面向海工装备耐磨部件的Ti–C–N复合薄膜不同环境条件的摩擦磨损性能

鞠洪博; 周锐; 栾静; Ch Sateesh Kumar; 喻利花; 许俊华; 杨俊峰; 张博威; Filipe Fernandes

doi:10.1007/s12613-022-2551-z

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(1): 144-155

Hongbo Ju, Rui Zhou, Jing Luan, Ch Sateesh Kumar, Lihua Yu, Junhua Xu, Junfeng Yang, Bowei Zhang, and Filipe Fernandes, Tribological performance under different environments of Ti–C–N composite films for marine wear-resistant parts, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 144-155. https://doi.org/10.1007/s12613-022-2551-z

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Hongbo Ju, Rui Zhou, Jing Luan, Ch Sateesh Kumar, Lihua Yu, Junhua Xu, Junfeng Yang, Bowei Zhang, and Filipe Fernandes, Tribological performance under different environments of Ti–C–N composite films for marine wear-resistant parts, Int. J. Miner. Metall. Mater., 30(2023), No. 1, pp. 144-155. https://doi.org/10.1007/s12613-022-2551-z

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研究论文

面向海工装备耐磨部件的Ti–C–N复合薄膜不同环境条件的摩擦磨损性能

1)
江苏科技大学材料科学与工程学院，镇江 212003，中国
2)
CEMMPRE—Centre for Mechanical Engineering Materials and Processes, Department of Mechanical Engineering, University of Coimbra, Coimbra 3030-788, Portugal
3)
Center for Aeronautics Advanced Manufacturing, University of the Basque Country UPV/EHU, Bilbao 48170, Spain
4)
ISEP-School of Engineering, Polytechnic of Porto, Porto 4200-072, Portugal
5)
中国科学院合肥物理研究所固体物理研究所，合肥 230031，中国
6)
北京科技大学先进材料与技术研究所，北京 100083，中国

通讯作者:
鞠洪博    E-mail: hbju@just.edu.cn

许俊华    E-mail: jhxu@just.edu.cn

杨俊峰    E-mail: jfyang@issp.ac.cn

文章亮点

(1) 系统地研究了C含量对Ti–C–N复合薄膜微观组织的影响规律。

(2) 揭示了C对Ti–C–N复合薄膜空气和水环境下的减摩和耐磨行为的影响。

(3) 基于微电池理论获得了Ti–C–N复合薄膜海水环境耐磨损行为规律。

中文摘要

海洋对人类社会文明和进步产生着重大影响，而如何利用表面工程技术提升海工装备关键部件多环境条件下的高效、持续减摩和耐磨性能以满足近海绿色可替代能源开发、远洋捕捞以及深海资源钻探需求是近年来摩擦学领域的热点问题之一。本文利用多靶共聚焦反应磁控溅射技术设计并制备出了一系列不同碳（C）含量的Ti–C–N自润滑复合薄膜材料，研究了其在空气、水以及海水环境下的摩擦磨损行为，揭示了各环境条件下因薄膜各相交互作用而产生的润滑、耐磨规律。主要研究结果表明，C的添加诱发非晶相（amorphous, a）的产生，导致薄膜两相共存，为面心立方（face-centered cubic, fcc）TiN+a-C。复合薄膜(<19.1at% C)中具有优异润滑性能的a-C相显著提升了其在空气和水环境下的摩擦磨损性能，但C含量的进一步升高降低了薄膜的力学性能，最终导致薄膜摩擦磨损性能有所降低。海水摩擦环境下，因a-C于fcc-TiN间产生微区原电池而使TiN相优先腐蚀，大量磨蚀产物黏附在磨痕表层，从而极大提升了薄膜的耐磨损性能。

关键词:

Research Article

Tribological performance under different environments of Ti–C–N composite films for marine wear-resistant parts

