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Volume 30 Issue 6
Jun.  2023
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文章导航 >  矿物冶金与材料学报（英文）  > 2023  >  30(6): 1152-1161
Dan Zhang, Chunyan Zhang, Xuan Zheng, Yizhuo Zhao, Xinyu Shi, Baomin Luo, Yuzhu Li, Guangyin Liu, Xiaodi Liu,  and Chuang Yu, Facile synthesis of the Mn3O4 polyhedron grown on N-doped honeycomb carbon as high-performance negative material for lithium-ion batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 6, pp. 1152-1161. https://doi.org/10.1007/s12613-022-2590-5
Cite this article as:
Dan Zhang, Chunyan Zhang, Xuan Zheng, Yizhuo Zhao, Xinyu Shi, Baomin Luo, Yuzhu Li, Guangyin Liu, Xiaodi Liu,  and Chuang Yu, Facile synthesis of the Mn3O4 polyhedron grown on N-doped honeycomb carbon as high-performance negative material for lithium-ion batteries, Int. J. Miner. Metall. Mater., 30(2023), No. 6, pp. 1152-1161. https://doi.org/10.1007/s12613-022-2590-5
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研究论文

简单合成四氧化三锰多面体与氮掺杂蜂窝碳的复合材料作为高性能锂离子电池负极材料

  • 1)

    南阳师范学院化学与制药工程学院，南阳 473061，中国

  • 2)

    华中科技大学电气与电子工程学院强电磁工程与新技术国家重点实验室，武汉 430074，中国

  • 通讯作者:

    张丹    E-mail: danzhangny@163.com

    余创    E-mail: cyu2020@hust.edu.cn

文章亮点

  • (1) 开发了一种四氧化三锰与氮掺杂蜂窝碳复合材料的简单制备方法。
  • (2) 四氧化三锰纳米多面体均匀的长在氮掺杂蜂窝碳上并与之形成了较强的化学键。
  • (3) 独特的结构显著地提升了电化学反应动力学。
  • 由于四氧化三锰基氧化物负极材料体积变化大、导电性差，且其循环寿命短，倍率性能差，阻碍了它们的发展。在这项研究中，我们使用一种智能且简单的合成方法成功地制备了四氧化三锰与氮掺杂蜂窝碳复合材料。四氧化三锰纳米多面体生长在氮掺杂蜂窝碳上，这明显减轻了充放电过程中的体积变化，而且也改善了电化学反应动力学。更重要的是，四氧化三锰与氮掺杂蜂窝碳复合材料中的Mn–O–C键有利于电化学可逆性。四氧化三锰与氮掺杂蜂窝碳复合材料的这些特征是其优异电化学性能的原因。当用于锂离子电池时，在1 A·g−1下进行350次循环后，四氧化三锰与氮掺杂蜂窝碳负极表现出598 mAh·g−1的高可逆容量。即使在2 A·g−1下，四氧化三锰与氮掺杂蜂窝碳负极仍能提供472 mAh·g−1的高容量。这项工作为合成和开发锰基氧化物储能材料提供了新的前景。
    • Research Article

    Facile synthesis of the Mn3O4 polyhedron grown on N-doped honeycomb carbon as high-performance negative material for lithium-ion batteries

    + Author Affiliations
      Abstract
    • Because of their large volume variation and inferior electrical conductivity, Mn3O4-based oxide anode materials have short cyclic lives and poor rate capability, which obstructs their development. In this study, we successfully prepared a Mn3O4/N-doped honeycomb carbon composite using a smart and facile synthetic method. The Mn3O4 nanopolyhedra are grown on N-doped honeycomb carbon, which evidently mitigates the volume change in the charging and discharging processes but also improves the electrochemical reaction kinetics. More importantly, the Mn–O–C bond in the Mn3O4/N-doped honeycomb carbon composite benefits electrochemical reversibility. These features of the Mn3O4/N-doped honeycomb carbon (NHC) composite are responsible for its superior electrochemical performance. When used for Li-ion batteries, the Mn3O4/N-doped honeycomb carbon anode exhibits a high reversible capacity of 598 mAh·g−1 after 350 cycles at 1 A·g−1. Even at 2 A·g−1, the Mn3O4/NHC anode still delivers a high capacity of 472 mAh·g−1. This work provides a new prospect for synthesizing and developing manganese-based oxide materials for energy storage.
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