MOF衍生电磁波吸收材料的设计原则：综述与展望

高振国; 杨锴; 赵泽昊; 兰笛; 周倩; 张教强; 吴宏景

doi:10.1007/s12613-022-2555-8

Volume 30 Issue 3

Mar. 2023

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(3): 405-427

Zhenguo Gao, Kai Yang, Zehao Zhao, Di Lan, Qian Zhou, Jiaoqiang Zhang, and Hongjing Wu, Design principles in MOF-derived electromagnetic wave absorption materials: Review and perspective, Int. J. Miner. Metall. Mater., 30(2023), No. 3, pp. 405-427. https://doi.org/10.1007/s12613-022-2555-8

Cite this article as:

Zhenguo Gao, Kai Yang, Zehao Zhao, Di Lan, Qian Zhou, Jiaoqiang Zhang, and Hongjing Wu, Design principles in MOF-derived electromagnetic wave absorption materials: Review and perspective, Int. J. Miner. Metall. Mater., 30(2023), No. 3, pp. 405-427. https://doi.org/10.1007/s12613-022-2555-8

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特约综述

MOF衍生电磁波吸收材料的设计原则：综述与展望

1)
西北工业大学化学与化工学院, 西安 710072, 中国
2)
西北工业大学物理科学与技术学院超常条件材料物理与化学教育部重点实验室, 西安 710072, 中国
3)
西安邮电大学, 西安 710121, 中国

通讯作者:
周倩    E-mail: zhouqian@xupt.edu.cn

张教强    E-mail: zhangjq@nwpu.edu.cn

吴宏景    E-mail: wuhongjing@nwpu.edu.cn

文章亮点

(1) 系统地综述了具有不同配体、中心离子组装的MOFs及其拓扑机构、衍生物的物理化学性质。

(2) 总结了MOFs衍生吸波材料的电磁波吸收机理

(3) 提出了MOFs衍生吸波材料的发展潜力和方向

中文摘要

目前，因为灵活的组分和结构操纵，金属-有机框架（MOF）衍生的纳微结构正被积极探索以增强介电和磁衰减并用于电磁波吸收。然而，MOF衍生微波吸收材料的基本设计原则尚未总结。本综述致力于从以下角度分析MOF衍生微波吸收材料的设计原理：不同的单体（MOF的配体和离子）、拓扑结构、化学状态和物理性质，还全面总结了有关电磁波吸收机制和结构–功能依赖性的衍生基本信息。最后，对这一前景广阔的领域中产业革命升级的挑战和前景提出了清晰的见解。

关键词:

Invited Review

Design principles in MOF-derived electromagnetic wave absorption materials: Review and perspective

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Abstract

Abstract

At present, metal–organic framework (MOF)-derived nano–micro architectures are actively explored for electromagnetic (EM) wave absorption owing to their flexible composition and structural manipulation that enhance dielectric and magnetic attenuations. However, the basic design principles in MOF-derived microwave absorption materials have not been summarized. This review is devoted to analyzing design principles in MOF-derived microwave absorption materials from the following perspectives: diverse monomers (ligands and ions of MOFs), topologies, chemical states, and physical properties. The derived essential information regarding the EM wave absorption mechanism and the structural–functional dependency is also comprehensively summarized. Finally, a clear insight into the challenges and perspectives of the industrial revolution upgrading in this promising field is proposed.
- metal–organic frameworks;
- topologies;
- chemical states;
- physical properties;
- electromagnetic wave absorption

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