+ Author Affiliations

1)
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China
2)
CEMMPRE—Centre for Mechanical Engineering Materials and Processes, Department of Mechanical Engineering, University of Coimbra, Coimbra 3030-788, Portugal
3)
CFAA, University of the Basque Country UPV/EHU, Bilbao 48170, Spain
4)
ISEP-School of Engineering, Polytechnic of Porto, Porto 4200-072, Portugal
5)
Key Laboratory of Materials Physic, Institute of Solid State Physics, Hefei Institute of Physical Sciences, Chinese Academy of Sciences, Hefei 230031, China
6)
Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China

Corresponding authors:
Hongbo Ju    E-mail: hbju@just.edu.cn

Junhua Xu    E-mail: jhxu@just.edu.cn

Junfeng Yang    E-mail: jfyang@issp.ac.cn
Received: 26 July 2022; Revised: 3 September 2022; Accepted: 14 September 2022; Available online: 16 September 2022

Abstract

Abstract

The need for reducing the wear in mechanical parts used in the industry makes self-lubricant films one of the sustainable solutions to achieve long-term protection under different environmental conditions. The purpose of this work is to study the influence of C additions on the tribological behavior of a magnetron-sputtered TiN film in air, water, and seawater. The results show that the addition of C into the TiN binary film induced a new amorphous phase, and the films exhibited a dual phase of fcc (face-centered cubic)-TiN and amorphous carbon. The antifriction and wear-resistance properties were enhanced in air and water by adding 19.1at% C. However, a further increase in the C concentration improved anti-frictional properties but also led to higher wear rates. Although the amorphous phase induced microbatteries and accelerated the corrosion of TiN phases in seawater, the negative abrasion state was detected for all Ti–C–N films due to the adhesion of the tribocorrosion debris on the wear track.
- RF reactive magnetron sputtering;
- Ti–C–N films;
- microstructure;
- tribological properties in air/water/seawater

