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Dajun Zhai, Xiaoping Li, and Jun Shen, Mechanism of microarc oxidation on AZ91D Mg alloy induced by β-Mg17Al12 phase, Int. J. Miner. Metall. Mater., 31(2024), No. 4, pp.712-724. https://dx.doi.org/10.1007/s12613-023-2752-0
Dajun Zhai, Xiaoping Li, and Jun Shen, Mechanism of microarc oxidation on AZ91D Mg alloy induced by β-Mg17Al12 phase, Int. J. Miner. Metall. Mater., 31(2024), No. 4, pp.712-724. https://dx.doi.org/10.1007/s12613-023-2752-0
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β-Mg17Al12相诱导AZ91D 镁合金微弧氧化过程机理

摘要: 由于镁合金中元素的不均匀分布以及金属间相的存在,导致合金表面的电化学特性是不均匀的。通过在镁合金中控制第二相β-Mg17Al12的含量和分布来间接诱导均匀微弧放电的方法有着巨大的研究潜力。本文通过搅拌摩擦处理(FSP)将两种纳米颗粒(ZrO2和TiO2)加入到镁合金基体中。然后,在磷酸盐和硅酸盐混合电解液中对设计的具有不同沉淀形态的β-Mg17Al12相的镁合金样品进行微弧氧化处理。利用扫描电子显微镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)、X光电子能谱仪、接触角仪和动电位极化仪对微弧氧化涂层的特性和性能进行分析。结果表明,FSP工艺细化了AZ91D轧制镁合金内的α-Mg晶粒,搅碎了β-Mg17Al12相的网状结构,使β相弥散分布。纳米ZrO2颗粒通过FSP工艺可钉扎在镁合金晶界处,不仅促进了α-Mg晶粒的细化,而且还促进了β相在α-Mg晶界处和晶内的弥散析出。由此有效地抑制了镁合金表面微弧氧化“级联”放电现象,从而导致放电孔隙的均匀分布。因此,通过FSP工艺将纳米ZrO2颗粒固定在晶界上,调控了基体中的β-Mg17Al12相结构和分布,提高了基体表面微弧氧化涂层的润湿性和耐腐蚀性。然而,在Ti-FSP样品上的微弧氧化涂层中几乎没有检测到TiO2颗粒。

 

Mechanism of microarc oxidation on AZ91D Mg alloy induced by β-Mg17Al12 phase

Abstract: This work proposed a strategy of indirectly inducing uniform microarc discharge by controlling the content and distribution of β-Mg17Al12 phase in AZ91D Mg alloy. Two kinds of nano-particles (ZrO2 and TiO2) were designed to be added into the substrate of Mg alloy by friction stir processing (FSP). Then, Mg alloy sample designed with different precipitated morphology of β-Mg17Al12 phase was treated by microarc oxidation (MAO) in Na3PO4/Na2SiO3 electrolyte. The characteristics and performance of the MAO coating was analyzed using scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), contact angle meter, and potentiodynamic polarization. It was found that the coarse α-Mg grains in extruded AZ91D Mg alloy were refined by FSP, and the β-Mg17Al12 phase with reticular structure was broken and dispersed. The nano-ZrO2 particles were pinned at the grain boundary by FSP, which refined the α-Mg grain and promoted the precipitation of β-Mg17Al12 phase in grains. It effectively inhibited the “cascade” phenomenon of microarcs, which induced the uniform distribution of discharge pores. The MAO coating on Zr-FSP sample had good wettability and corrosion resistance. However, TiO2 particles were hardly detected in the coating on Ti-FSP sample.

 

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