基于NdxSm1−xNiO3金属绝缘体相变特性的温度传感阵列

鄢峰波; 李子昂; 张豪; 崔雨晨; 聂开琪; 陈诺夫; 陈吉堃

doi:10.1007/s12613-023-2816-1

Volume 31 Issue 7

Jul. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(7): 1694-1700

Fengbo Yan, Ziang Li, Hao Zhang, Yuchen Cui, Kaiqi Nie, Nuofu Chen, and Jikun Chen, Temperature-sensing array using the metal-to-insulator transition of Nd_xSm_1−xNiO₃, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1694-1700. https://doi.org/10.1007/s12613-023-2816-1

Cite this article as:

Fengbo Yan, Ziang Li, Hao Zhang, Yuchen Cui, Kaiqi Nie, Nuofu Chen, and Jikun Chen, Temperature-sensing array using the metal-to-insulator transition of NdxSm1−xNiO3, Int. J. Miner. Metall. Mater., 31(2024), No. 7, pp. 1694-1700. https://doi.org/10.1007/s12613-023-2816-1

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研究论文

基于Nd_xSm_1−xNiO₃金属绝缘体相变特性的温度传感阵列

1)
北京科技大学材料科学与工程学院, 北京 100083, 中国
2)
华北电力大学可再生能源学院, 北京 102206, 中国
3)
中国科学院高能物理研究所北京同步辐射装置, 北京 100049, 中国

通讯作者:
陈吉堃 E-mail: jikunchen@ustb.edu.cn

文章亮点

(1) Nd_xSm_1−xNiO₃金属绝缘体相变特性无温度滞回且阻温系数远高于传统NTC热敏电阻

(2) Nd_xSm_1−xNiO₃金属绝缘体相变温度特性可通过稀土组分设计在200~400 K连续调节。

(3) 采用具有不同稀土组分的Nd_xSm_1−xNiO₃组成阵列可拓宽高阻温系数的温区，有望应用于精密温度测量。

中文摘要

在诸多电子相变材料中，稀土镍基氧化物（RENiO₃）具有宽温区可连续调控的金属绝缘体相变（MIT）特性，在强关联逻辑器件、突变式热敏电阻、红外伪装等方面具有潜在应用价值。本项工作利用碱金属卤化物助熔辅助下的高氧压固相反应制备了Nd_xSm_1−xNiO₃陶瓷材料，通过在x为0~1范围内调控Nd/Sm原子比例实现了其MIT特征触发温度（T_MIT）在200~400 K温区的准连续调控。特别是对于x ≤ 0.8的Nd_xSm_1−xNiO₃其在跨越特征温度（T_MIT）附近210~360 K温区范围内呈现出远高于传统负阻温系数（NTC）热敏电阻的阻温系数（例如，超过7%/K），且其升降温测量的电阻率温度关系无明显温度滞回。因此，通过引入优化的并联电阻可在10 K范围内实现Nd_xSm_1−xNiO₃电阻率与温度的线性变化，从而有望应用于精密温度传感；而进一步通过将具有不同稀土比例Nd_xSm_1−xNiO₃的组成阵列，可将上述精密温度传感的潜在温区拓宽至210~360 K。

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Research Article

Temperature-sensing array using the metal-to-insulator transition of Nd_xSm_1−xNiO₃

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Abstract

Abstract

Rare-earth nickelates (RENiO₃) show widely tunable metal-to-insulator transition (MIT) properties with ignorable variations in lattice constants and small latent heat across the critical temperature (T_MIT). Particularly, it is worth noting that compared with the more commonly investigated vanadium oxides, the MIT of RENiO₃ is less abrupt but usually across a wider range of temperatures. This sheds light on their alternative applications as negative temperature coefficient resistance (NTCR) thermistors with high sensitivity compared with the current NTCR thermistors, other than their expected use as critical temperature resistance thermistors. In this work, we demonstrate the NTCR thermistor functionality for using the adjustable MIT of Nd_xSm_1−xNiO₃ within 200–400 K, which displays larger magnitudes of NTCR (e.g., more than 7%/K) that is unattainable in traditional NTCR thermistor materials. The temperature dependence of resistance (R–T) shows sharp variation during the MIT of Nd_xSm_1−xNiO₃ with no hysteresis via decreasing the Nd content (e.g., x ≤ 0.8), and such a R–T tendency can be linearized by introducing an optimum parallel resistor. The sensitive range of temperature can be further extended to 210–360 K by combining a series of Nd_xSm_1−xNiO₃ with eight rare-earth co-occupation ratios as an array, with a high magnitude of NTCR (e.g., 7%–14%/K) covering the entire range of temperatures.
- rare-earth nickelates;
- metal-to-insulator transition;
- correlated oxides;
- perovskites

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References

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基于Nd_xSm_1−xNiO₃金属绝缘体相变特性的温度传感阵列

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Temperature-sensing array using the metal-to-insulator transition of Nd_xSm_1−xNiO₃

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