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[1]	R. Grinon-Echaniz, P. Refait, M. Jeannin, et al., Study of cathodic reactions in defects of thermal spray aluminium coatings on steel in artificial seawater, Corros. Sci., 187(2021), art. No. 109514. doi: 10.1016/j.corsci.2021.109514
[2]	D.P. Wang, G. Chen, A.D. Wang, et al., Corrosion behavior of single- and poly-crystalline dual-phase TiAl–Ti₃Al alloy in NaCl solution, Int. J. Miner. Metall. Mater., 2022. DOI: 10.1007/s12613-022-2513-5
[3]	H.S. Wu, G.Z. Shen, R.X. Li, et al., Influence of embedded reduced graphene oxide on the corrosion-wear performance of cold sprayed Zn-rGO/Al coating in NaCl solution, Surf. Coat. Technol., 429(2022), art. No. 127856. doi: 10.1016/j.surfcoat.2021.127856
[4]	D. Saran, A. Kumar, S. Bathula, D. Klaumünzer, and K.K. Sahu, Review on the phosphate-based conversion coatings of magnesium and its alloys, Int. J. Miner. Metall. Mater., 29(2022), No. 7, p. 1435. doi: 10.1007/s12613-022-2419-2
[5]	M.D. Zhang, F. Zhou, Y.J. Wu, Q.Z. Wang, and Z.F. Zhou, Microstructure and electrochemical characteristics of CrMoN/Ag nanocomposite coatings in seawater, Surf. Coat. Technol., 441(2022), art. No. 128551. doi: 10.1016/j.surfcoat.2022.128551
[6]	H.B. Ju, D. Yu, J.H. Xu, et al., Crystal structure and tribological properties of ZrAlMoN composite films deposited by magnetron sputtering, Mater. Chem. Phys., 230(2019), p. 347. doi: 10.1016/j.matchemphys.2019.03.071
[7]	W. Liu, J.X. Li, H.Y. Xu, J. Li, and X.P. Qiu, Stabilized cobalt-free lithium-rich cathode materials with an artificial lithium fluoride coating, Int. J. Miner. Metall. Mater., 29(2022), No. 5, p. 917. doi: 10.1007/s12613-022-2483-7
[8]	H.B. Ju, D. Yu, L.H. Yu, et al., The influence of Ag contents on the microstructure, mechanical and tribological properties of ZrN–Ag films, Vacuum, 148(2018), p. 54. doi: 10.1016/j.vacuum.2017.10.029
[9]	H.B. Ju, D. Yu, J.H. Xu, et al., Microstructure, mechanical, and tribological properties of niobium vanadium carbon nitride films, J. Vac. Sci. Technol. A, 36(2018), No. 3, art. No. 031511. doi: 10.1116/1.5020954
[10]	R. Wang, J.X. Deng, Z.H. Zhang, et al., Microstructure and wear performance of electro-sprayed self-lubricating Ni₃Al/Cr₃C₂–MoS₂ composite films, Surf. Coat. Technol., 428(2021), art. No. 127862. doi: 10.1016/j.surfcoat.2021.127862
[11]	H.B. Ju, N. Ding, J.H. Xu, et al., Improvement of tribological properties of niobium nitride films via copper addition, Vacuum, 158(2018), p. 1. doi: 10.1016/j.vacuum.2018.09.037
[12]	Y.J. Tarzanagh, D. Seifzadeh, and R. Samadianfard, Combining the 8-hydroxyquinoline intercalated layered double hydroxide film and sol–gel coating for active corrosion protection of the magnesium alloy, Int. J. Miner. Metall. Mater., 29(2022), No. 3, p. 536. doi: 10.1007/s12613-021-2251-0
[13]	R. Zhou, H.B. Ju, S.J. Liu, et al., The influences of Ag content on the friction and wear properties of TiCN–Ag films, Vacuum, 196(2022), art. No. 110719. doi: 10.1016/j.vacuum.2021.110719
[14]	Y. Xia, Z.G. Xu, J. Peng, Q. Shen, and C.B. Wang, In-situ formation, structural transformation and mechanical properties CrN coatings prepared by MPCVD, Surf. Coat. Technol., 441(2022), art. No. 128522. doi: 10.1016/j.surfcoat.2022.128522
[15]	R. Akhter, Z.F. Zhou, Z.H. Xie, and P. Munroe, TiN versus TiSiN coatings in indentation, scratch and wear setting, Appl. Surf. Sci., 563(2021), art. No. 150356. doi: 10.1016/j.apsusc.2021.150356
