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Baosheng Liu, Jiali Wei, Shaohua Zhang, Yuezhong Zhang, Pengpeng Wu, Daqing Fang, and Guorui Ma, Microstructures, corrosion behavior and mechanical properties of as-cast Mg–6Zn–2X(Fe/Cu/Ni) alloys for plugging tool applications, Int. J. Miner. Metall. Mater., 31(2024), No. 4, pp.697-711. https://dx.doi.org/10.1007/s12613-023-2775-6
Baosheng Liu, Jiali Wei, Shaohua Zhang, Yuezhong Zhang, Pengpeng Wu, Daqing Fang, and Guorui Ma, Microstructures, corrosion behavior and mechanical properties of as-cast Mg–6Zn–2X(Fe/Cu/Ni) alloys for plugging tool applications, Int. J. Miner. Metall. Mater., 31(2024), No. 4, pp.697-711. https://dx.doi.org/10.1007/s12613-023-2775-6
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用作封堵工具的铸态Mg–6Zn–2X(Fe/Cu/Ni)合金的微观组织、腐蚀行为和力学性能

摘要: 通过半连续铸造制备了 Mg–6Zn–2X(Fe/Cu/Ni)合金,以确定一种适合用于压裂球的可降解镁(Mg)合金。对比分析了Cu和Ni的添加的影响,导致了晶粒细化和电偶腐蚀位点的形成。扫描电子显微镜表明,析出相聚集在晶界处,形成半连续的网络结构,其结构加速了 Mg–6Zn–2Cu 和 Mg–6Zn–2Ni 合金腐蚀过程中电解质离子的渗透。在 Mg–6Zn–2Fe 中观察到了点蚀现象,而在 Mg–6Zn–2Cu 和 Mg–6Zn–2Ni 合金中,电偶腐蚀被确定为主要机制。在试验合金中,Mg–6Zn–2Ni合金的腐蚀速率最高(约 932.9 mm/a)。力学测试表明,Mg–6Zn–2Ni 合金具有合适的抗压强度,是可降解压裂球的潜在候选材料,有效解决了压裂应用中强度和降解率的平衡难题。

 

Microstructures, corrosion behavior and mechanical properties of as-cast Mg–6Zn–2X(Fe/Cu/Ni) alloys for plugging tool applications

Abstract: Mg–6Zn–2X(Fe/Cu/Ni) alloys were prepared through semi-continuous casting, with the aim of identifying a degradable magnesium (Mg) alloy suitable for use in fracturing balls. A comparative analysis was conducted to assess the impacts of adding Cu and Ni, which result in finer grains and the formation of galvanic corrosion sites. Scanner electronic microscopy examination revealed that precipitated phases concentrated at grain boundaries, forming a semi-continuous network structure that facilitated corrosion penetration in Mg–6Zn–2Cu and Mg–6Zn–2Ni alloys. Pitting corrosion was observed in Mg–6Zn–2Fe, while galvanic corrosion was identified as the primary mechanism in Mg–6Zn–2Cu and Mg–6Zn–2Ni alloys. Among the tests, the Mg–6Zn–2Ni alloy exhibited the highest corrosion rate (approximately 932.9 mm/a) due to its significant potential difference. Mechanical testing showed that Mg–6Zn–2Ni alloy possessed suitable ultimate compressive strength, making it a potential candidate material for degradable fracturing balls, effectively addressing the challenges of balancing strength and degradation rate in fracturing applications.

 

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