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Hongxia Li, Wenjun Xu, Yufei Zhang, Shenglan Yang, Lijun Zhang, Bin Liu, Qun Luo, and Qian Li, Prediction of the thermal conductivity of Mg–Al–La alloys by CALPHAD method, Int. J. Miner. Metall. Mater., 31(2024), No. 1, pp.129-137. https://dx.doi.org/10.1007/s12613-023-2759-6
Hongxia Li, Wenjun Xu, Yufei Zhang, Shenglan Yang, Lijun Zhang, Bin Liu, Qun Luo, and Qian Li, Prediction of the thermal conductivity of Mg–Al–La alloys by CALPHAD method, Int. J. Miner. Metall. Mater., 31(2024), No. 1, pp.129-137. https://dx.doi.org/10.1007/s12613-023-2759-6
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运用CALPHAD 方法预测Mg–Al–La 合金的热导率

摘要: Mg–Al合金作为最常用的铸造镁合金,以其卓越的强度和延展性而得到广泛应用,然而由于Al元素的添加导致热导率显著降低。准确预测导热系数是设计高导热镁铝合金的关键先决条件。因此,须建立用于预测与温度和成分相关的热导率的数据库。本研究通过热力学计算设计了六种含有不同Al2La、Al3La、Al11La3相含量以及Al在α-Mg相中固溶度不同的Mg–Al–La合金。实验结果表明,在La量保持恒定的情况下,随着Al含量的增加,合金中的第二相由Al2La相向Al3La相转变,并进一步向Al11La3相转变。其中第二相对Mg–Al–La合金热扩散率的负面影响为:Al2La相 > Al3La相 > Al11La3相。然而,在第二相含量相同但种类不同的三元合金中发现位于α-Mg + Al11La3两相区内且Al在基体α-Mg中固溶度最大的三元合金对应的热导率最小。这表明,与第二相相比,Al在基体α-Mg 中固溶度的增加显着降低了合金的热导率。基于实验数据,采用相图计算(CALPHAD)方法构建了Mg–Al–La体系的热扩散热阻数据库,得到的计算结果与实验结果吻合较好,标准误差为±1.2 W/(m·K)。Mg–Al系合金热导率数据库的建立可以为高导热镁铝合金的设计提供理论指导并拓展其应用前景。

 

Prediction of the thermal conductivity of Mg–Al–La alloys by CALPHAD method

Abstract: Mg−Al alloys have excellent strength and ductility but relatively low thermal conductivity due to Al addition. The accurate prediction of thermal conductivity is a prerequisite for designing Mg−Al alloys with high thermal conductivity. Thus, databases for predicting temperature- and composition-dependent thermal conductivities must be established. In this study, Mg−Al−La alloys with different contents of Al2La, Al3La, and Al11La3 phases and solid solubility of Al in the α-Mg phase were designed. The influence of the second phase(s) and Al solid solubility on thermal conductivity was investigated. Experimental results revealed a second phase transformation from Al2La to Al3La and further to Al11La3 with the increasing Al content at a constant La amount. The degree of the negative effect of the second phase(s) on thermal diffusivity followed the sequence of Al2La > Al3La > Al11La3. Compared with the second phase, an increase in the solid solubility of Al in α-Mg remarkably reduced the thermal conductivity. On the basis of the experimental data, a database of the reciprocal thermal diffusivity of the Mg−Al−La system was established by calculation of the phase diagram (CALPHAD) method. With a standard error of ±1.2 W/(m·K), the predicted results were in good agreement with the experimental data. The established database can be used to design Mg−Al alloys with high thermal conductivity and provide valuable guidance for expanding their application prospects.

 

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