[16]	M. Jafari, L. Rogström, J.M. Andersson, et al., Thermal degradation of TiN and TiAlN coatings during rapid laser treatment, Surf. Coat. Technol., 422(2021), art. No. 127517. doi: 10.1016/j.surfcoat.2021.127517
[17]	H.B. Ju, R. Zhou, S.J. Liu, et al., Enhancement of the tribological behavior of self-lubricating nanocomposite Mo₂N/Cu films by adding the amorphous SiN_x, Surf. Coat. Technol., 423(2021), art. No. 127565. doi: 10.1016/j.surfcoat.2021.127565
[18]	H.B. Ju, N. Ding, J.H. Xu, et al., The tribological behavior of niobium nitride and silver composite films at elevated testing temperatures, Mater. Chem. Phys., 237(2019), art. No. 121840. doi: 10.1016/j.matchemphys.2019.121840
[19]	C.K. Liu, H.B. Ju, J.H. Xu, et al., Influence of copper on the compositions, microstructure and room and elevated temperature tribological properties of the molybdenum nitride film, Surf. Coat. Technol., 395(2020), art. No. 125811. doi: 10.1016/j.surfcoat.2020.125811
[20]	H.B. Ju, R. Wang, W.X. Wang, et al., The microstructure and tribological properties of molybdenum and silicon nitride composite films, Surf. Coat. Technol., 401(2020), art. No. 126238. doi: 10.1016/j.surfcoat.2020.126238
[21]	H.B. Ju, N. Ding, J.H. Xu, et al., The influence of crystal structure and the enhancement of mechanical and frictional properties of titanium nitride film by addition of ruthenium, Appl. Surf. Sci., 489(2019), p. 247. doi: 10.1016/j.apsusc.2019.05.251
[22]	S.Q. Song, X.F. Cui, G. Jin, et al., Effect of N + Cr ions implantation on corrosion and tribological properties in simulated seawater of carburized alloy steel, Surf. Coat. Technol., 385(2020), art. No. 125357. doi: 10.1016/j.surfcoat.2020.125357
[23]	Y.Q. Fu, F. Zhou, and M.D. Zhang, The enhancement of individual friction and corrosion properties of CrSiN coatings by Mo doping in seawater, Surf. Coat. Technol., 432(2022), art. No. 128069. doi: 10.1016/j.surfcoat.2021.128069
[24]	P. Zhang, L. Shan, X.L. Su, et al., Microstructure and tribological performance of CrTiSiCN coatings on 316L and TC4 in seawater, Tribol. Int., 156(2021), art. No. 106832. doi: 10.1016/j.triboint.2020.106832
[25]	J. Takadoum, H.H. Bennani, and M. Allouard, Friction and wear characteristics of TiN, TiCN and diamond-like carbon films, Surf. Coat. Technol., 88(1997), No. 1-3, p. 232. doi: 10.1016/S0257-8972(96)02905-2
[26]	C.K. Liu, H.B. Ju, P.X. Han, et al., The influence of carbon content on the microstructure, mechanical and frictional property of chromium carbon nitride composite films, Vacuum, 178(2020), art. No. 109368. doi: 10.1016/j.vacuum.2020.109368
[27]	X.R. Deng, H. Kousaka, T. Tokoroyama, and N. Umehara, Tribological behavior of tetrahedral amorphous carbon (ta-C) coatings at elevated temperatures, Tribol. Int., 75(2014), p. 98. doi: 10.1016/j.triboint.2014.04.002
[28]	G.F. Zheng, Q. Jiao, C. Li, et al., Influence of nitridation on the microstructure and corrosion behavior of reactive plasma sprayed TiCN coatings, Surf. Coat. Technol., 396(2020), art. No. 125954. doi: 10.1016/j.surfcoat.2020.125954
[29]	H.B. Ju, R. Wang, N. Ding, et al., Improvement on the oxidation resistance and tribological properties of molybdenum disulfide film by doping nitrogen, Mater. Des., 186(2020), art. No. 108300. doi: 10.1016/j.matdes.2019.108300
[30]	Y.H. Cheng, T. Browne, B. Heckerman, and E.I. Meletis, Influence of the C content on the mechanical and tribological properties of the TiCN coatings deposited by LAFAD technique, Surf. Coat. Technol., 205(2011), No. 16, p. 4024. doi: 10.1016/j.surfcoat.2011.02.032
