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Han Dang, Runsheng Xu, Jianliang Zhang, Mingyong Wang, and Jinhua Li, Cross-upgrading of biomass hydrothermal carbonization and pyrolysis for high quality blast furnace injection fuel production: Physicochemical characteristics and gasification kinetics analysis, Int. J. Miner. Metall. Mater., 31(2024), No. 2, pp.268-281. https://dx.doi.org/10.1007/s12613-023-2728-0
Han Dang, Runsheng Xu, Jianliang Zhang, Mingyong Wang, and Jinhua Li, Cross-upgrading of biomass hydrothermal carbonization and pyrolysis for high quality blast furnace injection fuel production: Physicochemical characteristics and gasification kinetics analysis, Int. J. Miner. Metall. Mater., 31(2024), No. 2, pp.268-281. https://dx.doi.org/10.1007/s12613-023-2728-0
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水热与热解交叉炭化生物质制备高品质高炉喷吹燃料:理化特性和气化动力学分析

摘要: 本文提出了一种生物质交叉升级工艺,将水热炭化和热解相结合,生产出高质量的高炉喷吹燃料。结果表明,升级后的生物炭挥发物含量在 16.19% 至 45.35% 之间,碱金属含量、灰分含量和比表面积显著降低。生物质炭生产的最佳途径是先水热炭化后热解,从而获得热值更高、芳香结构更合理、石墨化程度更高的生物质炭。样品的表观活化能(E)范围为 199.1 至 324.8 kJ/mol,其中水热–热解(P-HC)的 E 为 277.8 kJ/mol,低于原生物质、初级生物质炭和无烟煤。这使得 P-HC 更适合用作高炉喷吹燃料。此外,论文还提出了在高炉中喷吹 P-HC 的工艺路线,并计算了潜在的环境效益。当取代 40wt% 的喷煤时,P-HC 具有最大的碳减排潜力,可减少 96.04 kg/t 的排放量。

 

Cross-upgrading of biomass hydrothermal carbonization and pyrolysis for high quality blast furnace injection fuel production: Physicochemical characteristics and gasification kinetics analysis

Abstract: The paper proposes a biomass cross-upgrading process that combines hydrothermal carbonization and pyrolysis to produce high-quality blast furnace injection fuel. The results showed that after upgrading, the volatile content of biochar ranged from 16.19% to 45.35%, and the alkali metal content, ash content, and specific surface area were significantly reduced. The optimal route for biochar production is hydrothermal carbonization–pyrolysis (P-HC), resulting in biochar with a higher calorific value, C=C structure, and increased graphitization degree. The apparent activation energy (E) of the sample ranges from 199.1 to 324.8 kJ/mol, with P-HC having an E of 277.8 kJ/mol, lower than that of raw biomass, primary biochar, and anthracite. This makes P-HC more suitable for blast furnace injection fuel. Additionally, the paper proposes a path for P-HC injection in blast furnaces and calculates potential environmental benefits. P-HC offers the highest potential for carbon emission reduction, capable of reducing emissions by 96.04 kg/t when replacing 40wt% coal injection.

 

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