗机制单一的缺点，本文采用水热法和退火处理方法，在碳纤维上原位制备了具有可调控物相和形貌的多级结构NiO/Ni纳米片阵列。结果表明，随着退火温度的增加，NiO/Ni体系中金属Ni的含量增加不仅增强了磁损耗同时也改善了阻抗匹配。另外，NiO/Ni纳米片呈现出明显的多孔结构。NiO/Ni、NiO/C、 Ni/C丰富的界面结构有助于极化损耗的增强。得益于三维导电网络、多级异质结构、强偶极子/界面极化、多重散射和良好的阻抗匹配等优点，最佳样品CF@NiO/Ni-500仅在3wt%填充量下，最小反射损耗达到-43.9 dB，有效的吸收带宽高达5.64 GHz。此外，雷达散射截面的仿真结果表明CF@NiO/Ni复合涂层能够有效抑制电磁波散射。本研究不仅丰富了碳纤维基吸波材料的结构设计与调控研究，也为碳基吸波材料的轻质宽频研究提供了新思路。
    • Research Article

    Promoting the microwave absorption performance of hierarchical CF@NiO/Ni composites via phase and morphology evolution

    + Author Affiliations
      Abstract
    • Lightweight and efficient carbon-based microwave absorbents are significant in addressing the increasing severity of electromagnetic pollution. In this study, hierarchical NiO/Ni nanosheets with a tuneable phase and morphology supported on a carbon fiber substrate (CF@NiO/Ni) were fabricated using a hydrothermal approach and post-annealing treatment. As the annealing temperature increases, more metallic Ni is formed, and an apparent porosity appears on the sheet surface. Benefiting from the advantages of a three-dimensional (3D) conducting network, hierarchical porous structure, reinforced dipole/interface polarization, multiple scattering, and good impedance matching, the CF@NiO/Ni-500 composite exhibits an excellent microwave absorption performance even at a filling rate of only 3wt%. Specifically, its minimal reflection loss is −43.92 dB, and the qualified bandwidth is up to 5.64 GHz. In addition, the low radar cross-section area of the CF@NiO/Ni composite coating confirms its strong ability to suppress electromagnetic wave scattering. We expect that this work could contribute to a deeper understanding of the phase and morphology evolution in enhancing microwave absorption.
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