[31]	B. Yi, S.H. Zhou, Z.G. Qiu, and D.C. Zeng, The influences of pulsed bias duty cycle on tribological properties of solid lubricating TiMoCN coatings, Vacuum, 180(2020), art. No. 109552. doi: 10.1016/j.vacuum.2020.109552
[32]	H.B. Ju, R. Zhou, J. Luan, et al., Multilayer Mo₂N–Ag/SiN_x films for demanding applications: Morphology, structure and temperature-cucling tribological properties, Mater. Des., 223(2022), art. No. 111128. doi: 10.1016/j.matdes.2022.111128
[33]	J.G. Qian, S.X. Li, J.B. Pu, et al., Effect of heat treatment on structure and properties of molybdenum nitride and molybdenum carbonitride films prepared by magnetron sputtering, Surf. Coat. Technol., 374(2019), p. 725. doi: 10.1016/j.surfcoat.2019.06.062
[34]	D. Özkan, M.A. Yılmaz, C. Erdem, et al., Wear and friction behavior of CrTiN/TiCN and CrTiN/CrCN multilayer composite coatings, Ceram. Int., 48(2022), No. 10, p. 13732. doi: 10.1016/j.ceramint.2022.01.254
[35]	H.Q. Wang, Y. Ou, X. Zhang, et al., Tribocorrosion behaviors of TiSiCN nanocomposite coatings deposited by high power impulse magnetron sputtering, Mater. Res. Express, 7(2020), art. No. 076407. doi: 10.1088/2053-1591/ab95d4
[36]	O. Savchuk and A.A. Volinsky, Nonparametric estimation of SiC film residual stress from the wafer surface profile, Measurement, 177(2021), art. No. 109238. doi: 10.1016/j.measurement.2021.109238
[37]	N. Madaoui, N. Saoula, B. Zaid, D. Saidi, and A.S. Ahmed, Structural, mechanical and electrochemical comparison of TiN and TiCN coatings on XC48 steel substrates in NaCl 3.5% water solution, Appl. Surf. Sci., 312(2014), p. 134. doi: 10.1016/j.apsusc.2014.04.167
[38]	P.B. Mi, J.N. He, Y.F. Qin, and K. Chen, Nanostructure reactive plasma sprayed TiCN coating, Surf. Coat. Technol., 309(2017), p. 1. doi: 10.1016/j.surfcoat.2016.11.033
[39]	J.C. Sánchez-López, M.D. Abad, I. Carvalho, et al., Influence of silver content on the tribomechanical behavior on Ag–TiCN bioactive coatings, Surf. Coat. Technol., 206(2012), No. 8-9, p. 2192. doi: 10.1016/j.surfcoat.2011.09.059
[40]	R. Chen, J.P. Tu, D.G. Liu, Y.J. Mai, and C.D. Gu, Microstructure, mechanical and tribological properties of TiCN nanocomposite films deposited by DC magnetron sputtering, Surf. Coat. Technol., 205(2011), No. 21-22, p. 5228. doi: 10.1016/j.surfcoat.2011.05.034
[41]	X.X. Liu, N. Umehara, T. Tokoroyama, and M. Murashima, Tribological properties of ta-CN_x coating sliding against steel and sapphire in unlubricated condition, Tribol. Int., 131(2019), p. 102. doi: 10.1016/j.triboint.2018.10.022
[42]	Y.F. Qin, G.F. Zheng, L.Y. Zhu, et al., Structure and wear characteristics of TiCN nanocomposite coatings fabricated by reactive plasma spraying, Surf. Coat. Technol., 342(2018), p. 137. doi: 10.1016/j.surfcoat.2018.02.108
[43]	F.Y. Yan, B.L. Jiang, Z.Y. Wang, et al., Thermal stabilization of nanocrystalline promoting conductive corrosion resistance of TiN–Ag films for metal bipolar plates, Vacuum, 195(2022), art. No. 110631. doi: 10.1016/j.vacuum.2021.110631
[44]	H. Cicek, Wear behaviors of TiN/TiCN/DLC composite coatings in different environments, Ceram. Int., 44(2018), No. 5, p. 4853. doi: 10.1016/j.ceramint.2017.12.074
[45]	H.B. Ju, L.H. Yu, S. He, et al., The enhancement of fracture toughness and tribological properties of the titanium nitride films by doping yttrium, Surf. Coat. Technol., 321(2017), p. 57. doi: 10.1016/j.surfcoat.2017.04.053
[46]	H.B. Ju and J.H. Xu, Microstructure, oxidation resistance, mechanical and tribological properties of Ti–Y–N films by reactive magnetron sputtering, Surf. Coat. Technol., 283(2015), p. 311. doi: 10.1016/j.surfcoat.2015.10.068
