对比溶胶–凝胶法和静电纺丝法制备的混合P2/O′3型层状镍锰酸钠正极材料的结构和电化学性能：Na过剩量的影响

Thongsuk Sichumsaeng; Atchara Chinnakorn; Ornuma Kalawa; Jintara Padchasri; Pinit Kidkhunthod; and Santi Maensiri

doi:10.1007/s12613-023-2702-x

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文章导航 > 矿物冶金与材料学报（英文） > 2023 > 30(10): 1887-1896

Thongsuk Sichumsaeng, Atchara Chinnakorn, Ornuma Kalawa, Jintara Padchasri, Pinit Kidkhunthod, and Santi Maensiri, Comparative structural and electrochemical properties of mixed P2/O′3-layered sodium nickel manganese oxide prepared by sol–gel and electrospinning methods: Effect of Na-excess content, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1887-1896. https://doi.org/10.1007/s12613-023-2702-x

Cite this article as:

Thongsuk Sichumsaeng, Atchara Chinnakorn, Ornuma Kalawa, Jintara Padchasri, Pinit Kidkhunthod, and Santi Maensiri, Comparative structural and electrochemical properties of mixed P2/O′3-layered sodium nickel manganese oxide prepared by sol–gel and electrospinning methods: Effect of Na-excess content, Int. J. Miner. Metall. Mater., 30(2023), No. 10, pp. 1887-1896. https://doi.org/10.1007/s12613-023-2702-x

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对比溶胶–凝胶法和静电纺丝法制备的混合P2/O′3型层状镍锰酸钠正极材料的结构和电化学性能：Na过剩量的影响

1)
School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
2)
SUT CoE on Advanced Functional Materials, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
3)
Research Network NANOTEC-SUT on Advanced Nanomaterials and Characterization, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
4)
Synchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, Thailand

通讯作者:
and Santi Maensiri E-mail: santimaensiri@gmail.com

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Research Article

Comparative structural and electrochemical properties of mixed P2/O′3-layered sodium nickel manganese oxide prepared by sol–gel and electrospinning methods: Effect of Na-excess content

+ Author Affiliations

1)
School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
2)
SUT CoE on Advanced Functional Materials, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
3)
Research Network NANOTEC-SUT on Advanced Nanomaterials and Characterization, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand
4)
Synchrotron Light Research Institute (Public Organization), 111 University Avenue, Muang District, Nakhon Ratchasima 30000, Thailand

All authors confirm that they have no competing interests or financial ties that could influence the outcomes or interpretation of this research.
The online version contains supplementary material available at https://doi.org/10.1007/s12613-023-2702-x

Corresponding author:
Santi Maensiri E-mail: santimaensiri@gmail.com
Received: 12 January 2023; Revised: 4 July 2023; Accepted: 5 July 2023; Available online: 7 July 2023

Abstract

Abstract

The effect of Na-excess content in the precursor on the structural and electrochemical performances of sodium nickel manganese oxide (NNMO) prepared by sol–gel and electrospinning methods is investigated in this paper. X-ray diffraction results of the prepared NNMO without adding Na-excess content indicate sodium loss, while the mixed phase of P2/O′3-type layered NNMO presented after adding Na-excess content. Compared with the sol–gel method, the secondary phase of NiO is more suppressed by using the electrospinning method, which is further confirmed by field emission scanning electron microscope images. N₂ adsorption–desorption isotherms show no remarkably difference in specific surface areas between different preparation methods and Na-excess contents. The analysis of X-ray absorption near edge structure indicates that the oxidation states of Ni and Mn are +2 and +4, respectively. For the electrochemical properties, superior electrochemical performance is observed in the NNMO electrode with a low Na-excess content of 5wt%. The highest specific capacitance is 36.07 F·g⁻¹ at 0.1 A·g⁻¹ in the NNMO electrode prepared by using the sol–gel method. By contrast, the NNMO electrode prepared using the electrospinning method with decreased Na-excess content shows excellent cycling stability of 100% after charge–discharge measurements for 300 cycles. Therefore, controlling the Na excess in the precursor together with the preparation method is important for improving the electrochemical performance of Na-based electrode materials in supercapacitors.
- sodium nickel manganese oxide;
- mixed P2/O′3-type;
- Na-excess content;
- sol–gel method;
- electrospinning method;
- electrochemical properties

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对比溶胶–凝胶法和静电纺丝法制备的混合P2/O′3型层状镍锰酸钠正极材料的结构和电化学性能：Na过剩量的影响

Comparative structural and electrochemical properties of mixed P2/O′3-layered sodium nickel manganese oxide prepared by sol–gel and electrospinning methods: Effect of Na-excess content

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