Jiabing Miao, Yingxiao Du, Ruotong Li, Zekun Zhang, Ningning Zhao, Lei Dai, Ling Wang, and Zhangxing He, Recent advances and perspectives of zinc metal-free anodes for zinc ion batteries, Int. J. Miner. Metall. Mater., 31(2024), No. 1, pp.33-47. https://dx.doi.org/10.1007/s12613-023-2665-y
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锌离子电池具有成本低、能量密度高和环境友好的优点，被公认为是潜在的储能设备。但是锌负极在电池充放电过程中会出现不可避免的锌枝晶、钝化、腐蚀和氢气析出反应等问题，这成为锌离子电池实际应用的障碍。合适的无锌金属负极提供了比金属锌负极更高的工作电位，可以有效解决金属锌负极工作过程中的锌枝晶、析氢和副反应问题。电池的安全性和循环寿命的提高为锌离子电池的商业化提供了进一步的进展。在此基础上，文章系统地介绍了无锌金属负极作为“摇椅”锌离子电池锌负极的研究进展。无锌金属负极主要依据四个类别进行了讨论：过渡金属氧化物、过渡金属硫化物、MXene复合材料和有机化合物的特性和储锌机制。最后，对无锌金属负极的发展提出了进一步的展望。希望文章将为商业可充电锌离子电池的进一步发展提供参考。
Zinc-ion batteries (ZIBs) are recognized as potential energy storage devices due to their advantages of low cost, high energy density, and environmental friendliness. However, zinc anodes are subject to unavoidable zinc dendrites, passivation, corrosion, and hydrogen evolution reactions during the charging and discharging of batteries, becoming obstacles to the practical application of ZIBs. Appropriate zinc metal-free anodes provide a higher working potential than metallic zinc anodes, effectively solving the problems of zinc dendrites, hydrogen evolution, and side reactions during the operation of metallic zinc anodes. The improvement in the safety and cycle life of batteries creates conditions for further commercialization of ZIBs. Therefore, this work systematically introduces the research progress of zinc metal-free anodes in “rocking chair” ZIBs. Zinc metal-free anodes are mainly discussed in four categories: transition metal oxides, transition metal sulfides, MXene (two dimensional transition metal carbide) composites, and organic compounds, with discussions on their properties and zinc storage mechanisms. Finally, the outlook for the development of zinc metal-free anodes is proposed. This paper is expected to provide a reference for the further promotion of commercial rechargeable ZIBs.
This work was financially supported by the National Natural Science Foundation of China (Nos. 51872090 and 51772097), the Hebei Natural Science Fund for Distinguished Young Scholar, China (No. E2019209433), the Youth Talent Program of Hebei Provincial Education Department, China (No. BJ2018020), the Natural Science Foundation of Hebei Province, China (No. E2020209151), and the Science and Technology Project of Hebei Education Department, China (No. SLRC2019028).
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