[47]	C.K. Liu, H. Ju, L.H. Yu, et al., Tribological properties of Mo₂N films at elevated temperature, Coatings, 9(2019), No. 11, p. 734. doi: 10.3390/coatings9110734
[48]	A. Erdemir, A crystal chemical approach to the formulation of self-lubricating nanocomposite coatings, Surf. Coat. Technol., 200(2005), No. 5-6, p. 1792. doi: 10.1016/j.surfcoat.2005.08.054
[49]	T.W.B. Riyadi, D. Setiadhi, A.D. Anggono, W.A. Siswanto, and H.H. Al-Kayiem, Analysis of mechanical and thermal stresses due to TiN coating of Fe substrate by physical vapor deposition, Forces Mech., 4(2021), art. No. 100042. doi: 10.1016/j.finmec.2021.100042
[50]	S.G. Ai, H.L. Fu, R.J. He, and Y.M. Pei, Multi-scale modeling of thermal expansion coefficients of C/C composites at high temperature, Mater. Des., 82(2015), p. 181. doi: 10.1016/j.matdes.2015.05.061
[51]	J.J. Wang and F.Y. Ouyang, Nanotwinned medium entropy alloy CoCrFeNi thin films with ultra-high hardness: Modifying residual stress without scarifying hardness through tuning substrate bias, Surf. Coat. Technol., 434(2022), art. No. 128191. doi: 10.1016/j.surfcoat.2022.128191
[52]	Y.H. Lu and Y.G. Shen, Effect of carbon content on thermal stability of Ti–C_x–N_y thin films, J. Mater. Res., 23(2008), No. 3, p. 671. doi: 10.1557/JMR.2008.0082
[53]	Y.X. Ou, H.Q. Wang, Q.S. Hua, B. Liao, and X.P. Ouyang, Tribocorrosion behaviors of superhard yet tough Ti–C–N ceramic coatings, Surf. Coat. Technol., 439(2022), art. No. 128448. doi: 10.1016/j.surfcoat.2022.128448
[54]	R.Z. Li, S.H. Wang, J.B. Pu, et al., Study of NaCl-induced hot-corrosion behavior of TiN single-layer and TiN/Ti multilayer coatings at 500°C, Corros. Sci., 192(2021), art. No. 109838. doi: 10.1016/j.corsci.2021.109838
[55]	I. Dreiling, A. Haug, H. Holzschuh, and T. Chassé, Raman spectroscopy as a tool to study cubic Ti–C–N CVD coatings, Surf. Coat. Technol., 204(2009), No. 6-7, p. 1008. doi: 10.1016/j.surfcoat.2009.05.029
[56]	L. Shan, Y.X. Wang, J.L. Li, et al., Tribological behaviours of PVD TiN and TiCN coatings in artificial seawater, Surf. Coat. Technol., 226(2013), p. 40. doi: 10.1016/j.surfcoat.2013.03.034
[57]	K.L. Ming, Z.H. Zhang, and H.B. Li, In situ growth of NaTiO₂ nanotubes on Ti₃C₂F_x for enhanced sodium ion batteries, Mater. Lett., 309(2022), art. No. 131457. doi: 10.1016/j.matlet.2021.131457
[58]	Y.X. Ou, H.Q. Wang, B. Liao, M.K. Lei, and X.P. Ouyang, Tribological behaviors in air and seawater of CrN/TiN superlattice coatings irradiated by high-intensity pulsed ion beam, Ceram. Int., 45(2019), No. 18, p. 24405. doi: 10.1016/j.ceramint.2019.08.162
[59]	B. Zhu, G.L. Kelly, and J. Mardel, An investigation of tribological properties of CN and TiCN coatings, J. Mater. Eng. Perform., 13(2004), No. 4, p. 481. doi: 10.1361/10599490420025
[60]	J.M. Lackner, W. Waldhauser, R. Ebner, et al., Room temperature pulsed laser deposited (Ti,Al)C_xN_1−x coatings—Chemical, structural, mechanical and tribological properties, Thin Solid Films, 468(2004), No. 1-2, p. 125. doi: 10.1016/j.tsf.2004.05.089
[61]	J. Liu, S.J. Li, C. Wang, et al., Self-lubricating design strategy for thermally sprayed ceramic coatings by in situ synthesis of carbon spheres, Surf. Coat. Technol., 446(2022), art. No. 128759. doi: 10.1016/j.surfcoat.2022.128759
[62]	I. Çaha, A.C. Alves, C. Chirico, et al., Improved tribocorrosion behavior on bio-functionalized β-type titanium alloy by the pillar effect given by TiN reinforcements, Surf. Coat. Technol., 415(2021), art. No. 127122. doi: 10.1016/j.surfcoat.2021.127122