g-C3N4纳米片/Bi5O7Br/NH2-MIL-88B（Fe）纳米复合材料的制备：双S异质结光催化剂优异的抗生素去除性能

Nasrin Sedaghati; Aziz Habibi-Yangjeh; Alireza Khataee

doi:10.1007/s12613-023-2618-5

Volume 30 Issue 7

Jul. 2023

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(7): 1363-1374

Nasrin Sedaghati, Aziz Habibi-Yangjeh, and Alireza Khataee, Fabrication of g-C₃N₄ nanosheet/Bi₅O₇Br/NH₂-MIL-88B (Fe) nanocomposites: Double S-scheme photocatalysts with impressive performance for the removal of antibiotics under visible light, Int. J. Miner. Metall. Mater., 30(2023), No. 7, pp. 1363-1374. https://doi.org/10.1007/s12613-023-2618-5

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Nasrin Sedaghati, Aziz Habibi-Yangjeh, and Alireza Khataee, Fabrication of g-C3N4 nanosheet/Bi5O7Br/NH2-MIL-88B (Fe) nanocomposites: Double S-scheme photocatalysts with impressive performance for the removal of antibiotics under visible light, Int. J. Miner. Metall. Mater., 30(2023), No. 7, pp. 1363-1374. https://doi.org/10.1007/s12613-023-2618-5

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研究论文

g-C₃N₄纳米片/Bi₅O₇Br/NH₂-MIL-88B（Fe）纳米复合材料的制备：双S异质结光催化剂优异的抗生素去除性能

1)
Department of Chemistry, Faculty of Science, University of Mohaghegh Ardabili, Ardabil 56199-11367, Iran
2)
Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz 51666-16471, Iran
3)
Department of Environmental Engineering, Faculty of Engineering, Gebze Technical University, Gebze 41400, Turkey

通讯作者:
Aziz Habibi-Yangjeh E-mail: ahabibi@uma.ac.ir

文章亮点

（1）制备了新型双S型异质结结构g-C3N4纳米片/Bi5O7Br/NH2-MIL-88B（Fe）光催化剂

（2）新型结构表现出优异的光催化性能

（3）提出双S方案电荷转移机制

中文摘要

通过简单的溶热方法合成了具有双S型异质结的新型g-C₃N₄纳米片/Bi₅O₇Br/NH₂-MIL-88B（Fe）光催化剂（记为GCN-NSh/Bi₅O₇Br/Fe-MOF，其中MOF是金属–有机框架），并通过X射线光电子能谱仪（XPS）、X射线衍射仪（XRD）、扫描电子显微镜（SEM）、能量色散X射线光谱法（EDX）、透射电子显微镜（TEM）、高分辨率透射电子显微镜法（HRTEM）、光致发光光谱法（PL）、傅立叶变换红外光谱法（FT-IR），UV-Vis漫反射光谱（UV-Vis DRS）、光电流密度、电化学阻抗光谱（EIS）和Brunauer–Emmett–Teller（BET）进行分析。结果表明，将Fe-MOF与GCN-NSh/Bi₅O₇Br复合后，与纯GCN相比，最佳Fe-MOF含量为15wt%的GCN-NSh/Bi₅O₇Br/Fe-MOF纳米复合材料对四环素的去除常数提高了33倍，且GCN-NSh/Bi₅O₇Br/Fe-MOF（15wt%）纳米复合材料对阿奇霉素、甲硝唑和头孢氨苄的去除分别是纯GCN的36.4倍、20.2倍和14.6倍。此外，该纳米复合材料在连续4次循环后保持了优异的活性。基于n-GCN-NSh、n-Bi₅O₇Br和n-Fe-MOF半导体之间n–n异质结的发展，双S方案电荷转移机制被用于抗生素的有效去除。

关键词:

Research Article

Fabrication of g-C₃N₄ nanosheet/Bi₅O₇Br/NH₂-MIL-88B (Fe) nanocomposites: Double S-scheme photocatalysts with impressive performance for the removal of antibiotics under visible light

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Abstract

Abstract

Novel graphitic carbon nitride (g-C₃N₄) nanosheet/Bi₅O₇Br/NH₂-MIL-88B (Fe) photocatalysts (denoted as GCN-NSh/Bi₅O₇Br/Fe-MOF, in which MOF is metal–organic framework) with double S-scheme heterojunctions were synthesized by a facile solvothermal route. The resultant materials were examined by X-ray photoelectron spectrometer (XPS), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), photoluminescence spectroscopy (PL), Fourier transform infrared spectroscopy (FT-IR), UV-Vis diffuse reflection spectroscopy (UV-vis DRS), photocurrent density, electrochemical impedance spectroscopy (EIS), and Brunauer–Emmett–Teller (BET) analyses. After the integration of Fe-MOF with GCN-NSh/Bi₅O₇Br, the removal constant of tetracycline over the optimal GCN-NSh/Bi₅O₇Br/Fe-MOF (15wt%) nanocomposite was promoted 33 times compared with that of the pristine GCN. The GCN-NSh/Bi₅O₇Br/Fe-MOF (15wt%) nanocomposite showed superior photoactivity to azithromycin, metronidazole, and cephalexin removal that was 36.4, 20.2, and 14.6 times higher than that of pure GCN, respectively. Radical quenching tests showed that ^•O${}_2^- $ and h⁺ mainly contributed to the elimination reaction. In addition, the nanocomposite maintained excellent activity after 4 successive cycles. Based on the developed n–n heterojunctions among n-GCN-NSh, n-Bi₅O₇Br, and n-Fe-MOF semiconductors, the double S-scheme charge transfer mechanism was proposed for the destruction of the selected antibiotics.
- g-C₃N₄ nanosheet/Bi₅O₇Br/NH₂-MIL-88B (Fe);
- metal–organic framework;
- double S-scheme heterojunctions;
- antibiotics;
- photocatalytic performance

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