壳聚糖基摩擦电材料用于高温环境下自供电传感

陈文灿; 李超; 陶叶晗; 鲁杰; 杜健; 王海松

doi:10.1007/s12613-024-2839-2

Volume 31 Issue 11

Nov. 2024

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文章导航 > 矿物冶金与材料学报（英文） > 2024 > 31(11): 2518-2527

Wencan Chen, Chao Li, Yehan Tao, Jie Lu, Jian Du, and Haisong Wang, Chitosan-based triboelectric materials for self-powered sensing at high temperatures, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp. 2518-2527. https://doi.org/10.1007/s12613-024-2839-2

Cite this article as:

Wencan Chen, Chao Li, Yehan Tao, Jie Lu, Jian Du, and Haisong Wang, Chitosan-based triboelectric materials for self-powered sensing at high temperatures, Int. J. Miner. Metall. Mater., 31(2024), No. 11, pp. 2518-2527. https://doi.org/10.1007/s12613-024-2839-2

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研究论文

壳聚糖基摩擦电材料用于高温环境下自供电传感

大连工业大学轻工与化学工程学院, 大连 116034, 中国

* 共同第一作者

通讯作者:
杜健 E-mail: wanghs@dlpu.edu.cn

王海松 E-mail: dujian01@dlpu.edu.cn

文章亮点

(1) 系统地研究了蒙脱土和木质素对摩擦电信号的影响规律

(2) 开发了抑制高温环境下摩擦电荷损失的新型壳聚糖/蒙脱土/木质素复合薄膜

(3) 总结并提出了适用于高温环境下摩擦电极所应具有的微观结构

中文摘要

天然高聚物已被广泛用作构建可降解自供电传感系统的摩擦电材料，但在高温下电极表面摩擦电荷的湮灭限制了组装传感器的输出信号和灵敏度。为开发适用于高温环境下的天然多糖基传感材料，本文章设计了一种适用于较高温度环境中（25–70°C）的新型壳聚糖/蒙脱石/木质素（CML）复合薄膜，用作自供电传感系统组装中的摩擦正极层。系统地表征结果表明，天然聚合物和无机蒙脱土纳米粒子之间较强的分子间相互作用赋予了薄膜致密结构，该结构可以有效抑制表面摩擦电荷的挥发。经过电信号优化，CML-TENG的最高开路电压（V_oc）和最大瞬时输出功率密度分别达到262 V和429 mW/m²。在不同温度下电信号输出实验结果表明，对于初始 TENG而言，当温度从室温增加到70°C时，输出电信号仅保留了39%，而优化后的CML-TENG 保留了66%，意味着本研究开发的新型摩擦电材料具有较好的温度适应性，本研究为抑制高温下摩擦电荷的湮灭提供了一种新策略。

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Research Article

Chitosan-based triboelectric materials for self-powered sensing at high temperatures

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Abstract

Abstract

Although biopolymers have been widely utilized as triboelectric materials for the construction of self-powered sensing systems, the annihilation of triboelectric charges at high temperatures restricts the output signals and sensitivity of the assembled sensors. Herein, a novel chitosan/montmorillonite/lignin (CML) composite film was designed and employed as a tribopositive layer in the assembly of a self-powered sensing system for use under hot conditions (25–70°C). The dense contact surface resulting from the strong intermolecular interaction between biopolymers and nanofillers restrained the volatilization of induced electrons. The optimized CML-TENG delivered the highest open-circuit voltage (V_oc) of 262 V and maximum instantaneous output power of 429 mW/m². Pristine CH-TENG retained only 39% of its initial V_oc at 70°C, whereas the optimized CM₅L₃-TENG retained 66% of its initial V_oc. Our work provides a new strategy for suppressing the annihilation of triboelectric charges at high temperatures, thus boosting the development of self-powered sensing devices for application under hot conditions.
- chitosan;
- lignin;
- montmorillonite;
- triboelectric nanogenerator;
- hot conditions

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References(43)

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壳聚糖基摩擦电材料用于高温环境下自供电传感

文章亮点

中文摘要

Chitosan-based triboelectric materials for self-powered sensing at high temperatures

Abstract

References

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